Synthesis and X-ray characterization of a polymeric 1:3 complex of copper(II) nitrate with pyrazine

Tom Otieno; Ann M. Gipson; Sean Parkin

doi:10.1023/A:1015612810446

Synthesis and X-ray characterization of a polymeric 1:3 complex of copper(II) nitrate with pyrazine

Tom Otieno, Ann M. Gipson, Sean Parkin

Chemistry

Research output: Contribution to journal › Article › peer-review

16 Scopus citations

Abstract

The structure of poly-μ-pyrazine-bis(pyrazine)(dinitrato-O)copper(II), Cu(pyz)₃(NO₃)₂, has been investigated by X-ray diffraction. The compound crystallizes in the triclinic space group P1 with a = 6.8040 (10), b = 7.2860 (10), c = 9.289 (2) Å, α = 69.65 (2), β = 68.51 (2), γ = 67.51 (2)°, and Z = 1. The structure consists of linear chains of copper ions bridged by bidentate pyrazine groups, with monodentate terminal pyrazine and nitrate groups completing the distorted octahedral geometry about the copper ions.

Original language	English
Pages (from-to)	81-85
Number of pages	5
Journal	Journal of Chemical Crystallography
Volume	32
Issue number	3-4
DOIs	https://doi.org/10.1023/A:1015612810446
State	Published - 2002

Bibliographical note

Funding Information:
This work was supported by Eastern Kentucky University.

Funding

This work was supported by Eastern Kentucky University.

Funders	Funder number
Eastern Kentucky, University

Keywords

Coordination polymer
Copper(II)
Pyrazine

ASJC Scopus subject areas

General Chemistry
Condensed Matter Physics

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10.1023/A:1015612810446

Cite this

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title = "Synthesis and X-ray characterization of a polymeric 1:3 complex of copper(II) nitrate with pyrazine",

abstract = "The structure of poly-μ-pyrazine-bis(pyrazine)(dinitrato-O)copper(II), Cu(pyz)3(NO3)2, has been investigated by X-ray diffraction. The compound crystallizes in the triclinic space group P1 with a = 6.8040 (10), b = 7.2860 (10), c = 9.289 (2) {\AA}, α = 69.65 (2), β = 68.51 (2), γ = 67.51 (2)°, and Z = 1. The structure consists of linear chains of copper ions bridged by bidentate pyrazine groups, with monodentate terminal pyrazine and nitrate groups completing the distorted octahedral geometry about the copper ions.",

keywords = "Coordination polymer, Copper(II), Pyrazine",

author = "Tom Otieno and Gipson, \{Ann M.\} and Sean Parkin",

note = "Funding Information: This work was supported by Eastern Kentucky University.",

year = "2002",

doi = "10.1023/A:1015612810446",

language = "English",

volume = "32",

pages = "81--85",

number = "3-4",

}

TY - JOUR

T1 - Synthesis and X-ray characterization of a polymeric 1:3 complex of copper(II) nitrate with pyrazine

AU - Otieno, Tom

AU - Gipson, Ann M.

AU - Parkin, Sean

N1 - Funding Information: This work was supported by Eastern Kentucky University.

PY - 2002

Y1 - 2002

N2 - The structure of poly-μ-pyrazine-bis(pyrazine)(dinitrato-O)copper(II), Cu(pyz)3(NO3)2, has been investigated by X-ray diffraction. The compound crystallizes in the triclinic space group P1 with a = 6.8040 (10), b = 7.2860 (10), c = 9.289 (2) Å, α = 69.65 (2), β = 68.51 (2), γ = 67.51 (2)°, and Z = 1. The structure consists of linear chains of copper ions bridged by bidentate pyrazine groups, with monodentate terminal pyrazine and nitrate groups completing the distorted octahedral geometry about the copper ions.

AB - The structure of poly-μ-pyrazine-bis(pyrazine)(dinitrato-O)copper(II), Cu(pyz)3(NO3)2, has been investigated by X-ray diffraction. The compound crystallizes in the triclinic space group P1 with a = 6.8040 (10), b = 7.2860 (10), c = 9.289 (2) Å, α = 69.65 (2), β = 68.51 (2), γ = 67.51 (2)°, and Z = 1. The structure consists of linear chains of copper ions bridged by bidentate pyrazine groups, with monodentate terminal pyrazine and nitrate groups completing the distorted octahedral geometry about the copper ions.

KW - Coordination polymer

KW - Copper(II)

KW - Pyrazine

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U2 - 10.1023/A:1015612810446

DO - 10.1023/A:1015612810446

M3 - Article

AN - SCOPUS:0036270316

SN - 1074-1542

VL - 32

SP - 81

EP - 85

JO - Journal of Chemical Crystallography

JF - Journal of Chemical Crystallography

IS - 3-4

ER -

Synthesis and X-ray characterization of a polymeric 1:3 complex of copper(II) nitrate with pyrazine

Abstract

Bibliographical note

Funding

Keywords

ASJC Scopus subject areas

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