Synthesis of Biological Markers in Fossil Fuels. 2. Synthesis and 13C NMR Studies of Substituted Indans and Tetralins

Maciej Adamczyk; David S. Watt; Daniel A. Netzel

doi:10.1021/jo00196a024

Synthesis of Biological Markers in Fossil Fuels. 2. Synthesis and 13C NMR Studies of Substituted Indans and Tetralins

Maciej Adamczyk, David S. Watt, Daniel A. Netzel

Molecular and Cellular Biochemistry

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Abstract

Unambiguous syntheses of all possible methyl, ethyl, n-propyl, and n-butyl derivatives of indan and tetralin were developed using the Kumada coupling procedure involving the reaction of aryl or vinyl halides with Grignard reagents in the presence of [l, 3-bis(diphenylphosphino)propyl]nickel(II) chloride. An analysis of the ¹³C NMR spectra of these compounds was also completed.

Original language	English
Pages (from-to)	4226-4237
Number of pages	12
Journal	Journal of Organic Chemistry
Volume	49
Issue number	22
DOIs	https://doi.org/10.1021/jo00196a024
State	Published - Feb 1984

ASJC Scopus subject areas

Organic Chemistry

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10.1021/jo00196a024

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title = "Synthesis of Biological Markers in Fossil Fuels. 2. Synthesis and 13C NMR Studies of Substituted Indans and Tetralins",

abstract = "Unambiguous syntheses of all possible methyl, ethyl, n-propyl, and n-butyl derivatives of indan and tetralin were developed using the Kumada coupling procedure involving the reaction of aryl or vinyl halides with Grignard reagents in the presence of [l, 3-bis(diphenylphosphino)propyl]nickel(II) chloride. An analysis of the 13C NMR spectra of these compounds was also completed.",

author = "Maciej Adamczyk and Watt, {David S.} and Netzel, {Daniel A.}",

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T1 - Synthesis of Biological Markers in Fossil Fuels. 2. Synthesis and 13C NMR Studies of Substituted Indans and Tetralins

AU - Adamczyk, Maciej

AU - Watt, David S.

AU - Netzel, Daniel A.

PY - 1984/2

Y1 - 1984/2

N2 - Unambiguous syntheses of all possible methyl, ethyl, n-propyl, and n-butyl derivatives of indan and tetralin were developed using the Kumada coupling procedure involving the reaction of aryl or vinyl halides with Grignard reagents in the presence of [l, 3-bis(diphenylphosphino)propyl]nickel(II) chloride. An analysis of the 13C NMR spectra of these compounds was also completed.

AB - Unambiguous syntheses of all possible methyl, ethyl, n-propyl, and n-butyl derivatives of indan and tetralin were developed using the Kumada coupling procedure involving the reaction of aryl or vinyl halides with Grignard reagents in the presence of [l, 3-bis(diphenylphosphino)propyl]nickel(II) chloride. An analysis of the 13C NMR spectra of these compounds was also completed.

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Synthesis of Biological Markers in Fossil Fuels. 2. Synthesis and 13C NMR Studies of Substituted Indans and Tetralins

Abstract

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