Synthesis and characterization of a 1,2-dibenzoylruthenocene and a derived pyridazine

Chad E. Wallace; John P. Selegue; Alberto Carrillo

doi:10.1021/om980209+

Synthesis and characterization of a 1,2-dibenzoylruthenocene and a derived pyridazine

Chad E. Wallace, John P. Selegue, Alberto Carrillo

Chemistry

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Abstract

The reaction of 1-benzoyl-6-hydroxy-6-phenylfulvene with thallous ethoxide results in the formation of [Tl{1,2-C₅H₃(COPh)₂}]. Subsequent reaction with [Ru(μ₃-Cl)(Cp*)]₄ gives [Ru{η⁵-1,2-C₅H₃(COPh) ₂}(Cp*)] (3, 79%). Treatment of 3 with hydrazine monohydrate results in the formation of the pyridazine [Ru{η⁵-1,2-C₅H₃(CPh)₂N ₂}(Cp*)] (6, 73%). The structures of 3 and 6 have been determined by X-ray crystallography.

Original language	English
Pages (from-to)	3390-3393
Number of pages	4
Journal	Organometallics
Volume	17
Issue number	15
DOIs	https://doi.org/10.1021/om980209+
State	Published - Jul 20 1998

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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title = "Synthesis and characterization of a 1,2-dibenzoylruthenocene and a derived pyridazine",

abstract = "The reaction of 1-benzoyl-6-hydroxy-6-phenylfulvene with thallous ethoxide results in the formation of [Tl{1,2-C5H3(COPh)2}]. Subsequent reaction with [Ru(μ3-Cl)(Cp*)]4 gives [Ru{η5-1,2-C5H3(COPh) 2}(Cp*)] (3, 79%). Treatment of 3 with hydrazine monohydrate results in the formation of the pyridazine [Ru{η5-1,2-C5H3(CPh)2N 2}(Cp*)] (6, 73%). The structures of 3 and 6 have been determined by X-ray crystallography.",

author = "Wallace, {Chad E.} and Selegue, {John P.} and Alberto Carrillo",

year = "1998",

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doi = "10.1021/om980209+",

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T1 - Synthesis and characterization of a 1,2-dibenzoylruthenocene and a derived pyridazine

AU - Wallace, Chad E.

AU - Selegue, John P.

AU - Carrillo, Alberto

PY - 1998/7/20

Y1 - 1998/7/20

N2 - The reaction of 1-benzoyl-6-hydroxy-6-phenylfulvene with thallous ethoxide results in the formation of [Tl{1,2-C5H3(COPh)2}]. Subsequent reaction with [Ru(μ3-Cl)(Cp*)]4 gives [Ru{η5-1,2-C5H3(COPh) 2}(Cp*)] (3, 79%). Treatment of 3 with hydrazine monohydrate results in the formation of the pyridazine [Ru{η5-1,2-C5H3(CPh)2N 2}(Cp*)] (6, 73%). The structures of 3 and 6 have been determined by X-ray crystallography.

AB - The reaction of 1-benzoyl-6-hydroxy-6-phenylfulvene with thallous ethoxide results in the formation of [Tl{1,2-C5H3(COPh)2}]. Subsequent reaction with [Ru(μ3-Cl)(Cp*)]4 gives [Ru{η5-1,2-C5H3(COPh) 2}(Cp*)] (3, 79%). Treatment of 3 with hydrazine monohydrate results in the formation of the pyridazine [Ru{η5-1,2-C5H3(CPh)2N 2}(Cp*)] (6, 73%). The structures of 3 and 6 have been determined by X-ray crystallography.

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Synthesis and characterization of a 1,2-dibenzoylruthenocene and a derived pyridazine

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