Abstract
The vibrational structure of the Ag+NH3 complex has been investigated by single-photon zero kinetic energy (ZEKE) photoelectron spectroscopy. The intermolecular stretching mode with a frequency of 375 cm-1 is measured from the ZEKE spectrum, whereas the intermolecular bending vibration is not observed, in contrast to the Ã2E1/2-X̃2A1 electronic spectrum of the neutral AgNH3 complex [Miyawaki et al., Chem. Phys. Lett. 302 (1999) 354]. The ionization potential of AgNH3 was determined to be 47580 cm-1 (5.899 eV).
Original language | English |
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Pages (from-to) | 627-631 |
Number of pages | 5 |
Journal | Chemical Physics Letters |
Volume | 372 |
Issue number | 5-6 |
DOIs | |
State | Published - May 6 2003 |
ASJC Scopus subject areas
- General Physics and Astronomy
- Physical and Theoretical Chemistry