Synthesis and crystal structure of 2-chloro-1-(3-hydroxyphenyl)ethanone

Prabhakar Priyanka; Bidarur K. Jayanna; Vinaya; Holehundi J. Shankara Prasad; Thayamma R. Divakara; Hemmige S. Yathirajan; Sean Parkin

doi:10.1107/S2056989022009835

Synthesis and crystal structure of 2-chloro-1-(3-hydroxyphenyl)ethanone

Prabhakar Priyanka, Bidarur K. Jayanna, Vinaya, Holehundi J. Shankara Prasad, Thayamma R. Divakara, Hemmige S. Yathirajan, Sean Parkin

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

The structure of 2-chloro-1-(3-hydroxyphenyl)ethanone, C₈H₇ClO₂, an α-haloketone is described. The molecule is planar (r.m.s. deviation = 0.0164 Å) and in the crystal, inversion-symmetric dimers are formed as a result of pairs of strong O—H. . .O and weak C—H. . .O hydrogen bonds. A brief comparison is made with structurally related compounds deposited in the CSD. In addition, the synthesis and some spectroscopic details are presented.

Original language	English
Pages (from-to)	1127-1130
Number of pages	4
Journal	Acta Crystallographica Section E: Crystallographic Communications
Volume	78
Issue number	11
DOIs	https://doi.org/10.1107/S2056989022009835
State	Published - Nov 1 2022

Bibliographical note

Publisher Copyright:
© 2022 International Union of Crystallography. All rights reserved.

Keywords

chlorinated acetophenone
crystal structure
α-haloketone

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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10.1107/S2056989022009835

Cite this

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title = "Synthesis and crystal structure of 2-chloro-1-(3-hydroxyphenyl)ethanone",

abstract = "The structure of 2-chloro-1-(3-hydroxyphenyl)ethanone, C8H7ClO2, an α-haloketone is described. The molecule is planar (r.m.s. deviation = 0.0164 {\AA}) and in the crystal, inversion-symmetric dimers are formed as a result of pairs of strong O—H. . .O and weak C—H. . .O hydrogen bonds. A brief comparison is made with structurally related compounds deposited in the CSD. In addition, the synthesis and some spectroscopic details are presented.",

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TY - JOUR

T1 - Synthesis and crystal structure of 2-chloro-1-(3-hydroxyphenyl)ethanone

AU - Priyanka, Prabhakar

AU - Jayanna, Bidarur K.

AU - Vinaya,

AU - Shankara Prasad, Holehundi J.

AU - Divakara, Thayamma R.

AU - Yathirajan, Hemmige S.

AU - Parkin, Sean

PY - 2022/11/1

Y1 - 2022/11/1

N2 - The structure of 2-chloro-1-(3-hydroxyphenyl)ethanone, C8H7ClO2, an α-haloketone is described. The molecule is planar (r.m.s. deviation = 0.0164 Å) and in the crystal, inversion-symmetric dimers are formed as a result of pairs of strong O—H. . .O and weak C—H. . .O hydrogen bonds. A brief comparison is made with structurally related compounds deposited in the CSD. In addition, the synthesis and some spectroscopic details are presented.

AB - The structure of 2-chloro-1-(3-hydroxyphenyl)ethanone, C8H7ClO2, an α-haloketone is described. The molecule is planar (r.m.s. deviation = 0.0164 Å) and in the crystal, inversion-symmetric dimers are formed as a result of pairs of strong O—H. . .O and weak C—H. . .O hydrogen bonds. A brief comparison is made with structurally related compounds deposited in the CSD. In addition, the synthesis and some spectroscopic details are presented.

KW - chlorinated acetophenone

KW - crystal structure

KW - α-haloketone

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U2 - 10.1107/S2056989022009835

DO - 10.1107/S2056989022009835

M3 - Article

AN - SCOPUS:85153343345

SN - 2056-9890

VL - 78

SP - 1127

EP - 1130

JO - Acta Crystallographica Section E: Crystallographic Communications

JF - Acta Crystallographica Section E: Crystallographic Communications

IS - 11

ER -

Synthesis and crystal structure of 2-chloro-1-(3-hydroxyphenyl)ethanone

Abstract

Bibliographical note

Keywords

ASJC Scopus subject areas

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