The preparation of 2-arylmethylidene-8-methyl-8-azabicyclo[3.2.1]octan-3- ones

Guangrong Zheng, Linda P. Dwoskin, Peter A. Crooks

Research output: Contribution to journalArticlepeer-review

9 Scopus citations

Abstract

An efficient and versatile two-step synthesis of 2-arylmethylidene-8- methyl-8-azabicyclo[3.2.1]octane-3-ones, via mono aldol condensation of tropinone with a variety of aryl aldehydes followed by pTsOH-catalyzed dehydration, is described.

Original languageEnglish
Pages (from-to)1931-1942
Number of pages12
JournalSynthetic Communications
Volume34
Issue number11
DOIs
StatePublished - 2004

Bibliographical note

Funding Information:
This research was supported by National Institute of Health grants DA13519 and DA00399. High resolution mass spectral determinations were carried out at the University of Kentucky Mass Spectrometry Facility.

Funding

This research was supported by National Institute of Health grants DA13519 and DA00399. High resolution mass spectral determinations were carried out at the University of Kentucky Mass Spectrometry Facility.

FundersFunder number
National Institute of Health National Institute of Minority and Health Disparities Loan Repayment ProgramDA13519, DA00399

    Keywords

    • Aldol condensation
    • CNS agents
    • THF
    • Tropane analogs

    ASJC Scopus subject areas

    • Organic Chemistry

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