Tripodal saltren Al(iBu)(Cl)3

Amitabha Mitra; Pingrong Wei; David A. Atwood

doi:10.1080/10241220600677555

Tripodal saltren Al(ⁱBu)(Cl)₃

Amitabha Mitra, Pingrong Wei, David A. Atwood

Chemistry

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

The compound saltren[AlⁱBuCl]₃ (1) has been prepared by the reaction of the tripodal ligand saltrenH₃ (tris(((2-hydroxybenzyl)amino)ethyl)amine) and di-isobutyl aluminum chloride. It has been characterized by physical (mp, EA), spectroscopic (¹H NMR, IR) and structural (single crystal X-ray diffraction) studies. 1 crystallizes in the trigonal space group P-3. The structure is a trimetallic monomer. Each aluminum atom is four-coordinate with a distorted tetrahedral geometry. It is the first main group halide compound of the saltren ligand.

Original language	English
Pages (from-to)	309-314
Number of pages	6
Journal	Main Group Chemistry
Volume	4
Issue number	4
DOIs	https://doi.org/10.1080/10241220600677555
State	Published - 2005

Keywords

Aluminum
Crystal structure
Ligand
Saltren
Trimetallic
Tripodal

ASJC Scopus subject areas

Organic Chemistry
Inorganic Chemistry
Materials Chemistry

Access to Document

10.1080/10241220600677555

Cite this

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title = "Tripodal saltren Al(iBu)(Cl)3",

abstract = "The compound saltren[AliBuCl]3 (1) has been prepared by the reaction of the tripodal ligand saltrenH3 (tris(((2-hydroxybenzyl)amino)ethyl)amine) and di-isobutyl aluminum chloride. It has been characterized by physical (mp, EA), spectroscopic (1H NMR, IR) and structural (single crystal X-ray diffraction) studies. 1 crystallizes in the trigonal space group P-3. The structure is a trimetallic monomer. Each aluminum atom is four-coordinate with a distorted tetrahedral geometry. It is the first main group halide compound of the saltren ligand.",

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T1 - Tripodal saltren Al(iBu)(Cl)3

AU - Mitra, Amitabha

AU - Wei, Pingrong

AU - Atwood, David A.

PY - 2005

Y1 - 2005

N2 - The compound saltren[AliBuCl]3 (1) has been prepared by the reaction of the tripodal ligand saltrenH3 (tris(((2-hydroxybenzyl)amino)ethyl)amine) and di-isobutyl aluminum chloride. It has been characterized by physical (mp, EA), spectroscopic (1H NMR, IR) and structural (single crystal X-ray diffraction) studies. 1 crystallizes in the trigonal space group P-3. The structure is a trimetallic monomer. Each aluminum atom is four-coordinate with a distorted tetrahedral geometry. It is the first main group halide compound of the saltren ligand.

AB - The compound saltren[AliBuCl]3 (1) has been prepared by the reaction of the tripodal ligand saltrenH3 (tris(((2-hydroxybenzyl)amino)ethyl)amine) and di-isobutyl aluminum chloride. It has been characterized by physical (mp, EA), spectroscopic (1H NMR, IR) and structural (single crystal X-ray diffraction) studies. 1 crystallizes in the trigonal space group P-3. The structure is a trimetallic monomer. Each aluminum atom is four-coordinate with a distorted tetrahedral geometry. It is the first main group halide compound of the saltren ligand.

KW - Aluminum

KW - Crystal structure

KW - Ligand

KW - Saltren

KW - Trimetallic

KW - Tripodal

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