Synthesis and Nanofiltration Membrane Performance of Oriented Mesoporous Silica Thin Films on Macroporous Supports

M. Kaitlyn Clark Wooten, Venkat R. Koganti, Shanshan Zhou, Stephen E. Rankin, Barbara L. Knutson

Research output: Contribution to journalArticlepeer-review

32 Scopus citations


Silica thin films with accessible hexagonal close-packed (HCP) pores have been deposited on macroporous supports to achieve composite nanofiltration membranes. The properties of these pore channels have been characterized through solvent flux and solute diffusion experiments. A chemically neutral surface (provided by a cross-linked layer of P123 copolymer) for silica thin film synthesis on the alumina macroporous support promotes the alignment of HCP channels vertical to the substrate, where the mesopore templating agent is block copolymer P123 (poly(ethylene glycol)-block-poly(propylene glycol)-block-poly(ethylene glycol)). Vertical pore alignment is achieved for thin films (less than ∼100 nm) on a neutral surface and by sandwiching thicker films (∼240 nm) between two chemically neutral surfaces. Solvent flux through the composite membranes is consistent with accessible 10 nm diameter pores. Size selectivity of the membranes is characterized from the permeability of fluorescently tagged solutes (ranging from 4000 to 70 000 Da), where a size cut off occurs at 69 000 Da for the model protein bovine serum albumin. These permeability studies of the nanofiltration membranes serve to demonstrate solute transport in oriented silica thin film membranes and also highlight their versatility for membrane-based separations.

Original languageEnglish
Pages (from-to)21806-21815
Number of pages10
JournalACS Applied Materials and Interfaces
Issue number33
StatePublished - Aug 24 2016

Bibliographical note

Funding Information:
EEC-0851716, the United States Department of Agriculture Biomass Research and Development Initiative (BRDI) grant (award no.2011-10006-30363), Kentucky Science and Engineering Foundation (KSEF-2929-RDE-016), and Kentucky NSF Experimental Program to Stimulate Competitive Research EPSCoR grant (grant no. 1355438)

Publisher Copyright:
© 2016 American Chemical Society.


  • ceramic membranes
  • mesoporous silica
  • oriented pores
  • self-assembly
  • size selective

ASJC Scopus subject areas

  • Materials Science (all)


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