Synthesis and structural characterization of crystalline nonacenes

Balaji Purushothaman; Matthew Bruzek; Sean R. Parkin; Anne Frances Miller; John E. Anthony

doi:10.1002/anie.201102671

Synthesis and structural characterization of crystalline nonacenes

Balaji Purushothaman, Matthew Bruzek, Sean R. Parkin, Anne Frances Miller, John E. Anthony

Research output: Contribution to journal › Article › peer-review

214 Scopus citations

Abstract

Nine in a line: A multifaceted approach, including a silylethylene functionalization strategy, to the synthesis of stable nonacene derivatives (see picture, F green, Si blue) allows an unprecedented level of characterization, including electrochemical, photophysical, and crystallographic studies. The nonacenes show a strong S₀-S₁ transition and no fluorescence in the visible region.

Original language	English
Pages (from-to)	7013-7017
Number of pages	5
Journal	Angewandte Chemie International Edition in English
Volume	50
Issue number	31
DOIs	https://doi.org/10.1002/anie.201102671
State	Published - Jul 25 2011

Keywords

acenes
alkynes
aromatic compounds
organic materials

ASJC Scopus subject areas

Catalysis
Chemistry (all)

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10.1002/anie.201102671

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abstract = "Nine in a line: A multifaceted approach, including a silylethylene functionalization strategy, to the synthesis of stable nonacene derivatives (see picture, F green, Si blue) allows an unprecedented level of characterization, including electrochemical, photophysical, and crystallographic studies. The nonacenes show a strong S0-S1 transition and no fluorescence in the visible region.",

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AU - Bruzek, Matthew

AU - Parkin, Sean R.

AU - Miller, Anne Frances

AU - Anthony, John E.

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AB - Nine in a line: A multifaceted approach, including a silylethylene functionalization strategy, to the synthesis of stable nonacene derivatives (see picture, F green, Si blue) allows an unprecedented level of characterization, including electrochemical, photophysical, and crystallographic studies. The nonacenes show a strong S0-S1 transition and no fluorescence in the visible region.

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KW - alkynes

KW - aromatic compounds

KW - organic materials

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Synthesis and structural characterization of crystalline nonacenes

Abstract

Keywords

ASJC Scopus subject areas

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