Understanding diffusion-induced-stresses in lithium ion battery electrodes

Yang Tse Cheng; Mark W. Verbrugge; Rutooj Deshpande

doi:10.1007/978-94-007-4911-5_18

Understanding diffusion-induced-stresses in lithium ion battery electrodes

Yang Tse Cheng, Mark W. Verbrugge, Rutooj Deshpande

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

2 Scopus citations

Abstract

Most lithium ion battery electrodes experience large volume expansion and contraction during lithiation and delithiation, respectively. Electrode failure, in the form of fracture and decrepitation, can occur as a result of repeated volume changes. In this paper, we provide an overview of our recent work on modeling the evolution of concentration, stress, and strain energy within a spherical- or cylindrical-electrode element under various charging-discharging conditions. Based on the analytic results, we propose tensile stress and strain energy based criteria for the initiation and propagation of cracks within the electrodes. We will also discuss "size effects" on stresses and fracture of electrodes. These results may help guide the development of new materials for lithium ion batteries with enhanced durability and performance.

Original language	English
Title of host publication	IUTAM Symposium on Surface Effects in the Mechanics of Nanomaterials and Heterostructures - Proceedings of the IUTAM Symposium
Editors	Alan Cocks, Jianxiang Wang
Pages	203-215
Number of pages	13
DOIs	https://doi.org/10.1007/978-94-007-4911-5_18
State	Published - 2013
Event	IUTAM Symposium on Surface Effects in the Mechanics of Nanomaterials and Heterostructures, 2010 - Beijing, China Duration: Aug 8 2010 → Aug 12 2010

Publication series

Name	IUTAM Bookseries
Volume	31
ISSN (Print)	1875-3507
ISSN (Electronic)	1875-3493

Conference

Conference	IUTAM Symposium on Surface Effects in the Mechanics of Nanomaterials and Heterostructures, 2010
Country/Territory	China
City	Beijing
Period	8/8/10 → 8/12/10

Bibliographical note

Publisher Copyright:
© Springer Science+Business Media Dordrecht 2013.

Keywords

Diffusion induced stress
Fracture
Lithium ion batteries
Size effect

ASJC Scopus subject areas

Civil and Structural Engineering
Automotive Engineering
Aerospace Engineering
Acoustics and Ultrasonics
Mechanical Engineering

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

Access to Document

10.1007/978-94-007-4911-5_18

Cite this

Cheng, Y. T., Verbrugge, M. W., & Deshpande, R. (2013). Understanding diffusion-induced-stresses in lithium ion battery electrodes. In A. Cocks, & J. Wang (Eds.), IUTAM Symposium on Surface Effects in the Mechanics of Nanomaterials and Heterostructures - Proceedings of the IUTAM Symposium (pp. 203-215). (IUTAM Bookseries; Vol. 31). https://doi.org/10.1007/978-94-007-4911-5_18

@inproceedings{aac05c5903344c599cdc0c93d026f14d,

title = "Understanding diffusion-induced-stresses in lithium ion battery electrodes",

abstract = "Most lithium ion battery electrodes experience large volume expansion and contraction during lithiation and delithiation, respectively. Electrode failure, in the form of fracture and decrepitation, can occur as a result of repeated volume changes. In this paper, we provide an overview of our recent work on modeling the evolution of concentration, stress, and strain energy within a spherical- or cylindrical-electrode element under various charging-discharging conditions. Based on the analytic results, we propose tensile stress and strain energy based criteria for the initiation and propagation of cracks within the electrodes. We will also discuss {"}size effects{"} on stresses and fracture of electrodes. These results may help guide the development of new materials for lithium ion batteries with enhanced durability and performance.",

keywords = "Diffusion induced stress, Fracture, Lithium ion batteries, Size effect",

author = "Cheng, \{Yang Tse\} and Verbrugge, \{Mark W.\} and Rutooj Deshpande",

note = "Publisher Copyright: {\textcopyright} Springer Science+Business Media Dordrecht 2013.; IUTAM Symposium on Surface Effects in the Mechanics of Nanomaterials and Heterostructures, 2010 ; Conference date: 08-08-2010 Through 12-08-2010",

year = "2013",

doi = "10.1007/978-94-007-4911-5\_18",

language = "English",

isbn = "9789400749108",

series = "IUTAM Bookseries",

pages = "203--215",

editor = "Alan Cocks and Jianxiang Wang",

booktitle = "IUTAM Symposium on Surface Effects in the Mechanics of Nanomaterials and Heterostructures - Proceedings of the IUTAM Symposium",

