Synthesis and characterisation of porphyrazinoctamine derivatives: X-ray crystallographic studies of [2,3,7,8,12,13,17,18-octakis(dibenzylamino)- porphyrazinato]magnesium(II) and {2,3,7,8,12,13,17,18-octakis[allyl(benzyl) amino]-porphyrazinato}nickel(II)

Neelakandha S. Mani; L. Scott Beall; Todd Miller; Oren P. Anderson; Håkon Hope; Sean R. Parkin; David J. Williams; Anthony G.M. Barrett; Brian M. Hoffman

doi:10.1039/C39940002095

Synthesis and characterisation of porphyrazinoctamine derivatives: X-ray crystallographic studies of [2,3,7,8,12,13,17,18-octakis(dibenzylamino)- porphyrazinato]magnesium(II) and {2,3,7,8,12,13,17,18-octakis[allyl(benzyl) amino]-porphyrazinato}nickel(II)

Neelakandha S. Mani, L. Scott Beall, Todd Miller, Oren P. Anderson, Håkon Hope, Sean R. Parkin, David J. Williams, Anthony G.M. Barrett, Brian M. Hoffman

Chemistry

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45 Scopus citations

Abstract

2,3-Bis(dibenzylamino)- and 2,3-bis[allyl(benzyl)amino]-2Z-butene-1,4- dinitriles are macrocyclised by reaction with magnesium propoxide in propanol to provide the corresponding (porphyrazinato)magnesium(II) derivatives, the structures of which are confirmed by X-ray crystallographic studies of the title magnesium and nickel(II) complexes; cyclisation of alternative diaminomaleonitrile derivatives gives the corresponding porphyrazinoctamines.

Original language	English
Pages (from-to)	2095-2096
Number of pages	2
Journal	Chemical Communications
Issue number	18
DOIs	https://doi.org/10.1039/C39940002095
State	Published - 1994

ASJC Scopus subject areas

Molecular Medicine

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Mani, N. S., Beall, L. S., Miller, T., Anderson, O. P., Hope, H., Parkin, S. R., Williams, D. J., Barrett, A. G. M., & Hoffman, B. M. (1994). Synthesis and characterisation of porphyrazinoctamine derivatives: X-ray crystallographic studies of [2,3,7,8,12,13,17,18-octakis(dibenzylamino)- porphyrazinato]magnesium(II) and {2,3,7,8,12,13,17,18-octakis[allyl(benzyl) amino]-porphyrazinato}nickel(II). Chemical Communications, (18), 2095-2096. https://doi.org/10.1039/C39940002095

Mani, Neelakandha S. ; Beall, L. Scott ; Miller, Todd et al. / Synthesis and characterisation of porphyrazinoctamine derivatives : X-ray crystallographic studies of [2,3,7,8,12,13,17,18-octakis(dibenzylamino)- porphyrazinato]magnesium(II) and {2,3,7,8,12,13,17,18-octakis[allyl(benzyl) amino]-porphyrazinato}nickel(II). In: Chemical Communications. 1994 ; No. 18. pp. 2095-2096.

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title = "Synthesis and characterisation of porphyrazinoctamine derivatives: X-ray crystallographic studies of [2,3,7,8,12,13,17,18-octakis(dibenzylamino)- porphyrazinato]magnesium(II) and {2,3,7,8,12,13,17,18-octakis[allyl(benzyl) amino]-porphyrazinato}nickel(II)",

abstract = "2,3-Bis(dibenzylamino)- and 2,3-bis[allyl(benzyl)amino]-2Z-butene-1,4- dinitriles are macrocyclised by reaction with magnesium propoxide in propanol to provide the corresponding (porphyrazinato)magnesium(II) derivatives, the structures of which are confirmed by X-ray crystallographic studies of the title magnesium and nickel(II) complexes; cyclisation of alternative diaminomaleonitrile derivatives gives the corresponding porphyrazinoctamines.",

