Synthesis and structural characterization of bi- and trimetallic octacyanometalate(IV) complexes: [Δ,Λ-M(II)(en) (3)][cis-M(II)(en)(2)(OH(2))][M (IV)(CN)(8)]·2H(2)O and [cis-M (II)(en)(2)(OH(2))](2)[(μ-NC) (2)M(IV)(CN)(6)]·4H(2)O (M (II) = Mn, Co, Ni; M(IV) = Mo, W)

Jeffrey R. Withers; Chad Ruschmann; Pasano Bojang; Sean Parkin; Stephen M. Holmes

doi:10.1021/ic048936m

Synthesis and structural characterization of bi- and trimetallic octacyanometalate(IV) complexes: [Δ,Λ-M(II)(en) (3)][cis-M(II)(en)(2)(OH(2))][M (IV)(CN)(8)]·2H(2)O and [cis-M (II)(en)(2)(OH(2))](2)[(μ-NC) (2)M(IV)(CN)(6)]·4H(2)O (M (II) = Mn, Co, Ni; M(IV) = Mo, W)

Jeffrey R. Withers, Chad Ruschmann, Pasano Bojang, Sean Parkin, Stephen M. Holmes

Chemistry

Research output: Contribution to journal › Article › peer-review

35 Scopus citations

Abstract

Treatment of [M^II(en)₃][OTs]₂ or methanolic ethylenediamine solutions containing transition metal p-toluenesulfonates (M^II = Mn, Co) with aqueous K₄M ^IV(CN)₈·2H₂O or Cs₃M ^V(CN)₈ (M^IV = Mo, W; M^V = Mo) affords crystalline clusters of [M^II(en)₃][cis-M ^II(en)₂(OH₂)(μ-NC)M^IV(CN) ₇]·2H₂O (M^IV = Mo; M^II = Mn, 1; Ni, 5; M^IV = W; M^II = Mn, 2; Ni, 6) and [cis-M ^II(en)₂(OH₂)]₂[(μ-NC) ₂M^IV(CN)₆]·4H₂O (M ^IV = Mo; M^II = Co, 3; Ni, 7; M^IV = W; M ^II = Co, 4) stoichiometry. Each cluster contains cis-M ^II(en)₂(OH₂)(μ-NC)²⁺ units that likely result from dissociative loss of en from [M^II(en) ₃]²⁺, affording cis-M^II(en)₂(OH ₂)₂²⁺ intermediates that are trapped by M ^IV(CN)₈^4-.

Original language	English
Pages (from-to)	352-358
Number of pages	7
Journal	Inorganic Chemistry
Volume	44
Issue number	2
DOIs	https://doi.org/10.1021/ic048936m
State	Published - Jan 24 2005

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry

Access to Document

10.1021/ic048936m

Fingerprint

Dive into the research topics of 'Synthesis and structural characterization of bi- and trimetallic octacyanometalate(IV) complexes: [Δ,Λ-M(II)(en) (3)][cis-M(II)(en)(2)(OH(2))][M (IV)(CN)(8)]·2H(2)O and [cis-M (II)(en)(2)(OH(2))](2)[(μ-NC) (2)M(IV)(CN)(6)]·4H(2)O (M (II) = Mn, Co, Ni; M(IV) = Mo, W)'. Together they form a unique fingerprint.

Cite this

Withers, J. R., Ruschmann, C., Bojang, P., Parkin, S., & Holmes, S. M. (2005). Synthesis and structural characterization of bi- and trimetallic octacyanometalate(IV) complexes: [Δ,Λ-M(II)(en) (3)][cis-M(II)(en)(2)(OH(2))][M (IV)(CN)(8)]·2H(2)O and [cis-M (II)(en)(2)(OH(2))](2)[(μ-NC) (2)M(IV)(CN)(6)]·4H(2)O (M (II) = Mn, Co, Ni; M(IV) = Mo, W). Inorganic Chemistry, 44(2), 352-358. https://doi.org/10.1021/ic048936m

