(Z)-3-[1-(4-Chloro-benz-yl)-1H-indol-3-yl]-2-(3-thien-yl)acrylonitrile

Vijayakumar N. Sonar; Sean Parkin; Peter A. Crooks

doi:10.1107/S1600536807042638

(Z)-3-[1-(4-Chloro-benz-yl)-1H-indol-3-yl]-2-(3-thien-yl)acrylonitrile

Vijayakumar N. Sonar, Sean Parkin, Peter A. Crooks

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

The title compound, C22H15ClN2S, was prepared by the base-catalyzed reaction of 1-(4-chloro-benz-yl)indole-3-carboxaldehyde with thio-phene-3-acetonitrile and recrystallization of the product from methanol. The double bond connecting the indole and thio-phene units has Z geometry. The indole ring system is nearly planar and makes a dihedral angle of 79.81 (4)° with the plane of the 4-chloro-phenyl ring. The mol-ecule exhibits orientational disorder of the thienyl fragment, with occupancy factors of 0.65:0.35.

Original language	English
Pages (from-to)	o3979
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	63
Issue number	10
DOIs	https://doi.org/10.1107/S1600536807042638
State	Published - 2007

ASJC Scopus subject areas

Chemistry (all)
Materials Science (all)
Condensed Matter Physics

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title = "(Z)-3-[1-(4-Chloro-benz-yl)-1H-indol-3-yl]-2-(3-thien-yl)acrylonitrile",

abstract = "The title compound, C22H15ClN2S, was prepared by the base-catalyzed reaction of 1-(4-chloro-benz-yl)indole-3-carboxaldehyde with thio-phene-3-acetonitrile and recrystallization of the product from methanol. The double bond connecting the indole and thio-phene units has Z geometry. The indole ring system is nearly planar and makes a dihedral angle of 79.81 (4)° with the plane of the 4-chloro-phenyl ring. The mol-ecule exhibits orientational disorder of the thienyl fragment, with occupancy factors of 0.65:0.35.",

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T1 - (Z)-3-[1-(4-Chloro-benz-yl)-1H-indol-3-yl]-2-(3-thien-yl)acrylonitrile

AU - Sonar, Vijayakumar N.

AU - Parkin, Sean

AU - Crooks, Peter A.

PY - 2007

Y1 - 2007

N2 - The title compound, C22H15ClN2S, was prepared by the base-catalyzed reaction of 1-(4-chloro-benz-yl)indole-3-carboxaldehyde with thio-phene-3-acetonitrile and recrystallization of the product from methanol. The double bond connecting the indole and thio-phene units has Z geometry. The indole ring system is nearly planar and makes a dihedral angle of 79.81 (4)° with the plane of the 4-chloro-phenyl ring. The mol-ecule exhibits orientational disorder of the thienyl fragment, with occupancy factors of 0.65:0.35.

AB - The title compound, C22H15ClN2S, was prepared by the base-catalyzed reaction of 1-(4-chloro-benz-yl)indole-3-carboxaldehyde with thio-phene-3-acetonitrile and recrystallization of the product from methanol. The double bond connecting the indole and thio-phene units has Z geometry. The indole ring system is nearly planar and makes a dihedral angle of 79.81 (4)° with the plane of the 4-chloro-phenyl ring. The mol-ecule exhibits orientational disorder of the thienyl fragment, with occupancy factors of 0.65:0.35.

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IS - 10

ER -

(Z)-3-[1-(4-Chloro-benz-yl)-1H-indol-3-yl]-2-(3-thien-yl)acrylonitrile

Abstract

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