Zero electron kinetic energy photoelectron spectroscopy of weakly bound In-NH2CH3, In-NH(CH3)2, and In-N(CH3)3 complexes

G. K. Rothschopf; S. Li; J. S. Perkins; D. S. Yang

doi:10.1063/1.1385525

Zero electron kinetic energy photoelectron spectroscopy of weakly bound In-NH₂CH₃, In-NH(CH₃)₂, and In-N(CH₃)₃ complexes

G. K. Rothschopf, S. Li, J. S. Perkins, D. S. Yang

Research output: Contribution to journal › Article › peer-review

15 Scopus citations

Abstract

Vibrationally resolved single-photon zero electron kinetic energy (ZEKE) spectra were obtained for the first time for the weakly bound adducts, In-NH₂CH₃, In-NH(CH₃)₂, and In-N(CH₃)₃. Adiabatic IPs and indium-amine vibrational frequencies were measured for the three complexes. The results suggest that the orbital interaction and electrostatic forces contribute to the binding between the indium metal and the nitrogen ligands.

Original language	English
Pages (from-to)	4565-4572
Number of pages	8
Journal	Journal of Chemical Physics
Volume	115
Issue number	10
DOIs	https://doi.org/10.1063/1.1385525
State	Published - Sep 8 2001

ASJC Scopus subject areas

General Physics and Astronomy
Physical and Theoretical Chemistry

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10.1063/1.1385525

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title = "Zero electron kinetic energy photoelectron spectroscopy of weakly bound In-NH2CH3, In-NH(CH3)2, and In-N(CH3)3 complexes",

abstract = "Vibrationally resolved single-photon zero electron kinetic energy (ZEKE) spectra were obtained for the first time for the weakly bound adducts, In-NH2CH3, In-NH(CH3)2, and In-N(CH3)3. Adiabatic IPs and indium-amine vibrational frequencies were measured for the three complexes. The results suggest that the orbital interaction and electrostatic forces contribute to the binding between the indium metal and the nitrogen ligands.",

author = "Rothschopf, {G. K.} and S. Li and Perkins, {J. S.} and Yang, {D. S.}",

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doi = "10.1063/1.1385525",

language = "English",

volume = "115",

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T1 - Zero electron kinetic energy photoelectron spectroscopy of weakly bound In-NH2CH3, In-NH(CH3)2, and In-N(CH3)3 complexes

AU - Rothschopf, G. K.

AU - Li, S.

AU - Perkins, J. S.

AU - Yang, D. S.

PY - 2001/9/8

Y1 - 2001/9/8

N2 - Vibrationally resolved single-photon zero electron kinetic energy (ZEKE) spectra were obtained for the first time for the weakly bound adducts, In-NH2CH3, In-NH(CH3)2, and In-N(CH3)3. Adiabatic IPs and indium-amine vibrational frequencies were measured for the three complexes. The results suggest that the orbital interaction and electrostatic forces contribute to the binding between the indium metal and the nitrogen ligands.

AB - Vibrationally resolved single-photon zero electron kinetic energy (ZEKE) spectra were obtained for the first time for the weakly bound adducts, In-NH2CH3, In-NH(CH3)2, and In-N(CH3)3. Adiabatic IPs and indium-amine vibrational frequencies were measured for the three complexes. The results suggest that the orbital interaction and electrostatic forces contribute to the binding between the indium metal and the nitrogen ligands.

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U2 - 10.1063/1.1385525

DO - 10.1063/1.1385525

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VL - 115

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EP - 4572

JO - Journal of Chemical Physics

JF - Journal of Chemical Physics

IS - 10

ER -

Zero electron kinetic energy photoelectron spectroscopy of weakly bound In-NH₂CH₃, In-NH(CH₃)₂, and In-N(CH₃)₃ complexes

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