author = "Mani, {Neelakandha S.} and Beall, {L. Scott} and Todd Miller and Anderson, {Oren P.} and H{\aa}kon Hope and Parkin, {Sean R.} and Williams, {David J.} and Barrett, {Anthony G.M.} and Hoffman, {Brian M.}",

year = "1994",

doi = "10.1039/C39940002095",

language = "English",

pages = "2095--2096",

number = "18",

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Mani, NS, Beall, LS, Miller, T, Anderson, OP, Hope, H, Parkin, SR, Williams, DJ, Barrett, AGM & Hoffman, BM 1994, 'Synthesis and characterisation of porphyrazinoctamine derivatives: X-ray crystallographic studies of [2,3,7,8,12,13,17,18-octakis(dibenzylamino)- porphyrazinato]magnesium(II) and {2,3,7,8,12,13,17,18-octakis[allyl(benzyl) amino]-porphyrazinato}nickel(II)', Chemical Communications, no. 18, pp. 2095-2096. https://doi.org/10.1039/C39940002095

Synthesis and characterisation of porphyrazinoctamine derivatives: X-ray crystallographic studies of [2,3,7,8,12,13,17,18-octakis(dibenzylamino)- porphyrazinato]magnesium(II) and {2,3,7,8,12,13,17,18-octakis[allyl(benzyl) amino]-porphyrazinato}nickel(II). / Mani, Neelakandha S.; Beall, L. Scott; Miller, Todd et al.
In: Chemical Communications, No. 18, 1994, p. 2095-2096.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Synthesis and characterisation of porphyrazinoctamine derivatives

T2 - X-ray crystallographic studies of [2,3,7,8,12,13,17,18-octakis(dibenzylamino)- porphyrazinato]magnesium(II) and {2,3,7,8,12,13,17,18-octakis[allyl(benzyl) amino]-porphyrazinato}nickel(II)

AU - Mani, Neelakandha S.

AU - Beall, L. Scott

AU - Miller, Todd

AU - Anderson, Oren P.

AU - Hope, Håkon

AU - Parkin, Sean R.

AU - Williams, David J.

AU - Barrett, Anthony G.M.

AU - Hoffman, Brian M.

PY - 1994

Y1 - 1994

N2 - 2,3-Bis(dibenzylamino)- and 2,3-bis[allyl(benzyl)amino]-2Z-butene-1,4- dinitriles are macrocyclised by reaction with magnesium propoxide in propanol to provide the corresponding (porphyrazinato)magnesium(II) derivatives, the structures of which are confirmed by X-ray crystallographic studies of the title magnesium and nickel(II) complexes; cyclisation of alternative diaminomaleonitrile derivatives gives the corresponding porphyrazinoctamines.

AB - 2,3-Bis(dibenzylamino)- and 2,3-bis[allyl(benzyl)amino]-2Z-butene-1,4- dinitriles are macrocyclised by reaction with magnesium propoxide in propanol to provide the corresponding (porphyrazinato)magnesium(II) derivatives, the structures of which are confirmed by X-ray crystallographic studies of the title magnesium and nickel(II) complexes; cyclisation of alternative diaminomaleonitrile derivatives gives the corresponding porphyrazinoctamines.

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Mani NS, Beall LS, Miller T, Anderson OP, Hope H, Parkin SR et al. Synthesis and characterisation of porphyrazinoctamine derivatives: X-ray crystallographic studies of [2,3,7,8,12,13,17,18-octakis(dibenzylamino)- porphyrazinato]magnesium(II) and {2,3,7,8,12,13,17,18-octakis[allyl(benzyl) amino]-porphyrazinato}nickel(II). Chemical Communications. 1994;(18):2095-2096. doi: 10.1039/C39940002095

Synthesis and characterisation of porphyrazinoctamine derivatives: X-ray crystallographic studies of [2,3,7,8,12,13,17,18-octakis(dibenzylamino)- porphyrazinato]magnesium(II) and {2,3,7,8,12,13,17,18-octakis[allyl(benzyl) amino]-porphyrazinato}nickel(II)

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