Tetrametallic D3-symmetric alkoxide molecules containing aluminum

David A. Atwood

doi:10.1021/om980900c

Tetrametallic D3-symmetric alkoxide molecules containing aluminum

David A. Atwood

Research output: Contribution to journal › Article › peer-review

33 Scopus citations

Abstract

A new series of aluminum alkoxide molecules of formula [Al{(μ-OEt)₂AlR₂}₃], where R = Me (1), Et (2), ⁱBu (3), and [Al{(μ-OEt)₂GaR₂}₃], where R = Me (4) and Et (5), have been synthesized and fully characterized. In pure form 1, 2, and 4 are crystalline solids. However, in the presence of a small amount of solvent or impurity all of the compounds exist as oils. They were characterized by ¹H NMR, IR, elemental analysis, mp, and single-crystal X-ray diffractometry for compounds 1, 2, and 4.

Original language	English
Pages (from-to)	976-981
Number of pages	6
Journal	Organometallics
Volume	18
Issue number	6
DOIs	https://doi.org/10.1021/om980900c
State	Published - Mar 15 1999

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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10.1021/om980900c

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title = "Tetrametallic D3-symmetric alkoxide molecules containing aluminum",

abstract = "A new series of aluminum alkoxide molecules of formula [Al{(μ-OEt)2AlR2}3], where R = Me (1), Et (2), iBu (3), and [Al{(μ-OEt)2GaR2}3], where R = Me (4) and Et (5), have been synthesized and fully characterized. In pure form 1, 2, and 4 are crystalline solids. However, in the presence of a small amount of solvent or impurity all of the compounds exist as oils. They were characterized by 1H NMR, IR, elemental analysis, mp, and single-crystal X-ray diffractometry for compounds 1, 2, and 4.",

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doi = "10.1021/om980900c",

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T1 - Tetrametallic D3-symmetric alkoxide molecules containing aluminum

AU - Atwood, David A.

PY - 1999/3/15

Y1 - 1999/3/15

N2 - A new series of aluminum alkoxide molecules of formula [Al{(μ-OEt)2AlR2}3], where R = Me (1), Et (2), iBu (3), and [Al{(μ-OEt)2GaR2}3], where R = Me (4) and Et (5), have been synthesized and fully characterized. In pure form 1, 2, and 4 are crystalline solids. However, in the presence of a small amount of solvent or impurity all of the compounds exist as oils. They were characterized by 1H NMR, IR, elemental analysis, mp, and single-crystal X-ray diffractometry for compounds 1, 2, and 4.

AB - A new series of aluminum alkoxide molecules of formula [Al{(μ-OEt)2AlR2}3], where R = Me (1), Et (2), iBu (3), and [Al{(μ-OEt)2GaR2}3], where R = Me (4) and Et (5), have been synthesized and fully characterized. In pure form 1, 2, and 4 are crystalline solids. However, in the presence of a small amount of solvent or impurity all of the compounds exist as oils. They were characterized by 1H NMR, IR, elemental analysis, mp, and single-crystal X-ray diffractometry for compounds 1, 2, and 4.

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DO - 10.1021/om980900c

M3 - Article

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EP - 981

JO - Organometallics

JF - Organometallics

IS - 6

ER -

Tetrametallic D3-symmetric alkoxide molecules containing aluminum

Abstract

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