Synthesis and structural characterisation of tripodal titanium silsesquioxane complexes: A new class of highly active catalysts for liquid phase alkene epoxidation

Mark Crocker, Ruud H.M. Herold, A. Guy Orpen

Research output: Contribution to journalArticlepeer-review

114 Scopus citations

Abstract

Titanium silsesquioxane complexes [Ti(L)(R7Si7O12)], possessing tripodal geometry, represent models for heterogeneous titanosilicate catalysts; the new complexes are exceptionally active and selective catalysts for liquid phase alkene epoxidation reactions.

Original languageEnglish
Pages (from-to)2411-2412
Number of pages2
JournalChemical Communications
Issue number24
DOIs
StatePublished - 1997

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • General Chemistry
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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