TY - JOUR
T1 - Unusual structural features in an alkyl aluminum lithium amideunusual structural features in an alkyl aluminum lithium amide
AU - Atwood, David A.
AU - Rutherford, Drew
PY - 1997
Y1 - 1997
N2 - In this communication are reported the structural characterization of Me3AlNH2But(l), [Me2AlNHBut]2 (2) and [Me2AlNLi(THF)But]2(3). These compounds mark the first instance that a direct structural comparison can be made within a homologous series consisting of an alkylaluminum primary amine adduct, -amide, and lithium amide. One change of interest within 1-3 relates to the degree of bond shortening that occurs with the growing negative charge on nitrogen.
AB - In this communication are reported the structural characterization of Me3AlNH2But(l), [Me2AlNHBut]2 (2) and [Me2AlNLi(THF)But]2(3). These compounds mark the first instance that a direct structural comparison can be made within a homologous series consisting of an alkylaluminum primary amine adduct, -amide, and lithium amide. One change of interest within 1-3 relates to the degree of bond shortening that occurs with the growing negative charge on nitrogen.
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U2 - 10.1080/13583149712331338809
DO - 10.1080/13583149712331338809
M3 - Article
AN - SCOPUS:85013602577
SN - 1024-1221
VL - 2
SP - 5
EP - 8
JO - Main Group Chemistry
JF - Main Group Chemistry
IS - 1
ER -