TY - JOUR
T1 - Tetraethylammonium tris(thiocyanato-κN)[tris(1H-pyrazol-1-yl- κN2)methane]nickelate(II)
AU - Lyubartseva, Ganna
AU - Parkin, Sean
AU - Mallik, Uma Prasad
AU - Jeon, Hee Kyung
PY - 2012/7
Y1 - 2012/7
N2 - The title salt, (C8H20N)[Ni(NCS)3(C 10H10N6)], consists of a tetraethylammonium cation and an anion comprising an octahedral NiII atom surrounded by three N atoms from a tripodal tris(pyrazol-1-yl)methane ligand, and three thiocyanate ligands, each bound at the N-atom end. The ligand Ni - N distances range from 2.097 (2) to 2.127 (2) Å for the tripodal ligand and from 2.045 (2) to 2.075 (2) Å for the thiocyanate ligands. The dihedral angles between the three pyrazole rings are 59.03 (12), 53.09 (10) and 67.90 (10)°.
AB - The title salt, (C8H20N)[Ni(NCS)3(C 10H10N6)], consists of a tetraethylammonium cation and an anion comprising an octahedral NiII atom surrounded by three N atoms from a tripodal tris(pyrazol-1-yl)methane ligand, and three thiocyanate ligands, each bound at the N-atom end. The ligand Ni - N distances range from 2.097 (2) to 2.127 (2) Å for the tripodal ligand and from 2.045 (2) to 2.075 (2) Å for the thiocyanate ligands. The dihedral angles between the three pyrazole rings are 59.03 (12), 53.09 (10) and 67.90 (10)°.
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U2 - 10.1107/S1600536812024774
DO - 10.1107/S1600536812024774
M3 - Article
C2 - 22807731
AN - SCOPUS:84863568757
SN - 1600-5368
VL - 68
SP - m888
JO - Acta Crystallographica Section E: Structure Reports Online
JF - Acta Crystallographica Section E: Structure Reports Online
IS - 7
ER -