Synthesis and crystal structure of 2-chloro-1-(3-hydroxyphenyl)ethanone

Prabhakar Priyanka; Bidarur K. Jayanna; Vinaya; Holehundi J. Shankara Prasad; Thayamma R. Divakara; Hemmige S. Yathirajan; Sean Parkin

doi:10.1107/S2056989022009835

Synthesis and crystal structure of 2-chloro-1-(3-hydroxyphenyl)ethanone

Prabhakar Priyanka
, Bidarur K. Jayanna
, Vinaya
, Holehundi J. Shankara Prasad
, Thayamma R. Divakara
, Hemmige S. Yathirajan
, Sean Parkin

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

The structure of 2-chloro-1-(3-hydroxyphenyl)ethanone, C₈H₇ClO₂, an α-haloketone is described. The molecule is planar (r.m.s. deviation = 0.0164 Å) and in the crystal, inversion-symmetric dimers are formed as a result of pairs of strong O—H. . .O and weak C—H. . .O hydrogen bonds. A brief comparison is made with structurally related compounds deposited in the CSD. In addition, the synthesis and some spectroscopic details are presented.

Original language	English
Pages (from-to)	1127-1130
Number of pages	4
Journal	Acta Crystallographica Section E: Crystallographic Communications
Volume	78
Issue number	11
DOIs	https://doi.org/10.1107/S2056989022009835
State	Published - Nov 1 2022

Bibliographical note

Publisher Copyright:
© 2022 International Union of Crystallography. All rights reserved.

Funding

HSY is grateful to UGC, New Delhi for a BSR Faculty Fellowship for three years. Funding for this research was provided by: NSF (MRI CHE1625732) and the University of Kentucky (Bruker D8 Venture diffractometer).

Funders	Funder number
National Science Foundation Arctic Social Science Program	MRI CHE1625732
National Science Foundation Arctic Social Science Program
University of Kentucky
University Grants Commission

Keywords

chlorinated acetophenone
crystal structure
α-haloketone

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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10.1107/S2056989022009835

Cite this

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title = "Synthesis and crystal structure of 2-chloro-1-(3-hydroxyphenyl)ethanone",

abstract = "The structure of 2-chloro-1-(3-hydroxyphenyl)ethanone, C8H7ClO2, an α-haloketone is described. The molecule is planar (r.m.s. deviation = 0.0164 {\AA}) and in the crystal, inversion-symmetric dimers are formed as a result of pairs of strong O—H. . .O and weak C—H. . .O hydrogen bonds. A brief comparison is made with structurally related compounds deposited in the CSD. In addition, the synthesis and some spectroscopic details are presented.",

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language = "English",

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T1 - Synthesis and crystal structure of 2-chloro-1-(3-hydroxyphenyl)ethanone

AU - Priyanka, Prabhakar

AU - Jayanna, Bidarur K.

AU - Vinaya,

AU - Shankara Prasad, Holehundi J.

AU - Divakara, Thayamma R.

AU - Yathirajan, Hemmige S.

AU - Parkin, Sean

PY - 2022/11/1

Y1 - 2022/11/1

N2 - The structure of 2-chloro-1-(3-hydroxyphenyl)ethanone, C8H7ClO2, an α-haloketone is described. The molecule is planar (r.m.s. deviation = 0.0164 Å) and in the crystal, inversion-symmetric dimers are formed as a result of pairs of strong O—H. . .O and weak C—H. . .O hydrogen bonds. A brief comparison is made with structurally related compounds deposited in the CSD. In addition, the synthesis and some spectroscopic details are presented.

AB - The structure of 2-chloro-1-(3-hydroxyphenyl)ethanone, C8H7ClO2, an α-haloketone is described. The molecule is planar (r.m.s. deviation = 0.0164 Å) and in the crystal, inversion-symmetric dimers are formed as a result of pairs of strong O—H. . .O and weak C—H. . .O hydrogen bonds. A brief comparison is made with structurally related compounds deposited in the CSD. In addition, the synthesis and some spectroscopic details are presented.

KW - chlorinated acetophenone

KW - crystal structure

KW - α-haloketone

UR - https://www.scopus.com/pages/publications/85153343345

UR - https://www.scopus.com/pages/publications/85153343345#tab=citedBy

U2 - 10.1107/S2056989022009835

DO - 10.1107/S2056989022009835

M3 - Article

AN - SCOPUS:85153343345

SN - 2056-9890

VL - 78

SP - 1127

EP - 1130

JO - Acta Crystallographica Section E: Crystallographic Communications

JF - Acta Crystallographica Section E: Crystallographic Communications

IS - 11

ER -

Synthesis and crystal structure of 2-chloro-1-(3-hydroxyphenyl)ethanone

Abstract

Bibliographical note

Funding

Keywords

ASJC Scopus subject areas

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