A bis(pyrazolyl)borate complex of silicon(IV)

Vicki O. Atwood; David A. Atwood; Alan H. Cowley; Swiatoslaw Trofimenko

doi:10.1016/S0277-5387(00)83330-6

A bis(pyrazolyl)borate complex of silicon(IV)

Vicki O. Atwood
, David A. Atwood
, Alan H. Cowley
, Swiatoslaw Trofimenko

Producción científica: Article › revisión exhaustiva

10 Citas (Scopus)

Resumen

The first pyrazolylborate complex of silicon, [Ph₂B(pz)₂]₂SiCl₂, has been prepared via the reaction of K[Ph₂B(pz)₂] with SiCl₄. The structure of this complex has been determined by X-ray crystallography. The bis(pyrazolyl)borate ligand behaves in a bidentate fashion and the silicon adopts a distorted octahedral geometry.

Idioma original	English
Páginas (desde-hasta)	711-715
Número de páginas	5
Publicación	Polyhedron
Volumen	11
N.º	6
DOI	https://doi.org/10.1016/S0277-5387(00)83330-6
Estado	Published - 1992

Nota bibliográfica

Funding Information:
Acknowledgements-We thank the National Science Foundation and the Robert A. Welch Foundation for generousfi nancial support.

Financiación

Acknowledgements-We thank the National Science Foundation and the Robert A. Welch Foundation for generousfi nancial support.

Financiadores
Robert A. Welch Foundation
National Science Foundation (NSF)

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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title = "A bis(pyrazolyl)borate complex of silicon(IV)",

abstract = "The first pyrazolylborate complex of silicon, [Ph2B(pz)2]2SiCl2, has been prepared via the reaction of K[Ph2B(pz)2] with SiCl4. The structure of this complex has been determined by X-ray crystallography. The bis(pyrazolyl)borate ligand behaves in a bidentate fashion and the silicon adopts a distorted octahedral geometry.",

author = "Atwood, \{Vicki O.\} and Atwood, \{David A.\} and Cowley, \{Alan H.\} and Swiatoslaw Trofimenko",

note = "Funding Information: Acknowledgements-We thank the National Science Foundation and the Robert A. Welch Foundation for generousfi nancial support.",

year = "1992",

doi = "10.1016/S0277-5387(00)83330-6",

language = "English",

volume = "11",

pages = "711--715",

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T1 - A bis(pyrazolyl)borate complex of silicon(IV)

AU - Atwood, Vicki O.

AU - Atwood, David A.

AU - Cowley, Alan H.

AU - Trofimenko, Swiatoslaw

N1 - Funding Information: Acknowledgements-We thank the National Science Foundation and the Robert A. Welch Foundation for generousfi nancial support.

PY - 1992

Y1 - 1992

N2 - The first pyrazolylborate complex of silicon, [Ph2B(pz)2]2SiCl2, has been prepared via the reaction of K[Ph2B(pz)2] with SiCl4. The structure of this complex has been determined by X-ray crystallography. The bis(pyrazolyl)borate ligand behaves in a bidentate fashion and the silicon adopts a distorted octahedral geometry.

AB - The first pyrazolylborate complex of silicon, [Ph2B(pz)2]2SiCl2, has been prepared via the reaction of K[Ph2B(pz)2] with SiCl4. The structure of this complex has been determined by X-ray crystallography. The bis(pyrazolyl)borate ligand behaves in a bidentate fashion and the silicon adopts a distorted octahedral geometry.

UR - https://www.scopus.com/pages/publications/0040053770

UR - https://www.scopus.com/pages/publications/0040053770#tab=citedBy

U2 - 10.1016/S0277-5387(00)83330-6

DO - 10.1016/S0277-5387(00)83330-6

M3 - Article

AN - SCOPUS:0040053770

SN - 0277-5387

VL - 11

SP - 711

EP - 715

JO - Polyhedron

JF - Polyhedron

IS - 6

ER -

A bis(pyrazolyl)borate complex of silicon(IV)

Resumen

Nota bibliográfica

Financiación

ASJC Scopus subject areas

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