Transition metal complexes of 2,4,6-trimercapto-1,3,5-triazine (TMT): Potential precursors to nanoparticulate metal sulfides

Jaime R. Bailey; M. Jason Hatfield; Kevin R. Henke; Matthew K. Krepps; Jessica L. Morris; Tom Otieno; Karen D. Simonetti; Eric A. Wall; David A. Atwood

doi:10.1016/S0022-328X(00)00740-3

Transition metal complexes of 2,4,6-trimercapto-1,3,5-triazine (TMT): Potential precursors to nanoparticulate metal sulfides

Jaime R. Bailey, M. Jason Hatfield, Kevin R. Henke, Matthew K. Krepps, Jessica L. Morris, Tom Otieno, Karen D. Simonetti, Eric A. Wall, David A. Atwood

Chemistry

Research output: Contribution to journal › Article › peer-review

50 Scopus citations

Abstract

Although known for over 100 years, complexes of the TMT ligand with transition metals have not, until now, been prepared in a predictable and controlled manner. In the present work, high yield, intentional syntheses of a series of transition metal-TMT combinations are reported. These are of the form M₃(TMT)₂·nH₂O (M=Co (1), Cu (2), Cd(3)), M(HTMT)·nH₂O (M=Co (4), Cu (5)) and M(H₂TMT)₂·nH₂O (M=Co (6), Cu (7)). They are prepared by carefully controlling the pH of aqueous TMT solutions and metal to ligand stoichiometry. Serving to demonstrate that these transition metal-TMT complexes may be useful as materials precursors, nanoparticulate Greenockite (CdS) was formed by increasing the pH of a solution of 3.

Original language	English
Pages (from-to)	185-190
Number of pages	6
Journal	Journal of Organometallic Chemistry
Volume	623
Issue number	1-2
DOIs	https://doi.org/10.1016/S0022-328X(00)00740-3
State	Published - Mar 30 2001

Bibliographical note

Funding Information:
This project was supported by the Office of Naval Research (N00014-00-1-0630), NSF-KY EPSCoR, and the EKU Institutional Research Program. The Chemical U.S. Travel Program (CHUST) administered through The Royal Institute of Technology, Stockholm, Sweden provided a fellowship to E.A.W. to study at the University of Kentucky for the Summer of 2000.

Keywords

Cadmium sulfide
Nanoparticulate metal sulfides
TMT ligand

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/S0022-328X(00)00740-3

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Bailey, J. R., Hatfield, M. J., Henke, K. R., Krepps, M. K., Morris, J. L., Otieno, T., Simonetti, K. D., Wall, E. A., & Atwood, D. A. (2001). Transition metal complexes of 2,4,6-trimercapto-1,3,5-triazine (TMT): Potential precursors to nanoparticulate metal sulfides. Journal of Organometallic Chemistry, 623(1-2), 185-190. https://doi.org/10.1016/S0022-328X(00)00740-3

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abstract = "Although known for over 100 years, complexes of the TMT ligand with transition metals have not, until now, been prepared in a predictable and controlled manner. In the present work, high yield, intentional syntheses of a series of transition metal-TMT combinations are reported. These are of the form M3(TMT)2·nH2O (M=Co (1), Cu (2), Cd(3)), M(HTMT)·nH2O (M=Co (4), Cu (5)) and M(H2TMT)2·nH2O (M=Co (6), Cu (7)). They are prepared by carefully controlling the pH of aqueous TMT solutions and metal to ligand stoichiometry. Serving to demonstrate that these transition metal-TMT complexes may be useful as materials precursors, nanoparticulate Greenockite (CdS) was formed by increasing the pH of a solution of 3.",

keywords = "Cadmium sulfide, Nanoparticulate metal sulfides, TMT ligand",

author = "Bailey, {Jaime R.} and Hatfield, {M. Jason} and Henke, {Kevin R.} and Krepps, {Matthew K.} and Morris, {Jessica L.} and Tom Otieno and Simonetti, {Karen D.} and Wall, {Eric A.} and Atwood, {David A.}",

note = "Funding Information: This project was supported by the Office of Naval Research (N00014-00-1-0630), NSF-KY EPSCoR, and the EKU Institutional Research Program. The Chemical U.S. Travel Program (CHUST) administered through The Royal Institute of Technology, Stockholm, Sweden provided a fellowship to E.A.W. to study at the University of Kentucky for the Summer of 2000. ",

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doi = "10.1016/S0022-328X(00)00740-3",

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T1 - Transition metal complexes of 2,4,6-trimercapto-1,3,5-triazine (TMT)

T2 - Potential precursors to nanoparticulate metal sulfides

AU - Bailey, Jaime R.

AU - Hatfield, M. Jason

AU - Henke, Kevin R.

AU - Krepps, Matthew K.

AU - Morris, Jessica L.

AU - Otieno, Tom

AU - Simonetti, Karen D.

AU - Wall, Eric A.

AU - Atwood, David A.

N1 - Funding Information: This project was supported by the Office of Naval Research (N00014-00-1-0630), NSF-KY EPSCoR, and the EKU Institutional Research Program. The Chemical U.S. Travel Program (CHUST) administered through The Royal Institute of Technology, Stockholm, Sweden provided a fellowship to E.A.W. to study at the University of Kentucky for the Summer of 2000.

PY - 2001/3/30

Y1 - 2001/3/30

N2 - Although known for over 100 years, complexes of the TMT ligand with transition metals have not, until now, been prepared in a predictable and controlled manner. In the present work, high yield, intentional syntheses of a series of transition metal-TMT combinations are reported. These are of the form M3(TMT)2·nH2O (M=Co (1), Cu (2), Cd(3)), M(HTMT)·nH2O (M=Co (4), Cu (5)) and M(H2TMT)2·nH2O (M=Co (6), Cu (7)). They are prepared by carefully controlling the pH of aqueous TMT solutions and metal to ligand stoichiometry. Serving to demonstrate that these transition metal-TMT complexes may be useful as materials precursors, nanoparticulate Greenockite (CdS) was formed by increasing the pH of a solution of 3.

AB - Although known for over 100 years, complexes of the TMT ligand with transition metals have not, until now, been prepared in a predictable and controlled manner. In the present work, high yield, intentional syntheses of a series of transition metal-TMT combinations are reported. These are of the form M3(TMT)2·nH2O (M=Co (1), Cu (2), Cd(3)), M(HTMT)·nH2O (M=Co (4), Cu (5)) and M(H2TMT)2·nH2O (M=Co (6), Cu (7)). They are prepared by carefully controlling the pH of aqueous TMT solutions and metal to ligand stoichiometry. Serving to demonstrate that these transition metal-TMT complexes may be useful as materials precursors, nanoparticulate Greenockite (CdS) was formed by increasing the pH of a solution of 3.

KW - Cadmium sulfide

KW - Nanoparticulate metal sulfides

KW - TMT ligand

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Transition metal complexes of 2,4,6-trimercapto-1,3,5-triazine (TMT): Potential precursors to nanoparticulate metal sulfides

Abstract

Bibliographical note

Keywords

ASJC Scopus subject areas

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