}

Cheng, YT, Verbrugge, MW & Deshpande, R 2013, Understanding diffusion-induced-stresses in lithium ion battery electrodes. in A Cocks & J Wang (eds), IUTAM Symposium on Surface Effects in the Mechanics of Nanomaterials and Heterostructures - Proceedings of the IUTAM Symposium. IUTAM Bookseries, vol. 31, pp. 203-215, IUTAM Symposium on Surface Effects in the Mechanics of Nanomaterials and Heterostructures, 2010, Beijing, China, 8/8/10. https://doi.org/10.1007/978-94-007-4911-5_18

Understanding diffusion-induced-stresses in lithium ion battery electrodes. / Cheng, Yang Tse; Verbrugge, Mark W.; Deshpande, Rutooj.
IUTAM Symposium on Surface Effects in the Mechanics of Nanomaterials and Heterostructures - Proceedings of the IUTAM Symposium. ed. / Alan Cocks; Jianxiang Wang. 2013. p. 203-215 (IUTAM Bookseries; Vol. 31).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

TY - GEN

T1 - Understanding diffusion-induced-stresses in lithium ion battery electrodes

AU - Cheng, Yang Tse

AU - Verbrugge, Mark W.

AU - Deshpande, Rutooj

N1 - Publisher Copyright: © Springer Science+Business Media Dordrecht 2013.

PY - 2013

Y1 - 2013

N2 - Most lithium ion battery electrodes experience large volume expansion and contraction during lithiation and delithiation, respectively. Electrode failure, in the form of fracture and decrepitation, can occur as a result of repeated volume changes. In this paper, we provide an overview of our recent work on modeling the evolution of concentration, stress, and strain energy within a spherical- or cylindrical-electrode element under various charging-discharging conditions. Based on the analytic results, we propose tensile stress and strain energy based criteria for the initiation and propagation of cracks within the electrodes. We will also discuss "size effects" on stresses and fracture of electrodes. These results may help guide the development of new materials for lithium ion batteries with enhanced durability and performance.

AB - Most lithium ion battery electrodes experience large volume expansion and contraction during lithiation and delithiation, respectively. Electrode failure, in the form of fracture and decrepitation, can occur as a result of repeated volume changes. In this paper, we provide an overview of our recent work on modeling the evolution of concentration, stress, and strain energy within a spherical- or cylindrical-electrode element under various charging-discharging conditions. Based on the analytic results, we propose tensile stress and strain energy based criteria for the initiation and propagation of cracks within the electrodes. We will also discuss "size effects" on stresses and fracture of electrodes. These results may help guide the development of new materials for lithium ion batteries with enhanced durability and performance.

KW - Diffusion induced stress

KW - Fracture

KW - Lithium ion batteries

KW - Size effect

UR - http://www.scopus.com/inward/record.url?scp=85018906141&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=85018906141&partnerID=8YFLogxK

U2 - 10.1007/978-94-007-4911-5_18

DO - 10.1007/978-94-007-4911-5_18

M3 - Conference contribution

AN - SCOPUS:85018906141

SN - 9789400749108

T3 - IUTAM Bookseries

SP - 203

EP - 215

BT - IUTAM Symposium on Surface Effects in the Mechanics of Nanomaterials and Heterostructures - Proceedings of the IUTAM Symposium

A2 - Cocks, Alan

A2 - Wang, Jianxiang

T2 - IUTAM Symposium on Surface Effects in the Mechanics of Nanomaterials and Heterostructures, 2010

Y2 - 8 August 2010 through 12 August 2010

ER -

Understanding diffusion-induced-stresses in lithium ion battery electrodes

Abstract

Publication series

Conference

Bibliographical note

Keywords

ASJC Scopus subject areas

UN SDGs

Access to Document

Other files and links

Fingerprint

Cite this