Synthesis and structural characterisation of tripodal titanium silsesquioxane complexes: A new class of highly active catalysts for liquid phase alkene epoxidation

Mark Crocker; Ruud H.M. Herold; A. Guy Orpen

doi:10.1039/a704969b

Synthesis and structural characterisation of tripodal titanium silsesquioxane complexes: A new class of highly active catalysts for liquid phase alkene epoxidation

Mark Crocker, Ruud H.M. Herold, A. Guy Orpen

Chemistry

Research output: Contribution to journal › Article › peer-review

117 Scopus citations

Abstract

Titanium silsesquioxane complexes [Ti(L)(R₇Si₇O₁₂)], possessing tripodal geometry, represent models for heterogeneous titanosilicate catalysts; the new complexes are exceptionally active and selective catalysts for liquid phase alkene epoxidation reactions.

Original language	English
Pages (from-to)	2411-2412
Number of pages	2
Journal	Chemical Communications
Issue number	24
DOIs	https://doi.org/10.1039/a704969b
State	Published - 1997

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/a704969b

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title = "Synthesis and structural characterisation of tripodal titanium silsesquioxane complexes: A new class of highly active catalysts for liquid phase alkene epoxidation",

abstract = "Titanium silsesquioxane complexes [Ti(L)(R7Si7O12)], possessing tripodal geometry, represent models for heterogeneous titanosilicate catalysts; the new complexes are exceptionally active and selective catalysts for liquid phase alkene epoxidation reactions.",

author = "Mark Crocker and Herold, {Ruud H.M.} and Orpen, {A. Guy}",

year = "1997",

doi = "10.1039/a704969b",

language = "English",

pages = "2411--2412",

number = "24",

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T2 - A new class of highly active catalysts for liquid phase alkene epoxidation

AU - Crocker, Mark

AU - Herold, Ruud H.M.

AU - Orpen, A. Guy

PY - 1997

Y1 - 1997

N2 - Titanium silsesquioxane complexes [Ti(L)(R7Si7O12)], possessing tripodal geometry, represent models for heterogeneous titanosilicate catalysts; the new complexes are exceptionally active and selective catalysts for liquid phase alkene epoxidation reactions.

AB - Titanium silsesquioxane complexes [Ti(L)(R7Si7O12)], possessing tripodal geometry, represent models for heterogeneous titanosilicate catalysts; the new complexes are exceptionally active and selective catalysts for liquid phase alkene epoxidation reactions.

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U2 - 10.1039/a704969b

DO - 10.1039/a704969b

M3 - Article

AN - SCOPUS:0002101714

SN - 1359-7345

SP - 2411

EP - 2412

JO - Chemical Communications

JF - Chemical Communications

IS - 24

ER -

Synthesis and structural characterisation of tripodal titanium silsesquioxane complexes: A new class of highly active catalysts for liquid phase alkene epoxidation

Abstract

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