Use of the 2,6-bis[(dimethylamino)methyl]phenyl ligand to form some pentacoordinate derivatives of P(III), As(III), Sb(III) and Bi(III)

David A. Atwood; Alan H. Cowley; Jaime Ruiz

doi:10.1016/S0020-1693(00)92369-7

Use of the 2,6-bis[(dimethylamino)methyl]phenyl ligand to form some pentacoordinate derivatives of P(III), As(III), Sb(III) and Bi(III)

David A. Atwood, Alan H. Cowley, Jaime Ruiz

Chemistry

Research output: Contribution to journal › Article › peer-review

53 Scopus citations

Abstract

Reaction of Li[2,6-(Me₂NCH₂)₂C₆H₃] with ECl₃ results in the chelated dichlorides, [2,6-(Me₂NCH₂)₂C₆H₃]ECl₂ (EP (1), As (2), Sb (3), Bi (4)). Compounds 1 and 2 are converted into the corresponding EH₂ derivatives, [2,6-(Me₂NCH₂)₂C₆H₃]EH₂ (EP (5), As (6)) by reduction with LiAlH₄. The structure of 3 has been determined by X-ray crystallography. Compound 3 crystallizes in the monoclinic space group P2₁/c with a=11.135(1), b=8.620(1), c=16.245(2) Å, β=95.87(1)°, V=1551(2) Å³ and Z=4. The geometry at Sb is distorted square pyramidal.

Original language	English
Pages (from-to)	271-274
Number of pages	4
Journal	Inorganica Chimica Acta
Volume	198-200
Issue number	C
DOIs	https://doi.org/10.1016/S0020-1693(00)92369-7
State	Published - 1992

Bibliographical note

Funding Information:
The authors are grateful to the National Science Foundation and the Robert A. Welch Foundation for generousf inancial support.

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/S0020-1693(00)92369-7

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@article{eeee31670e564642a6aab73e4957951b,

title = "Use of the 2,6-bis[(dimethylamino)methyl]phenyl ligand to form some pentacoordinate derivatives of P(III), As(III), Sb(III) and Bi(III)",

abstract = "Reaction of Li[2,6-(Me2NCH2)2C6H3] with ECl3 results in the chelated dichlorides, [2,6-(Me2NCH2)2C6H3]ECl2 (EP (1), As (2), Sb (3), Bi (4)). Compounds 1 and 2 are converted into the corresponding EH2 derivatives, [2,6-(Me2NCH2)2C6H3]EH2 (EP (5), As (6)) by reduction with LiAlH4. The structure of 3 has been determined by X-ray crystallography. Compound 3 crystallizes in the monoclinic space group P21/c with a=11.135(1), b=8.620(1), c=16.245(2) {\AA}, β=95.87(1)°, V=1551(2) {\AA}3 and Z=4. The geometry at Sb is distorted square pyramidal.",

author = "Atwood, {David A.} and Cowley, {Alan H.} and Jaime Ruiz",

note = "Funding Information: The authors are grateful to the National Science Foundation and the Robert A. Welch Foundation for generousf inancial support.",

year = "1992",

doi = "10.1016/S0020-1693(00)92369-7",

language = "English",

volume = "198-200",

pages = "271--274",

number = "C",

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TY - JOUR

T1 - Use of the 2,6-bis[(dimethylamino)methyl]phenyl ligand to form some pentacoordinate derivatives of P(III), As(III), Sb(III) and Bi(III)

AU - Atwood, David A.

AU - Cowley, Alan H.

AU - Ruiz, Jaime

N1 - Funding Information: The authors are grateful to the National Science Foundation and the Robert A. Welch Foundation for generousf inancial support.

PY - 1992

Y1 - 1992

N2 - Reaction of Li[2,6-(Me2NCH2)2C6H3] with ECl3 results in the chelated dichlorides, [2,6-(Me2NCH2)2C6H3]ECl2 (EP (1), As (2), Sb (3), Bi (4)). Compounds 1 and 2 are converted into the corresponding EH2 derivatives, [2,6-(Me2NCH2)2C6H3]EH2 (EP (5), As (6)) by reduction with LiAlH4. The structure of 3 has been determined by X-ray crystallography. Compound 3 crystallizes in the monoclinic space group P21/c with a=11.135(1), b=8.620(1), c=16.245(2) Å, β=95.87(1)°, V=1551(2) Å3 and Z=4. The geometry at Sb is distorted square pyramidal.

AB - Reaction of Li[2,6-(Me2NCH2)2C6H3] with ECl3 results in the chelated dichlorides, [2,6-(Me2NCH2)2C6H3]ECl2 (EP (1), As (2), Sb (3), Bi (4)). Compounds 1 and 2 are converted into the corresponding EH2 derivatives, [2,6-(Me2NCH2)2C6H3]EH2 (EP (5), As (6)) by reduction with LiAlH4. The structure of 3 has been determined by X-ray crystallography. Compound 3 crystallizes in the monoclinic space group P21/c with a=11.135(1), b=8.620(1), c=16.245(2) Å, β=95.87(1)°, V=1551(2) Å3 and Z=4. The geometry at Sb is distorted square pyramidal.

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U2 - 10.1016/S0020-1693(00)92369-7

DO - 10.1016/S0020-1693(00)92369-7

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VL - 198-200

SP - 271

EP - 274

IS - C

ER -

Use of the 2,6-bis[(dimethylamino)methyl]phenyl ligand to form some pentacoordinate derivatives of P(III), As(III), Sb(III) and Bi(III)

Abstract

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