Unusual intramolecular hydrogen bonding in Cy2GaBrNH2Ph. The first structurally characterized dialkyl gallium halide primary amine adduct

D. A. Atwood; A. H. Cowley; R. A. Jones

doi:10.1016/0022-328X(92)86012-S

Unusual intramolecular hydrogen bonding in Cy₂GaBrNH₂Ph. The first structurally characterized dialkyl gallium halide primary amine adduct

D. A. Atwood, A. H. Cowley, R. A. Jones

Research output: Contribution to journal › Article › peer-review

14 Scopus citations

Abstract

The aniline adduct of dicyclohexyl gallium bromide Cy₂GaBrNH₂Ph (1) provides the first example of a structurally characterized dialkyi gallium halide primary amine adduct. X-ray crystallographic data indicate the possibility of an intramolecular hydrogen bond between the bromide and a hydrogen of the amine group (H⋯Br = 2.48 Å).

Original language	English
Pages (from-to)	C29-C32
Journal	Journal of Organometallic Chemistry
Volume	430
Issue number	2
DOIs	https://doi.org/10.1016/0022-328X(92)86012-S
State	Published - Jun 6 1992

Bibliographical note

Funding Information:
Acknowledgements. We are grateful to the National Science Foundation, the Army Research Office, the Robert A. Welch Foundation, and ACS-PRF for generousf inancial support.

Funding

Acknowledgements. We are grateful to the National Science Foundation, the Army Research Office, the Robert A. Welch Foundation, and ACS-PRF for generousf inancial support.

Funders	Funder number
ACS-PRF
Robert A. Welch Foundation
National Science Foundation (NSF)
Army Research Office

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

Access to Document

10.1016/0022-328X(92)86012-S

Cite this

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title = "Unusual intramolecular hydrogen bonding in Cy2GaBrNH2Ph. The first structurally characterized dialkyl gallium halide primary amine adduct",

abstract = "The aniline adduct of dicyclohexyl gallium bromide Cy2GaBrNH2Ph (1) provides the first example of a structurally characterized dialkyi gallium halide primary amine adduct. X-ray crystallographic data indicate the possibility of an intramolecular hydrogen bond between the bromide and a hydrogen of the amine group (H⋯Br = 2.48 {\AA}).",

author = "Atwood, {D. A.} and Cowley, {A. H.} and Jones, {R. A.}",

note = "Funding Information: Acknowledgements. We are grateful to the National Science Foundation, the Army Research Office, the Robert A. Welch Foundation, and ACS-PRF for generousf inancial support.",

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AU - Atwood, D. A.

AU - Cowley, A. H.

AU - Jones, R. A.

N1 - Funding Information: Acknowledgements. We are grateful to the National Science Foundation, the Army Research Office, the Robert A. Welch Foundation, and ACS-PRF for generousf inancial support.

PY - 1992/6/6

Y1 - 1992/6/6

N2 - The aniline adduct of dicyclohexyl gallium bromide Cy2GaBrNH2Ph (1) provides the first example of a structurally characterized dialkyi gallium halide primary amine adduct. X-ray crystallographic data indicate the possibility of an intramolecular hydrogen bond between the bromide and a hydrogen of the amine group (H⋯Br = 2.48 Å).

AB - The aniline adduct of dicyclohexyl gallium bromide Cy2GaBrNH2Ph (1) provides the first example of a structurally characterized dialkyi gallium halide primary amine adduct. X-ray crystallographic data indicate the possibility of an intramolecular hydrogen bond between the bromide and a hydrogen of the amine group (H⋯Br = 2.48 Å).

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