Tuning crystalline solid-state order and charge transport via building-block modification of oligothiophenes

Colin Reese; Mark E. Roberts; Sean R. Parkin; Zhenan Bao

doi:10.1002/adma.200900836

Tuning crystalline solid-state order and charge transport via building-block modification of oligothiophenes

Colin Reese, Mark E. Roberts, Sean R. Parkin, Zhenan Bao

Chemistry

Research output: Contribution to journal › Article › peer-review

51 Scopus citations

Abstract

The packing structure of a series of oligothiophenes is tuned via terminal substitution (see figure). The structural changes dramatically alter intermolecular interactions and charge-transport properties, as measured by elastomeric singlecrystal field-effect transistors. Electronic structure calculations reveal the sensitivity of the transport efficiency to orbital nodal alignment, as correlated to the observed trend in field-effect mobilities.

Original language	English
Pages (from-to)	3678-3681
Number of pages	4
Journal	Advanced Materials
Volume	21
Issue number	36
DOIs	https://doi.org/10.1002/adma.200900836
State	Published - 2009

ASJC Scopus subject areas

General Materials Science
Mechanics of Materials
Mechanical Engineering

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10.1002/adma.200900836

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title = "Tuning crystalline solid-state order and charge transport via building-block modification of oligothiophenes",

abstract = "The packing structure of a series of oligothiophenes is tuned via terminal substitution (see figure). The structural changes dramatically alter intermolecular interactions and charge-transport properties, as measured by elastomeric singlecrystal field-effect transistors. Electronic structure calculations reveal the sensitivity of the transport efficiency to orbital nodal alignment, as correlated to the observed trend in field-effect mobilities.",

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AU - Reese, Colin

AU - Roberts, Mark E.

AU - Parkin, Sean R.

AU - Bao, Zhenan

PY - 2009

Y1 - 2009

N2 - The packing structure of a series of oligothiophenes is tuned via terminal substitution (see figure). The structural changes dramatically alter intermolecular interactions and charge-transport properties, as measured by elastomeric singlecrystal field-effect transistors. Electronic structure calculations reveal the sensitivity of the transport efficiency to orbital nodal alignment, as correlated to the observed trend in field-effect mobilities.

AB - The packing structure of a series of oligothiophenes is tuned via terminal substitution (see figure). The structural changes dramatically alter intermolecular interactions and charge-transport properties, as measured by elastomeric singlecrystal field-effect transistors. Electronic structure calculations reveal the sensitivity of the transport efficiency to orbital nodal alignment, as correlated to the observed trend in field-effect mobilities.

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U2 - 10.1002/adma.200900836

DO - 10.1002/adma.200900836

M3 - Article

AN - SCOPUS:70349781903

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EP - 3681

JO - Advanced Materials

JF - Advanced Materials

IS - 36

ER -

Tuning crystalline solid-state order and charge transport via building-block modification of oligothiophenes

Abstract

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