Withers, Jeffrey R. ; Ruschmann, Chad ; Bojang, Pasano et al. / Synthesis and structural characterization of bi- and trimetallic octacyanometalate(IV) complexes : [Δ,Λ-M(II)(en) (3)][cis-M(II)(en)(2)(OH(2))][M (IV)(CN)(8)]·2H(2)O and [cis-M (II)(en)(2)(OH(2))](2)[(μ-NC) (2)M(IV)(CN)(6)]·4H(2)O (M (II) = Mn, Co, Ni; M(IV) = Mo, W). In: Inorganic Chemistry. 2005 ; Vol. 44, No. 2. pp. 352-358.

@article{38ec924ffa424c37ab1536281ad0afa2,

title = "Synthesis and structural characterization of bi- and trimetallic octacyanometalate(IV) complexes: [Δ,Λ-M(II)(en) (3)][cis-M(II)(en)(2)(OH(2))][M (IV)(CN)(8)]·2H(2)O and [cis-M (II)(en)(2)(OH(2))](2)[(μ-NC) (2)M(IV)(CN)(6)]·4H(2)O (M (II) = Mn, Co, Ni; M(IV) = Mo, W)",

abstract = "Treatment of [MII(en)3][OTs]2 or methanolic ethylenediamine solutions containing transition metal p-toluenesulfonates (MII = Mn, Co) with aqueous K4M IV(CN)8·2H2O or Cs3M V(CN)8 (MIV = Mo, W; MV = Mo) affords crystalline clusters of [MII(en)3][cis-M II(en)2(OH2)(μ-NC)MIV(CN) 7]·2H2O (MIV = Mo; MII = Mn, 1; Ni, 5; MIV = W; MII = Mn, 2; Ni, 6) and [cis-M II(en)2(OH2)]2[(μ-NC) 2MIV(CN)6]·4H2O (M IV = Mo; MII = Co, 3; Ni, 7; MIV = W; M II = Co, 4) stoichiometry. Each cluster contains cis-M II(en)2(OH2)(μ-NC)2+ units that likely result from dissociative loss of en from [MII(en) 3]2+, affording cis-MII(en)2(OH 2)22+ intermediates that are trapped by M IV(CN)84-.",

author = "Withers, {Jeffrey R.} and Chad Ruschmann and Pasano Bojang and Sean Parkin and Holmes, {Stephen M.}",

year = "2005",

month = jan,

day = "24",

doi = "10.1021/ic048936m",

language = "English",

volume = "44",

pages = "352--358",

number = "2",

}

Withers, JR, Ruschmann, C, Bojang, P, Parkin, S & Holmes, SM 2005, 'Synthesis and structural characterization of bi- and trimetallic octacyanometalate(IV) complexes: [Δ,Λ-M(II)(en) (3)][cis-M(II)(en)(2)(OH(2))][M (IV)(CN)(8)]·2H(2)O and [cis-M (II)(en)(2)(OH(2))](2)[(μ-NC) (2)M(IV)(CN)(6)]·4H(2)O (M (II) = Mn, Co, Ni; M(IV) = Mo, W)', Inorganic Chemistry, vol. 44, no. 2, pp. 352-358. https://doi.org/10.1021/ic048936m

Synthesis and structural characterization of bi- and trimetallic octacyanometalate(IV) complexes: [Δ,Λ-M(II)(en) (3)][cis-M(II)(en)(2)(OH(2))][M (IV)(CN)(8)]·2H(2)O and [cis-M (II)(en)(2)(OH(2))](2)[(μ-NC) (2)M(IV)(CN)(6)]·4H(2)O (M (II) = Mn, Co, Ni; M(IV) = Mo, W). / Withers, Jeffrey R.; Ruschmann, Chad; Bojang, Pasano et al.
In: Inorganic Chemistry, Vol. 44, No. 2, 24.01.2005, p. 352-358.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Synthesis and structural characterization of bi- and trimetallic octacyanometalate(IV) complexes

T2 - [Δ,Λ-M(II)(en) (3)][cis-M(II)(en)(2)(OH(2))][M (IV)(CN)(8)]·2H(2)O and [cis-M (II)(en)(2)(OH(2))](2)[(μ-NC) (2)M(IV)(CN)(6)]·4H(2)O (M (II) = Mn, Co, Ni; M(IV) = Mo, W)

AU - Withers, Jeffrey R.

