Synthesis and structures of two bulky gallium chlorides

David A. Atwood; Alan H. Cowley; Richard A. Jones; Miguel A. Mardones; Jerry L. Atwood; Simon G. Bott

doi:10.1080/00958979209409196

Synthesis and structures of two bulky gallium chlorides

David A. Atwood
, Alan H. Cowley
, Richard A. Jones
, Miguel A. Mardones
, Jerry L. Atwood
, Simon G. Bott

Research output: Contribution to journal › Article › peer-review

19 Scopus citations

Abstract

The bulky gallium chlorides, (t-BuGaCl₂)₂ (1) and (Cy₂GaCl₂), (Cy = C₆H₁₁) have been prepared via the reaction of GaC3₃, with I-BuLi and CyMgCl, respectively. The structures of 1 and 2 have been determined by X-ray methods. Crystals of 1 are monoclinic, space group P2₁/c, with a = 6.937(4), b = 6.877(5), c = 17.1l(1)Å, β = 95.65(6)°, Z = 2; crystals of 2 are monoclinic, space group P2₁,/c, with a = 10.389(2), b = 11.580(3), c = 11.198(2)Å = 95.96(2)°, Z = 2. The R values for 1 and 2 are 0.0617 and 0.0681, respectively. The solid state structures of 1 and 2 consist of chloride-bridged dimers.

Original language	English
Pages (from-to)	233-239
Number of pages	7
Journal	Journal of Coordination Chemistry
Volume	25
Issue number	3
DOIs	https://doi.org/10.1080/00958979209409196
State	Published - Jan 1 1992

Keywords

Gallium(III)
X-ray structure
cyclohexyl
synthesis
t-butyl

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Materials Chemistry

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10.1080/00958979209409196

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@article{f2db981ad728438b861033b6fe6649b4,

title = "Synthesis and structures of two bulky gallium chlorides",

abstract = "The bulky gallium chlorides, (t-BuGaCl2)2 (1) and (Cy2GaCl2), (Cy = C6H11) have been prepared via the reaction of GaC33, with I-BuLi and CyMgCl, respectively. The structures of 1 and 2 have been determined by X-ray methods. Crystals of 1 are monoclinic, space group P21/c, with a = 6.937(4), b = 6.877(5), c = 17.1l(1){\AA}, β = 95.65(6)°, Z = 2; crystals of 2 are monoclinic, space group P21,/c, with a = 10.389(2), b = 11.580(3), c = 11.198(2){\AA} = 95.96(2)°, Z = 2. The R values for 1 and 2 are 0.0617 and 0.0681, respectively. The solid state structures of 1 and 2 consist of chloride-bridged dimers.",

keywords = "Gallium(III), X-ray structure, cyclohexyl, synthesis, t-butyl",

author = "Atwood, \{David A.\} and Cowley, \{Alan H.\} and Jones, \{Richard A.\} and Mardones, \{Miguel A.\} and Atwood, \{Jerry L.\} and Bott, \{Simon G.\}",

year = "1992",

month = jan,

day = "1",

doi = "10.1080/00958979209409196",

language = "English",

volume = "25",

pages = "233--239",

number = "3",

}

TY - JOUR

T1 - Synthesis and structures of two bulky gallium chlorides

AU - Atwood, David A.

AU - Cowley, Alan H.

AU - Jones, Richard A.

AU - Mardones, Miguel A.

AU - Atwood, Jerry L.

AU - Bott, Simon G.

PY - 1992/1/1

Y1 - 1992/1/1

N2 - The bulky gallium chlorides, (t-BuGaCl2)2 (1) and (Cy2GaCl2), (Cy = C6H11) have been prepared via the reaction of GaC33, with I-BuLi and CyMgCl, respectively. The structures of 1 and 2 have been determined by X-ray methods. Crystals of 1 are monoclinic, space group P21/c, with a = 6.937(4), b = 6.877(5), c = 17.1l(1)Å, β = 95.65(6)°, Z = 2; crystals of 2 are monoclinic, space group P21,/c, with a = 10.389(2), b = 11.580(3), c = 11.198(2)Å = 95.96(2)°, Z = 2. The R values for 1 and 2 are 0.0617 and 0.0681, respectively. The solid state structures of 1 and 2 consist of chloride-bridged dimers.

AB - The bulky gallium chlorides, (t-BuGaCl2)2 (1) and (Cy2GaCl2), (Cy = C6H11) have been prepared via the reaction of GaC33, with I-BuLi and CyMgCl, respectively. The structures of 1 and 2 have been determined by X-ray methods. Crystals of 1 are monoclinic, space group P21/c, with a = 6.937(4), b = 6.877(5), c = 17.1l(1)Å, β = 95.65(6)°, Z = 2; crystals of 2 are monoclinic, space group P21,/c, with a = 10.389(2), b = 11.580(3), c = 11.198(2)Å = 95.96(2)°, Z = 2. The R values for 1 and 2 are 0.0617 and 0.0681, respectively. The solid state structures of 1 and 2 consist of chloride-bridged dimers.

KW - Gallium(III)

KW - X-ray structure

KW - cyclohexyl

KW - synthesis

KW - t-butyl

UR - https://www.scopus.com/pages/publications/0000547116

UR - https://www.scopus.com/pages/publications/0000547116#tab=citedBy

U2 - 10.1080/00958979209409196

DO - 10.1080/00958979209409196

M3 - Article

AN - SCOPUS:0000547116

SN - 0095-8972

VL - 25

SP - 233

EP - 239

JO - Journal of Coordination Chemistry

JF - Journal of Coordination Chemistry

IS - 3

ER -

Synthesis and structures of two bulky gallium chlorides

Abstract

Keywords

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