Synthesis of a remarkably stable dehydro[14]annulene

Grant J. Palmer; Sean R. Parkin; John E. Anthony

doi:10.1002/1521-3773(20010702)40:13<2509::AID-ANIE2509>3.0.CO;2-F

Synthesis of a remarkably stable dehydro[14]annulene

Grant J. Palmer, Sean R. Parkin, John E. Anthony

Chemistry

Research output: Contribution to journal › Article › peer-review

17 Scopus citations

Abstract

The substituents at the peri positions of dehydro[14]annulenes 1 have a dramatic effect on the stability of these macrocycles, and lead to derivatives that are stable even at elevated temperatures (up to 190°C).

Original language	English
Pages (from-to)	2509-2512
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	40
Issue number	13
DOIs	https://doi.org/10.1002/1521-3773(20010702)40:13<2509::AID-ANIE2509>3.0.CO;2-F
State	Published - Jul 2 2001

Keywords

Alkynes
Annulenes
Conjugation
Macrocycles

ASJC Scopus subject areas

Catalysis
Chemistry (all)

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10.1002/1521-3773(20010702)40:13<2509::AID-ANIE2509>3.0.CO;2-F

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title = "Synthesis of a remarkably stable dehydro[14]annulene",

abstract = "The substituents at the peri positions of dehydro[14]annulenes 1 have a dramatic effect on the stability of these macrocycles, and lead to derivatives that are stable even at elevated temperatures (up to 190°C).",

keywords = "Alkynes, Annulenes, Conjugation, Macrocycles",

author = "Palmer, {Grant J.} and Parkin, {Sean R.} and Anthony, {John E.}",

year = "2001",

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AU - Parkin, Sean R.

AU - Anthony, John E.

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N2 - The substituents at the peri positions of dehydro[14]annulenes 1 have a dramatic effect on the stability of these macrocycles, and lead to derivatives that are stable even at elevated temperatures (up to 190°C).

AB - The substituents at the peri positions of dehydro[14]annulenes 1 have a dramatic effect on the stability of these macrocycles, and lead to derivatives that are stable even at elevated temperatures (up to 190°C).

KW - Alkynes

KW - Annulenes

KW - Conjugation

KW - Macrocycles

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U2 - 10.1002/1521-3773(20010702)40:13<2509::AID-ANIE2509>3.0.CO;2-F

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Synthesis of a remarkably stable dehydro[14]annulene

Abstract

Keywords

ASJC Scopus subject areas

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