Vacuum ultraviolet laser/time-of-flight mass spectroscopy: Ion-pair spectra of 79Br35Cl

S. S. Dimov, R. H. Lipson, T. Turgeon, J. A. Vanstone, P. Wang, D. S. Yang

Research output: Contribution to journalArticlepeer-review

26 Scopus citations

Abstract

A newly built vacuum ultraviolet (VUV) laser/time-of-flight mass spectrometer is described, which has been used to record the first vibrationally and rotationally resoved spectra of the E0+ ion-pair state ←X0+ ground state transition of jet-cooled bromine monochloride BrCl, near 145 nm. The mass resolution of the instrument (m/Δm≈1000) was sufficient to obtain single isotopomer data. Preliminary results for 79Br35Cl are reported. Like other interhalogens, BrCl vibronic band intensities vary widely in the VUV, presumably as a result of excited state perturbations. This scenario has been corroborated by the observation of an irregularly spaced vibrational progression, and the irregular behavior of the excited state rotational constants as a function of v′.

Original languageEnglish
Pages (from-to)8666-8672
Number of pages7
JournalJournal of Chemical Physics
Volume100
Issue number12
DOIs
StatePublished - 1994

ASJC Scopus subject areas

  • Physics and Astronomy (all)
  • Physical and Theoretical Chemistry

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