Transport in organic semiconductors in large electric fields: From thermal activation to field emission

J. H. Worne, J. E. Anthony, D. Natelson

Research output: Contribution to journalArticlepeer-review

35 Scopus citations

Abstract

Understanding charge transport in organic semiconductors in large electric fields is relevant to many applications. We present transport measurements in organic field-effect transistors based on poly(3-hexylthiophene) and 6,13-bis(triisopropyl-silylethynyl) (TIPS) pentacene with short channels, from room temperature down to 4.2 K. Near 300 K transport in both systems is well described by thermally assisted hopping with Poole-Frenkel-type enhancement of the mobility. At low temperatures and large gate voltages, transport in both materials becomes nearly temperature independent, crossing over into field-driven tunneling. These data, particularly in TIPS-pentacene, show that great caution must be exercised when considering more exotic (e.g., Tomonaga-Luttinger liquid) interpretations of transport.

Original languageEnglish
Article number053308
JournalApplied Physics Letters
Volume96
Issue number5
DOIs
StatePublished - 2010

ASJC Scopus subject areas

  • Physics and Astronomy (miscellaneous)

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