Tetradentate -N2O2 ligand complexes of Tin(II). X-ray crystal structure of [N,N′-(1,2-ethylene) bis (salicylaldamine)]tin(II), (SaleanH2Sn)

David A. Atwood, Jolin A. Jegier, Kyli J. Martin, Drew Rutherford

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33 Scopus citations

Abstract

The tetradentate -N2O2 ligands, [N,N′-(1,2-ethylenebis(salicylaldamine)] (SaleanH4 (1), [N,N′-(1,3-propylene)bis(salicylaldamine)](SalpanH4 (2)and [N,N′-(1,2-phenylenebis(salicylaldamine)] (SalophanH4) 3, were used to prepare Sn(II) complexes that are monomeric (SaleanH2Sn (7), SalpanH2Sn (8)) and dimeric ([SalophanH2Sn]2) (9)). The structure of 7 was determined by single-crystal X-ray crystallography: orthorhombic, space pbcn with a = 19.849(4), b = 10.791(3), c = 18.559(5) A ̊ and Z = 8. Compounds 8 and 9 undergo transmetallation reactions with three equivalents of AlMe3 to produce the trimetallic derivatives, SalpanAlMe(Alme2)2 (10) and SalophanAlMe(AlMe2)2 (11).

Original languageEnglish
Pages (from-to)C4-C7
JournalJournal of Organometallic Chemistry
Volume503
Issue number1
DOIs
StatePublished - Nov 1 1995

Bibliographical note

Funding Information:
Gratitude is expressed to the National Science Foundation (Grant RII-861075) and the NDSU Grant-in-Aid program for generous financial support.

Keywords

  • Aluminium
  • Tin
  • Transmetallation

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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