Synthesis of the first diarsadigalletane

David A. Atwood; Alan H. Cowley; Richard A. Jones; Miguel A. Mardones

doi:10.1016/0022-328X(92)80234-O

Synthesis of the first diarsadigalletane

David A. Atwood, Alan H. Cowley, Richard A. Jones, Miguel A. Mardones

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Abstract

The diarsadigalletane [¹BuGaAsC₆H₃(CH₂NMe₂)₂] (1) has been prepared by treatment of [¹BuGaCl₂]₂ with Li₂AsC₆H₃(CH₂NMe₂)₂ in Et₂O solution. One of the Me₂N groups of each (Me₂NCH₂)₂C₆H₃ ring is coordinated to each of the gallium atoms in the As₂Ga₂ ring. Compound 1 is air and moisture stable.

Original language	English
Pages (from-to)	C33-C35
Journal	Journal of Organometallic Chemistry
Volume	439
Issue number	2
DOIs	https://doi.org/10.1016/0022-328X(92)80234-O
State	Published - Nov 3 1992

Bibliographical note

Funding Information:
Acknowledgements. We are grateful to the National Science Foundation and the Robert A. Welch Foundation for generousf inancial support.

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/0022-328X(92)80234-O

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@article{018e6af6614d4f3c94bcc73a4a625e67,

title = "Synthesis of the first diarsadigalletane",

abstract = "The diarsadigalletane [1BuGaAsC6H3(CH2NMe2)2] (1) has been prepared by treatment of [1BuGaCl2]2 with Li2AsC6H3(CH2NMe2)2 in Et2O solution. One of the Me2N groups of each (Me2NCH2)2C6H3 ring is coordinated to each of the gallium atoms in the As2Ga2 ring. Compound 1 is air and moisture stable.",

author = "Atwood, {David A.} and Cowley, {Alan H.} and Jones, {Richard A.} and Mardones, {Miguel A.}",

note = "Funding Information: Acknowledgements. We are grateful to the National Science Foundation and the Robert A. Welch Foundation for generousf inancial support.",

year = "1992",

month = nov,

day = "3",

doi = "10.1016/0022-328X(92)80234-O",

language = "English",

volume = "439",

pages = "C33--C35",

number = "2",

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TY - JOUR

T1 - Synthesis of the first diarsadigalletane

AU - Atwood, David A.

AU - Cowley, Alan H.

AU - Jones, Richard A.

AU - Mardones, Miguel A.

N1 - Funding Information: Acknowledgements. We are grateful to the National Science Foundation and the Robert A. Welch Foundation for generousf inancial support.

PY - 1992/11/3

Y1 - 1992/11/3

N2 - The diarsadigalletane [1BuGaAsC6H3(CH2NMe2)2] (1) has been prepared by treatment of [1BuGaCl2]2 with Li2AsC6H3(CH2NMe2)2 in Et2O solution. One of the Me2N groups of each (Me2NCH2)2C6H3 ring is coordinated to each of the gallium atoms in the As2Ga2 ring. Compound 1 is air and moisture stable.

AB - The diarsadigalletane [1BuGaAsC6H3(CH2NMe2)2] (1) has been prepared by treatment of [1BuGaCl2]2 with Li2AsC6H3(CH2NMe2)2 in Et2O solution. One of the Me2N groups of each (Me2NCH2)2C6H3 ring is coordinated to each of the gallium atoms in the As2Ga2 ring. Compound 1 is air and moisture stable.

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U2 - 10.1016/0022-328X(92)80234-O

DO - 10.1016/0022-328X(92)80234-O

M3 - Article

AN - SCOPUS:23944492622

SN - 0022-328X

VL - 439

SP - C33-C35

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 2

ER -

Synthesis of the first diarsadigalletane

Abstract

Bibliographical note

ASJC Scopus subject areas

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