The reactions of σ,η3-butadienylruthenium complexes with donor ligands and protons: Structures of [RuC(Ph)=C(Ph)-η2- {(Z)-C(Ph)=CH(Ph)} {P(OMe)3}(η-C5H5)] and [RuC(O)C(Ph)=C(Ph)-η2-{(Z)-C(Ph)=CH(Ph)} {P(OMe)3} (η-C5H5)]

Lee Brammer; Mark Crocker; Barry J. Dunne; Michael Green; Carolyn E. Morton; Katharine R. Nagle; A. Guy Orpen

doi:10.1039/C39860001226

The reactions of σ,η³-butadienylruthenium complexes with donor ligands and protons: Structures of [RuC(Ph)=C(Ph)-η²- {(Z)-C(Ph)=CH(Ph)} {P(OMe)₃}(η-C₅H₅)] and [RuC(O)C(Ph)=C(Ph)-η²-{(Z)-C(Ph)=CH(Ph)} {P(OMe)₃} (η-C₅H₅)]

Lee Brammer, Mark Crocker, Barry J. Dunne, Michael Green, Carolyn E. Morton, Katharine R. Nagle, A. Guy Orpen

Chemistry

Research output: Contribution to journal › Article › peer-review

18 Scopus citations

Abstract

σ,η³(5e)-Butadienylruthenium complexes behave as masked σ,η²(3e)-butadienyl complexes in their reactions with P(OMe)₃ and PhC₂Ph, whereas, protons react on the 'inside' of the σ,η³-butadienyl chain at the α-carbenoid carbon; attempts to expel P(OMe)₃ thermally from the resulting σ,η²(3e)-butadienyl complexes results instead in a zeta-H abstraction reaction.

Original language	English
Pages (from-to)	1226-1228
Number of pages	3
Journal	Chemical Communications
Issue number	15
DOIs	https://doi.org/10.1039/C39860001226
State	Published - 1986

ASJC Scopus subject areas

Molecular Medicine

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Brammer, L., Crocker, M., Dunne, B. J., Green, M., Morton, C. E., Nagle, K. R., & Orpen, A. G. (1986). The reactions of σ,η³-butadienylruthenium complexes with donor ligands and protons: Structures of [RuC(Ph)=C(Ph)-η²- {(Z)-C(Ph)=CH(Ph)} {P(OMe)₃}(η-C₅H₅)] and [RuC(O)C(Ph)=C(Ph)-η²-{(Z)-C(Ph)=CH(Ph)} {P(OMe)₃} (η-C₅H₅)]. Chemical Communications, (15), 1226-1228. https://doi.org/10.1039/C39860001226

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title = "The reactions of σ,η3-butadienylruthenium complexes with donor ligands and protons: Structures of [RuC(Ph)=C(Ph)-η2- {(Z)-C(Ph)=CH(Ph)} {P(OMe)3}(η-C5H5)] and [RuC(O)C(Ph)=C(Ph)-η2-{(Z)-C(Ph)=CH(Ph)} {P(OMe)3} (η-C5H5)]",

abstract = "σ,η3(5e)-Butadienylruthenium complexes behave as masked σ,η2(3e)-butadienyl complexes in their reactions with P(OMe)3 and PhC2Ph, whereas, protons react on the 'inside' of the σ,η3-butadienyl chain at the α-carbenoid carbon; attempts to expel P(OMe)3 thermally from the resulting σ,η2(3e)-butadienyl complexes results instead in a zeta-H abstraction reaction.",

author = "Lee Brammer and Mark Crocker and Dunne, {Barry J.} and Michael Green and Morton, {Carolyn E.} and Nagle, {Katharine R.} and Orpen, {A. Guy}",

year = "1986",

doi = "10.1039/C39860001226",

language = "English",

pages = "1226--1228",

number = "15",

}

Brammer, L, Crocker, M, Dunne, BJ, Green, M, Morton, CE, Nagle, KR & Orpen, AG 1986, 'The reactions of σ,η³-butadienylruthenium complexes with donor ligands and protons: Structures of [RuC(Ph)=C(Ph)-η²- {(Z)-C(Ph)=CH(Ph)} {P(OMe)₃}(η-C₅H₅)] and [RuC(O)C(Ph)=C(Ph)-η²-{(Z)-C(Ph)=CH(Ph)} {P(OMe)₃} (η-C₅H₅)]', Chemical Communications, no. 15, pp. 1226-1228. https://doi.org/10.1039/C39860001226

The reactions of σ,η³-butadienylruthenium complexes with donor ligands and protons: Structures of [RuC(Ph)=C(Ph)-η²- {(Z)-C(Ph)=CH(Ph)} {P(OMe)₃}(η-C₅H₅)] and [RuC(O)C(Ph)=C(Ph)-η²-{(Z)-C(Ph)=CH(Ph)} {P(OMe)₃} (η-C₅H₅)]. / Brammer, Lee; Crocker, Mark; Dunne, Barry J. et al.
In: Chemical Communications, No. 15, 1986, p. 1226-1228.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - The reactions of σ,η3-butadienylruthenium complexes with donor ligands and protons

T2 - Structures of [RuC(Ph)=C(Ph)-η2- {(Z)-C(Ph)=CH(Ph)} {P(OMe)3}(η-C5H5)] and [RuC(O)C(Ph)=C(Ph)-η2-{(Z)-C(Ph)=CH(Ph)} {P(OMe)3} (η-C5H5)]

AU - Brammer, Lee

AU - Crocker, Mark

AU - Dunne, Barry J.

AU - Green, Michael

AU - Morton, Carolyn E.

AU - Nagle, Katharine R.

AU - Orpen, A. Guy

PY - 1986

Y1 - 1986

N2 - σ,η3(5e)-Butadienylruthenium complexes behave as masked σ,η2(3e)-butadienyl complexes in their reactions with P(OMe)3 and PhC2Ph, whereas, protons react on the 'inside' of the σ,η3-butadienyl chain at the α-carbenoid carbon; attempts to expel P(OMe)3 thermally from the resulting σ,η2(3e)-butadienyl complexes results instead in a zeta-H abstraction reaction.

AB - σ,η3(5e)-Butadienylruthenium complexes behave as masked σ,η2(3e)-butadienyl complexes in their reactions with P(OMe)3 and PhC2Ph, whereas, protons react on the 'inside' of the σ,η3-butadienyl chain at the α-carbenoid carbon; attempts to expel P(OMe)3 thermally from the resulting σ,η2(3e)-butadienyl complexes results instead in a zeta-H abstraction reaction.

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EP - 1228

JO - Chemical Communications

JF - Chemical Communications

IS - 15

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