Synthesis and Structure of a C2-Symmetric, Doubly Bridged ansa-Titanocene Complex

Robert B. Grossman; Jing Cherng Tsai; William M. Davis; Alberto Gutiérrez; Stephen L. Buchwald

doi:10.1021/om00022a026

Synthesis and Structure of a C₂-Symmetric, Doubly Bridged ansa-Titanocene Complex

Robert B. Grossman, Jing Cherng Tsai, William M. Davis, Alberto Gutiérrez, Stephen L. Buchwald

Chemistry

Research output: Contribution to journal › Article › peer-review

45 Scopus citations

Abstract

A chiral, doubly bridged ansa-titanocene complex with C₂ symmetry has been synthesized in four steps from bicyclo[3.3.1 ]nonane-2,6-dione. The design of the complex precludes the formation of meso or C₁ diastereomers or conformers.

Original language	English
Pages (from-to)	3892-3896
Number of pages	5
Journal	Organometallics
Volume	13
Issue number	10
DOIs	https://doi.org/10.1021/om00022a026
State	Published - Oct 1 1994

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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10.1021/om00022a026

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title = "Synthesis and Structure of a C2-Symmetric, Doubly Bridged ansa-Titanocene Complex",

abstract = "A chiral, doubly bridged ansa-titanocene complex with C2 symmetry has been synthesized in four steps from bicyclo[3.3.1 ]nonane-2,6-dione. The design of the complex precludes the formation of meso or C1 diastereomers or conformers.",

author = "Grossman, \{Robert B.\} and Tsai, \{Jing Cherng\} and Davis, \{William M.\} and Alberto Guti{\'e}rrez and Buchwald, \{Stephen L.\}",

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AU - Grossman, Robert B.

AU - Tsai, Jing Cherng

AU - Davis, William M.

AU - Gutiérrez, Alberto

AU - Buchwald, Stephen L.

PY - 1994/10/1

Y1 - 1994/10/1

N2 - A chiral, doubly bridged ansa-titanocene complex with C2 symmetry has been synthesized in four steps from bicyclo[3.3.1 ]nonane-2,6-dione. The design of the complex precludes the formation of meso or C1 diastereomers or conformers.

AB - A chiral, doubly bridged ansa-titanocene complex with C2 symmetry has been synthesized in four steps from bicyclo[3.3.1 ]nonane-2,6-dione. The design of the complex precludes the formation of meso or C1 diastereomers or conformers.

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Synthesis and Structure of a C₂-Symmetric, Doubly Bridged ansa-Titanocene Complex

Abstract

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