Tetradentate -N2O2 ligand complexes of Tin(II). X-ray crystal structure of [N,N′-(1,2-ethylene) bis (salicylaldamine)]tin(II), (SaleanH2Sn)

David A. Atwood; Jolin A. Jegier; Kyli J. Martin; Drew Rutherford

doi:10.1016/0022-328X(95)05666-D

Tetradentate -N₂O₂ ligand complexes of Tin(II). X-ray crystal structure of [N,N′-(1,2-ethylene) bis (salicylaldamine)]tin(II), (SaleanH₂Sn)

David A. Atwood, Jolin A. Jegier, Kyli J. Martin, Drew Rutherford

Research output: Contribution to journal › Article › peer-review

34 Scopus citations

Abstract

The tetradentate -N₂O₂ ligands, [N,N′-(1,2-ethylenebis(salicylaldamine)] (SaleanH₄ (1), [N,N′-(1,3-propylene)bis(salicylaldamine)](SalpanH₄ (2)and [N,N′-(1,2-phenylenebis(salicylaldamine)] (SalophanH₄) 3, were used to prepare Sn(II) complexes that are monomeric (SaleanH₂Sn (7), SalpanH₂Sn (8)) and dimeric ([SalophanH₂Sn]₂) (9)). The structure of 7 was determined by single-crystal X-ray crystallography: orthorhombic, space pbcn with a = 19.849(4), b = 10.791(3), c = 18.559(5) A ̊ and Z = 8. Compounds 8 and 9 undergo transmetallation reactions with three equivalents of AlMe₃ to produce the trimetallic derivatives, SalpanAlMe(Alme₂)₂ (10) and SalophanAlMe(AlMe₂)₂ (11).

Original language	English
Pages (from-to)	C4-C7
Journal	Journal of Organometallic Chemistry
Volume	503
Issue number	1
DOIs	https://doi.org/10.1016/0022-328X(95)05666-D
State	Published - Nov 1 1995

Bibliographical note

Funding Information:
Gratitude is expressed to the National Science Foundation (Grant RII-861075) and the NDSU Grant-in-Aid program for generous financial support.

Keywords

Aluminium
Tin
Transmetallation

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

Access to Document

10.1016/0022-328X(95)05666-D

Cite this

@article{24952192f0e5474589c830f186541006,

title = "Tetradentate -N2O2 ligand complexes of Tin(II). X-ray crystal structure of [N,N′-(1,2-ethylene) bis (salicylaldamine)]tin(II), (SaleanH2Sn)",

abstract = "The tetradentate -N2O2 ligands, [N,N′-(1,2-ethylenebis(salicylaldamine)] (SaleanH4 (1), [N,N′-(1,3-propylene)bis(salicylaldamine)](SalpanH4 (2)and [N,N′-(1,2-phenylenebis(salicylaldamine)] (SalophanH4) 3, were used to prepare Sn(II) complexes that are monomeric (SaleanH2Sn (7), SalpanH2Sn (8)) and dimeric ([SalophanH2Sn]2) (9)). The structure of 7 was determined by single-crystal X-ray crystallography: orthorhombic, space pbcn with a = 19.849(4), b = 10.791(3), c = 18.559(5) A ̊ and Z = 8. Compounds 8 and 9 undergo transmetallation reactions with three equivalents of AlMe3 to produce the trimetallic derivatives, SalpanAlMe(Alme2)2 (10) and SalophanAlMe(AlMe2)2 (11).",

keywords = "Aluminium, Tin, Transmetallation",

author = "Atwood, {David A.} and Jegier, {Jolin A.} and Martin, {Kyli J.} and Drew Rutherford",

note = "Funding Information: Gratitude is expressed to the National Science Foundation (Grant RII-861075) and the NDSU Grant-in-Aid program for generous financial support.",

year = "1995",

month = nov,

day = "1",

doi = "10.1016/0022-328X(95)05666-D",

language = "English",

volume = "503",

pages = "C4--C7",

number = "1",

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TY - JOUR

T1 - Tetradentate -N2O2 ligand complexes of Tin(II). X-ray crystal structure of [N,N′-(1,2-ethylene) bis (salicylaldamine)]tin(II), (SaleanH2Sn)

AU - Atwood, David A.

AU - Jegier, Jolin A.

AU - Martin, Kyli J.

AU - Rutherford, Drew

N1 - Funding Information: Gratitude is expressed to the National Science Foundation (Grant RII-861075) and the NDSU Grant-in-Aid program for generous financial support.

PY - 1995/11/1

Y1 - 1995/11/1

N2 - The tetradentate -N2O2 ligands, [N,N′-(1,2-ethylenebis(salicylaldamine)] (SaleanH4 (1), [N,N′-(1,3-propylene)bis(salicylaldamine)](SalpanH4 (2)and [N,N′-(1,2-phenylenebis(salicylaldamine)] (SalophanH4) 3, were used to prepare Sn(II) complexes that are monomeric (SaleanH2Sn (7), SalpanH2Sn (8)) and dimeric ([SalophanH2Sn]2) (9)). The structure of 7 was determined by single-crystal X-ray crystallography: orthorhombic, space pbcn with a = 19.849(4), b = 10.791(3), c = 18.559(5) A ̊ and Z = 8. Compounds 8 and 9 undergo transmetallation reactions with three equivalents of AlMe3 to produce the trimetallic derivatives, SalpanAlMe(Alme2)2 (10) and SalophanAlMe(AlMe2)2 (11).

AB - The tetradentate -N2O2 ligands, [N,N′-(1,2-ethylenebis(salicylaldamine)] (SaleanH4 (1), [N,N′-(1,3-propylene)bis(salicylaldamine)](SalpanH4 (2)and [N,N′-(1,2-phenylenebis(salicylaldamine)] (SalophanH4) 3, were used to prepare Sn(II) complexes that are monomeric (SaleanH2Sn (7), SalpanH2Sn (8)) and dimeric ([SalophanH2Sn]2) (9)). The structure of 7 was determined by single-crystal X-ray crystallography: orthorhombic, space pbcn with a = 19.849(4), b = 10.791(3), c = 18.559(5) A ̊ and Z = 8. Compounds 8 and 9 undergo transmetallation reactions with three equivalents of AlMe3 to produce the trimetallic derivatives, SalpanAlMe(Alme2)2 (10) and SalophanAlMe(AlMe2)2 (11).

KW - Aluminium

KW - Tin

KW - Transmetallation

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