AU - Ruschmann, Chad

AU - Bojang, Pasano

AU - Parkin, Sean

AU - Holmes, Stephen M.

PY - 2005/1/24

Y1 - 2005/1/24

N2 - Treatment of [MII(en)3][OTs]2 or methanolic ethylenediamine solutions containing transition metal p-toluenesulfonates (MII = Mn, Co) with aqueous K4M IV(CN)8·2H2O or Cs3M V(CN)8 (MIV = Mo, W; MV = Mo) affords crystalline clusters of [MII(en)3][cis-M II(en)2(OH2)(μ-NC)MIV(CN) 7]·2H2O (MIV = Mo; MII = Mn, 1; Ni, 5; MIV = W; MII = Mn, 2; Ni, 6) and [cis-M II(en)2(OH2)]2[(μ-NC) 2MIV(CN)6]·4H2O (M IV = Mo; MII = Co, 3; Ni, 7; MIV = W; M II = Co, 4) stoichiometry. Each cluster contains cis-M II(en)2(OH2)(μ-NC)2+ units that likely result from dissociative loss of en from [MII(en) 3]2+, affording cis-MII(en)2(OH 2)22+ intermediates that are trapped by M IV(CN)84-.

AB - Treatment of [MII(en)3][OTs]2 or methanolic ethylenediamine solutions containing transition metal p-toluenesulfonates (MII = Mn, Co) with aqueous K4M IV(CN)8·2H2O or Cs3M V(CN)8 (MIV = Mo, W; MV = Mo) affords crystalline clusters of [MII(en)3][cis-M II(en)2(OH2)(μ-NC)MIV(CN) 7]·2H2O (MIV = Mo; MII = Mn, 1; Ni, 5; MIV = W; MII = Mn, 2; Ni, 6) and [cis-M II(en)2(OH2)]2[(μ-NC) 2MIV(CN)6]·4H2O (M IV = Mo; MII = Co, 3; Ni, 7; MIV = W; M II = Co, 4) stoichiometry. Each cluster contains cis-M II(en)2(OH2)(μ-NC)2+ units that likely result from dissociative loss of en from [MII(en) 3]2+, affording cis-MII(en)2(OH 2)22+ intermediates that are trapped by M IV(CN)84-.

UR - http://www.scopus.com/inward/record.url?scp=12444304405&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=12444304405&partnerID=8YFLogxK

U2 - 10.1021/ic048936m

DO - 10.1021/ic048936m

M3 - Article

AN - SCOPUS:12444304405

SN - 0020-1669

VL - 44

SP - 352

EP - 358

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 2

ER -

Withers JR, Ruschmann C, Bojang P, Parkin S, Holmes SM. Synthesis and structural characterization of bi- and trimetallic octacyanometalate(IV) complexes: [Δ,Λ-M(II)(en) (3)][cis-M(II)(en)(2)(OH(2))][M (IV)(CN)(8)]·2H(2)O and [cis-M (II)(en)(2)(OH(2))](2)[(μ-NC) (2)M(IV)(CN)(6)]·4H(2)O (M (II) = Mn, Co, Ni; M(IV) = Mo, W). Inorganic Chemistry. 2005 Jan 24;44(2):352-358. doi: 10.1021/ic048936m

Synthesis and structural characterization of bi- and trimetallic octacyanometalate(IV) complexes: [Δ,Λ-M(II)(en) (3)][cis-M(II)(en)(2)(OH(2))][M (IV)(CN)(8)]·2H(2)O and [cis-M (II)(en)(2)(OH(2))](2)[(μ-NC) (2)M(IV)(CN)(6)]·4H(2)O (M (II) = Mn, Co, Ni; M(IV) = Mo, W)

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this