ZEKE spectroscopy of the AgNH3 complex

Jun Miyawaki, Dong Sheng Yang, Ko Ichi Sugawara

Research output: Contribution to journalArticlepeer-review

17 Scopus citations


The vibrational structure of the Ag+NH3 complex has been investigated by single-photon zero kinetic energy (ZEKE) photoelectron spectroscopy. The intermolecular stretching mode with a frequency of 375 cm-1 is measured from the ZEKE spectrum, whereas the intermolecular bending vibration is not observed, in contrast to the Ã2E1/2-X̃2A1 electronic spectrum of the neutral AgNH3 complex [Miyawaki et al., Chem. Phys. Lett. 302 (1999) 354]. The ionization potential of AgNH3 was determined to be 47580 cm-1 (5.899 eV).

Original languageEnglish
Pages (from-to)627-631
Number of pages5
JournalChemical Physics Letters
Issue number5-6
StatePublished - May 6 2003

ASJC Scopus subject areas

  • General Physics and Astronomy
  • Physical and Theoretical Chemistry


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