Synthesis and structural characterization of crystalline nonacenes

Balaji Purushothaman; Matthew Bruzek; Sean R. Parkin; Anne Frances Miller; John E. Anthony

doi:10.1002/anie.201102671

Synthesis and structural characterization of crystalline nonacenes

Balaji Purushothaman
, Matthew Bruzek
, Sean R. Parkin
, Anne Frances Miller
, John E. Anthony

Research output: Contribution to journal › Article › peer-review

241 Scopus citations

Abstract

Nine in a line: A multifaceted approach, including a silylethylene functionalization strategy, to the synthesis of stable nonacene derivatives (see picture, F green, Si blue) allows an unprecedented level of characterization, including electrochemical, photophysical, and crystallographic studies. The nonacenes show a strong S₀-S₁ transition and no fluorescence in the visible region.

Original language	English
Pages (from-to)	7013-7017
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	50
Issue number	31
DOIs	https://doi.org/10.1002/anie.201102671
State	Published - Jul 25 2011

Keywords

acenes
alkynes
aromatic compounds
organic materials

ASJC Scopus subject areas

Catalysis
General Chemistry

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10.1002/anie.201102671

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abstract = "Nine in a line: A multifaceted approach, including a silylethylene functionalization strategy, to the synthesis of stable nonacene derivatives (see picture, F green, Si blue) allows an unprecedented level of characterization, including electrochemical, photophysical, and crystallographic studies. The nonacenes show a strong S0-S1 transition and no fluorescence in the visible region.",

keywords = "acenes, alkynes, aromatic compounds, organic materials",

author = "Balaji Purushothaman and Matthew Bruzek and Parkin, \{Sean R.\} and Miller, \{Anne Frances\} and Anthony, \{John E.\}",

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AU - Purushothaman, Balaji

AU - Bruzek, Matthew

AU - Parkin, Sean R.

AU - Miller, Anne Frances

AU - Anthony, John E.

PY - 2011/7/25

Y1 - 2011/7/25

N2 - Nine in a line: A multifaceted approach, including a silylethylene functionalization strategy, to the synthesis of stable nonacene derivatives (see picture, F green, Si blue) allows an unprecedented level of characterization, including electrochemical, photophysical, and crystallographic studies. The nonacenes show a strong S0-S1 transition and no fluorescence in the visible region.

AB - Nine in a line: A multifaceted approach, including a silylethylene functionalization strategy, to the synthesis of stable nonacene derivatives (see picture, F green, Si blue) allows an unprecedented level of characterization, including electrochemical, photophysical, and crystallographic studies. The nonacenes show a strong S0-S1 transition and no fluorescence in the visible region.

KW - acenes

KW - alkynes

KW - aromatic compounds

KW - organic materials

UR - https://www.scopus.com/pages/publications/79960621039

UR - https://www.scopus.com/pages/publications/79960621039#tab=citedBy

U2 - 10.1002/anie.201102671

DO - 10.1002/anie.201102671

M3 - Article

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AN - SCOPUS:79960621039

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VL - 50

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JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 31

ER -

Synthesis and structural characterization of crystalline nonacenes

Abstract

Keywords

ASJC Scopus subject areas

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