Two-dimensional network acquired by Pb(II)-2-aminoethanethiolate

Mohan S. Bharara; Sean Parkin; David A. Atwood

doi:10.1016/j.ica.2006.03.037

Two-dimensional network acquired by Pb(II)-2-aminoethanethiolate

Mohan S. Bharara, Sean Parkin, David A. Atwood

Research output: Contribution to journal › Article › peer-review

7 Scopus citations

Abstract

The combination of an equivalent amount of Pb(NO₃)₂ and 2-aminoethanethiol hydrochloride in the presence of a base yielded a two-dimensional network consisting of [PbCl(SCH₂CH₂NH₃)](NO₃) (1) units. The network is further extended to a three-dimensional framework with intermolecular hydrogen bonding involving NO₃^- and Cl^-. The geometry around Pb in 1 can be best described as distorted pentagonal bipyrimidal with the axial positions occupied by Cl atoms. Due to the presence of a weak Pb{single bond}Cl bond, the two-dimensional network can be considered to be formed of PbS₂Cl units with an additional Cl acting as bridging atom.

Original language	English
Pages (from-to)	3375-3378
Number of pages	4
Journal	Inorganica Chimica Acta
Volume	359
Issue number	10
DOIs	https://doi.org/10.1016/j.ica.2006.03.037
State	Published - Jul 1 2006

Bibliographical note

Funding Information:
This work was supported by the University of Kentucky Tracy’s Farmer Center for the Environment and the State of Kentucky Research Challenge Trust Fund. NMR instruments used in this research were obtained with funds from the CRIF program of the National Science Foundation (Grant CHE 997841) and from the Research Challenge Trust Fund of the University of Kentucky.

Copyright:
Copyright 2020 Elsevier B.V., All rights reserved.

Funding

This work was supported by the University of Kentucky Tracy’s Farmer Center for the Environment and the State of Kentucky Research Challenge Trust Fund. NMR instruments used in this research were obtained with funds from the CRIF program of the National Science Foundation (Grant CHE 997841) and from the Research Challenge Trust Fund of the University of Kentucky.

Funders	Funder number
Kentucky Research Challenge Trust Fund
University of Kentucky Tracy’s Farmer Center for the Environment
National Science Foundation (NSF)	CHE 997841
University of Kentucky

Keywords

2-Aminoethanethiol
Homonuclear interaction
Lead(II)-thiolate
UV-Vis
X-ray

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/j.ica.2006.03.037

Cite this

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title = "Two-dimensional network acquired by Pb(II)-2-aminoethanethiolate",

abstract = "The combination of an equivalent amount of Pb(NO3)2 and 2-aminoethanethiol hydrochloride in the presence of a base yielded a two-dimensional network consisting of [PbCl(SCH2CH2NH3)](NO3) (1) units. The network is further extended to a three-dimensional framework with intermolecular hydrogen bonding involving NO3- and Cl-. The geometry around Pb in 1 can be best described as distorted pentagonal bipyrimidal with the axial positions occupied by Cl atoms. Due to the presence of a weak Pb{single bond}Cl bond, the two-dimensional network can be considered to be formed of PbS2Cl units with an additional Cl acting as bridging atom.",

keywords = "2-Aminoethanethiol, Homonuclear interaction, Lead(II)-thiolate, UV-Vis, X-ray",

author = "Bharara, {Mohan S.} and Sean Parkin and Atwood, {David A.}",

note = "Funding Information: This work was supported by the University of Kentucky Tracy{\textquoteright}s Farmer Center for the Environment and the State of Kentucky Research Challenge Trust Fund. NMR instruments used in this research were obtained with funds from the CRIF program of the National Science Foundation (Grant CHE 997841) and from the Research Challenge Trust Fund of the University of Kentucky. Copyright: Copyright 2020 Elsevier B.V., All rights reserved.",

year = "2006",

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doi = "10.1016/j.ica.2006.03.037",

language = "English",

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AU - Bharara, Mohan S.

AU - Parkin, Sean

AU - Atwood, David A.

N1 - Funding Information: This work was supported by the University of Kentucky Tracy’s Farmer Center for the Environment and the State of Kentucky Research Challenge Trust Fund. NMR instruments used in this research were obtained with funds from the CRIF program of the National Science Foundation (Grant CHE 997841) and from the Research Challenge Trust Fund of the University of Kentucky. Copyright: Copyright 2020 Elsevier B.V., All rights reserved.

PY - 2006/7/1

Y1 - 2006/7/1

N2 - The combination of an equivalent amount of Pb(NO3)2 and 2-aminoethanethiol hydrochloride in the presence of a base yielded a two-dimensional network consisting of [PbCl(SCH2CH2NH3)](NO3) (1) units. The network is further extended to a three-dimensional framework with intermolecular hydrogen bonding involving NO3- and Cl-. The geometry around Pb in 1 can be best described as distorted pentagonal bipyrimidal with the axial positions occupied by Cl atoms. Due to the presence of a weak Pb{single bond}Cl bond, the two-dimensional network can be considered to be formed of PbS2Cl units with an additional Cl acting as bridging atom.

AB - The combination of an equivalent amount of Pb(NO3)2 and 2-aminoethanethiol hydrochloride in the presence of a base yielded a two-dimensional network consisting of [PbCl(SCH2CH2NH3)](NO3) (1) units. The network is further extended to a three-dimensional framework with intermolecular hydrogen bonding involving NO3- and Cl-. The geometry around Pb in 1 can be best described as distorted pentagonal bipyrimidal with the axial positions occupied by Cl atoms. Due to the presence of a weak Pb{single bond}Cl bond, the two-dimensional network can be considered to be formed of PbS2Cl units with an additional Cl acting as bridging atom.

KW - 2-Aminoethanethiol

KW - Homonuclear interaction

KW - Lead(II)-thiolate

KW - UV-Vis

KW - X-ray

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U2 - 10.1016/j.ica.2006.03.037

DO - 10.1016/j.ica.2006.03.037

M3 - Article

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SN - 0020-1693

VL - 359

SP - 3375

EP - 3378

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

IS - 10

ER -

Two-dimensional network acquired by Pb(II)-2-aminoethanethiolate

Abstract

Bibliographical note

Funding

Keywords

ASJC Scopus subject areas

Access to Document

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