Synthesis and Structure of [Ru(C3Ph2)(PMe3)2(Cp)][PF6], a Cationic Diphenylallenylldene Complex

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Abstract

The electron-rich complex [RuCl(PMe3)2(Cp)] reacts with the alkynol Ph2C(OH)(C≡CH) and NH4PF6 to produce the novel diphenylallenylidene complex [Ru(η1-C=C=CPh2)(PMe3)2(Cp)] [PF6]. An X-ray structural determination reveals a nearly linear metallacumulene chain with a short (1.884 (5) Å) ruthenium-carbon bond.

Original languageEnglish
Pages (from-to)217-218
Number of pages2
JournalOrganometallics
Volume1
Issue number1
DOIs
StatePublished - 1982

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

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