Synthesis and reactivity of well-characterized low-valent titanium species

Folami Ladipo

doi:10.1080/02603590600767138

Synthesis and reactivity of well-characterized low-valent titanium species

Folami Ladipo

Research output: Contribution to journal › Review article › peer-review

7 Scopus citations

Abstract

This account mainly describes results from studies in our laboratory of the reactivity of well-characterized titanium(II) species, supported by chelating bis(aryloxide) ligation, with unsaturated organic compounds, including alkynes, aldehydes, and ketones. Taken together with reported chemistry of related low-valent titanium complexes, our results serve to advance current understanding of the nature of the active species and mechanism(s) of alkyne cyclotrimerization, pinacol coupling, and McMurry reactions.

Original language	English
Pages (from-to)	73-102
Number of pages	30
Journal	Comments on Inorganic Chemistry
Volume	27
Issue number	3-4
DOIs	https://doi.org/10.1080/02603590600767138
State	Published - Aug 1 2006

Bibliographical note

Funding Information:
Thanks are expressed to the US National Science Foundation (grant numbers CHE-9984776 and CHE-0416098) for financial support of our research program in low-valent titanium chemistry.

Funding

Thanks are expressed to the US National Science Foundation (grant numbers CHE-9984776 and CHE-0416098) for financial support of our research program in low-valent titanium chemistry.

Funders	Funder number
US National Science Foundation	CHE-9984776, CHE-0416098

ASJC Scopus subject areas

Inorganic Chemistry

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10.1080/02603590600767138

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title = "Synthesis and reactivity of well-characterized low-valent titanium species",

abstract = "This account mainly describes results from studies in our laboratory of the reactivity of well-characterized titanium(II) species, supported by chelating bis(aryloxide) ligation, with unsaturated organic compounds, including alkynes, aldehydes, and ketones. Taken together with reported chemistry of related low-valent titanium complexes, our results serve to advance current understanding of the nature of the active species and mechanism(s) of alkyne cyclotrimerization, pinacol coupling, and McMurry reactions.",

author = "Folami Ladipo",

note = "Funding Information: Thanks are expressed to the US National Science Foundation (grant numbers CHE-9984776 and CHE-0416098) for financial support of our research program in low-valent titanium chemistry.",

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AU - Ladipo, Folami

N1 - Funding Information: Thanks are expressed to the US National Science Foundation (grant numbers CHE-9984776 and CHE-0416098) for financial support of our research program in low-valent titanium chemistry.

PY - 2006/8/1

Y1 - 2006/8/1

N2 - This account mainly describes results from studies in our laboratory of the reactivity of well-characterized titanium(II) species, supported by chelating bis(aryloxide) ligation, with unsaturated organic compounds, including alkynes, aldehydes, and ketones. Taken together with reported chemistry of related low-valent titanium complexes, our results serve to advance current understanding of the nature of the active species and mechanism(s) of alkyne cyclotrimerization, pinacol coupling, and McMurry reactions.

AB - This account mainly describes results from studies in our laboratory of the reactivity of well-characterized titanium(II) species, supported by chelating bis(aryloxide) ligation, with unsaturated organic compounds, including alkynes, aldehydes, and ketones. Taken together with reported chemistry of related low-valent titanium complexes, our results serve to advance current understanding of the nature of the active species and mechanism(s) of alkyne cyclotrimerization, pinacol coupling, and McMurry reactions.

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UR - https://www.scopus.com/pages/publications/33745166616#tab=citedBy

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DO - 10.1080/02603590600767138

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JO - Comments on Inorganic Chemistry

JF - Comments on Inorganic Chemistry

IS - 3-4

ER -

Synthesis and reactivity of well-characterized low-valent titanium species

Abstract

Bibliographical note

Funding

ASJC Scopus subject areas

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