Syntheses and reactions of tetrazole-group 13 complexes

Miguel Angel Muñoz-Hernández; Michael S. Hill; D. A. Atwood

doi:10.1016/S0277-5387(98)00057-6

Syntheses and reactions of tetrazole-group 13 complexes

Miguel Angel Muñoz-Hernández, Michael S. Hill, D. A. Atwood

Research output: Contribution to journal › Article › peer-review

10 Scopus citations

Abstract

The combination of 5-phenyl-1-H-tetrazole (let) with AlR₃ in stoichiometries of 1-3 leads to the compounds [(tet)AlR₂]_n R=Me (1), Et (2), ⁱBu (3), [(tet)₂AlMe]_n (4), and [(tet)₃Al]_n (5). The addition of pyridine to 1 leads to a soluble compound with the formulation, [(tet)AlMe₂-pyridine]_n (6). Likewise the addition of AlMe₃ to 1 and 4 leads to the products [(tet)AlMe₂-AlMe₃]₂ (7) and [(tet)₂AlMe-AlMe₃]_n (8). The compounds were characterized by standard techniques and, in the case of 7 by X-ray crystallography. Compounds 1, 4 and 5 were examined (unsuccessfully) as potential unimolecular precursors to aluminum nitride.

Original language	English
Pages (from-to)	2237-2242
Number of pages	6
Journal	Polyhedron
Volume	17
Issue number	13-14
DOIs	https://doi.org/10.1016/S0277-5387(98)00057-6
State	Published - 1998

Keywords

Aluminum
Precursor
Tetrazole

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/S0277-5387(98)00057-6

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@article{680b347cdbde4486a5b280249b879734,

title = "Syntheses and reactions of tetrazole-group 13 complexes",

abstract = "The combination of 5-phenyl-1-H-tetrazole (let) with AlR3 in stoichiometries of 1-3 leads to the compounds [(tet)AlR2]n R=Me (1), Et (2), iBu (3), [(tet)2AlMe]n (4), and [(tet)3Al]n (5). The addition of pyridine to 1 leads to a soluble compound with the formulation, [(tet)AlMe2-pyridine]n (6). Likewise the addition of AlMe3 to 1 and 4 leads to the products [(tet)AlMe2-AlMe3]2 (7) and [(tet)2AlMe-AlMe3]n (8). The compounds were characterized by standard techniques and, in the case of 7 by X-ray crystallography. Compounds 1, 4 and 5 were examined (unsuccessfully) as potential unimolecular precursors to aluminum nitride.",

keywords = "Aluminum, Precursor, Tetrazole",

author = "Mu{\~n}oz-Hern{\'a}ndez, {Miguel Angel} and Hill, {Michael S.} and Atwood, {D. A.}",

year = "1998",

doi = "10.1016/S0277-5387(98)00057-6",

language = "English",

volume = "17",

pages = "2237--2242",

number = "13-14",

}

TY - JOUR

T1 - Syntheses and reactions of tetrazole-group 13 complexes

AU - Muñoz-Hernández, Miguel Angel

AU - Hill, Michael S.

AU - Atwood, D. A.

PY - 1998

Y1 - 1998

N2 - The combination of 5-phenyl-1-H-tetrazole (let) with AlR3 in stoichiometries of 1-3 leads to the compounds [(tet)AlR2]n R=Me (1), Et (2), iBu (3), [(tet)2AlMe]n (4), and [(tet)3Al]n (5). The addition of pyridine to 1 leads to a soluble compound with the formulation, [(tet)AlMe2-pyridine]n (6). Likewise the addition of AlMe3 to 1 and 4 leads to the products [(tet)AlMe2-AlMe3]2 (7) and [(tet)2AlMe-AlMe3]n (8). The compounds were characterized by standard techniques and, in the case of 7 by X-ray crystallography. Compounds 1, 4 and 5 were examined (unsuccessfully) as potential unimolecular precursors to aluminum nitride.

AB - The combination of 5-phenyl-1-H-tetrazole (let) with AlR3 in stoichiometries of 1-3 leads to the compounds [(tet)AlR2]n R=Me (1), Et (2), iBu (3), [(tet)2AlMe]n (4), and [(tet)3Al]n (5). The addition of pyridine to 1 leads to a soluble compound with the formulation, [(tet)AlMe2-pyridine]n (6). Likewise the addition of AlMe3 to 1 and 4 leads to the products [(tet)AlMe2-AlMe3]2 (7) and [(tet)2AlMe-AlMe3]n (8). The compounds were characterized by standard techniques and, in the case of 7 by X-ray crystallography. Compounds 1, 4 and 5 were examined (unsuccessfully) as potential unimolecular precursors to aluminum nitride.

KW - Aluminum

KW - Precursor

KW - Tetrazole

UR - http://www.scopus.com/inward/record.url?scp=0041193137&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0041193137&partnerID=8YFLogxK

U2 - 10.1016/S0277-5387(98)00057-6

DO - 10.1016/S0277-5387(98)00057-6

M3 - Article

AN - SCOPUS:0041193137

SN - 0277-5387

VL - 17

SP - 2237

EP - 2242

JO - Polyhedron

JF - Polyhedron

IS - 13-14

ER -

Syntheses and reactions of tetrazole-group 13 complexes

Abstract

Keywords

ASJC Scopus subject areas

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