Syntheses, structures, and magnetic characterization of dicyanometalate(II) building blocks: [NEt4][(Tp*)MII(CN)2] [MII = Cr, Co, Ni; Tp* = hydridotris(3,5-dimethylpyrazol-1-yl) borate]

Dongfeng Li, Chad Ruschman, Sean Parkin, Rodolphe Clérac, Stephen M. Holmes

Research output: Contribution to journalArticlepeer-review

19 Scopus citations

Abstract

The syntheses and structures of three dicyanometalate(II) complexes, [NEt4][(Tp*)MII(CN)2] ·nMeCN·1/2Et2O (MII = Cr, 1, n = 1/2; Co, 2, n = 1; Ni, 3, n = 1) are described; magnetic studies indicate that 3 is diamagnetic while 1 and 2 are paramagnetic high- and low-spin S = 2 and 1/2 complexes, respectively.

Original languageEnglish
Pages (from-to)4036-4038
Number of pages3
JournalChemical Communications
Issue number38
DOIs
StatePublished - 2006

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • General Chemistry
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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