Abstract
Electronic spectra of aluminum-trimethylphosphine and trimethylarsine was obtained using pulsed field ionization zero electron kinetic energy (ZEKE) photoelectron spectroscopy. Density functional calculations on equilibrium geometries, vibrational frequencies and metal-ligand bond dissociation energies for the two complexes and their ions were also performed. The spectra exhibited vibrational progressions arising from the intermolecular and molecular vibrations.
Original language | English |
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Pages (from-to) | 6589-6594 |
Number of pages | 6 |
Journal | Journal of Chemical Physics |
Volume | 116 |
Issue number | 15 |
DOIs | |
State | Published - Apr 15 2002 |
ASJC Scopus subject areas
- General Physics and Astronomy
- Physical and Theoretical Chemistry