Synthesis, characterization, and applications of group 13 cationic compounds

Samuel Dagorne; David A. Atwood

doi:10.1021/cr078351k

Synthesis, characterization, and applications of group 13 cationic compounds

Samuel Dagorne, David A. Atwood

Research output: Contribution to journal › Article › peer-review

145 Citations (SciVal)

Abstract

Six-coordinate aluminum cations (and related neutral derivatives) supported by Salen and porphyrin ligands have now become widely used for catalytic applications including propylene oxide polymerization and a wide range of carbonylation reactions. These applications rely on the stable environment provided by the ligands and the Lewis acidity of the cations. In the carbonylation reactions, added Lewis basic ligands are needed to mitigate the cationic charge on the aluminum atom.

Original language	English
Pages (from-to)	4037-4071
Number of pages	35
Journal	Chemical Reviews
Volume	108
Issue number	10
DOIs	https://doi.org/10.1021/cr078351k
State	Published - Oct 2008

ASJC Scopus subject areas

General Chemistry

Access to Document

10.1021/cr078351k

Cite this

@article{e83b2dd4658b491b8256c1d51f7a3b7c,

title = "Synthesis, characterization, and applications of group 13 cationic compounds",

abstract = "Six-coordinate aluminum cations (and related neutral derivatives) supported by Salen and porphyrin ligands have now become widely used for catalytic applications including propylene oxide polymerization and a wide range of carbonylation reactions. These applications rely on the stable environment provided by the ligands and the Lewis acidity of the cations. In the carbonylation reactions, added Lewis basic ligands are needed to mitigate the cationic charge on the aluminum atom.",

author = "Samuel Dagorne and Atwood, {David A.}",

year = "2008",

month = oct,

doi = "10.1021/cr078351k",

language = "English",

volume = "108",

pages = "4037--4071",

number = "10",

}

TY - JOUR

T1 - Synthesis, characterization, and applications of group 13 cationic compounds

AU - Dagorne, Samuel

AU - Atwood, David A.

PY - 2008/10

Y1 - 2008/10

N2 - Six-coordinate aluminum cations (and related neutral derivatives) supported by Salen and porphyrin ligands have now become widely used for catalytic applications including propylene oxide polymerization and a wide range of carbonylation reactions. These applications rely on the stable environment provided by the ligands and the Lewis acidity of the cations. In the carbonylation reactions, added Lewis basic ligands are needed to mitigate the cationic charge on the aluminum atom.

AB - Six-coordinate aluminum cations (and related neutral derivatives) supported by Salen and porphyrin ligands have now become widely used for catalytic applications including propylene oxide polymerization and a wide range of carbonylation reactions. These applications rely on the stable environment provided by the ligands and the Lewis acidity of the cations. In the carbonylation reactions, added Lewis basic ligands are needed to mitigate the cationic charge on the aluminum atom.

UR - http://www.scopus.com/inward/record.url?scp=54849404485&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=54849404485&partnerID=8YFLogxK

U2 - 10.1021/cr078351k

DO - 10.1021/cr078351k

M3 - Article

C2 - 18817357

AN - SCOPUS:54849404485

SN - 0009-2665

VL - 108

SP - 4037

EP - 4071

JO - Chemical Reviews

JF - Chemical Reviews

IS - 10

ER -

Synthesis, characterization, and applications of group 13 cationic compounds

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this