Zero electron kinetic energy photoelectron spectroscopy and density functional calculations of Al-P(CH3)3 and Al-As(CH3)3

Shenggang Li, Gretchen K. Rothschopf, Dong Sheng Yang

Research output: Contribution to journalArticlepeer-review

8 Scopus citations

Abstract

Electronic spectra of aluminum-trimethylphosphine and trimethylarsine was obtained using pulsed field ionization zero electron kinetic energy (ZEKE) photoelectron spectroscopy. Density functional calculations on equilibrium geometries, vibrational frequencies and metal-ligand bond dissociation energies for the two complexes and their ions were also performed. The spectra exhibited vibrational progressions arising from the intermolecular and molecular vibrations.

Original languageEnglish
Pages (from-to)6589-6594
Number of pages6
JournalJournal of Chemical Physics
Volume116
Issue number15
DOIs
StatePublished - Apr 15 2002

ASJC Scopus subject areas

  • General Physics and Astronomy
  • Physical and Theoretical Chemistry

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