A photodissociation study of HgI2

K. J. Jordan; R. H. Lipson; D. S. Yang

doi:10.1063/1.463337

A photodissociation study of HgI₂

K. J. Jordan
, R. H. Lipson
, D. S. Yang

Producción científica: Article › revisión exhaustiva

5 Citas (Scopus)

Resumen

The photodissociation of jet-cooled HgI₂ has been studied in the 244-323 nm region using a tunable ultraviolet (UV) laser. Dispersed emission, action, and multiphoton ionization spectra have been recorded. A vibrational analysis of the action spectra near 305 nm shows that the production of excited Hg atoms from HgI₂ UV photodissociation proceeds through a HgI ground-state intermediate. Near 248 nm the results are less conclusive. Possible reasons for a wavelength-dependent kinetic mechanism are discussed.

Idioma original	English
Páginas (desde-hasta)	9099-9106
Número de páginas	8
Publicación	Journal of Chemical Physics
Volumen	97
N.º	12
DOI	https://doi.org/10.1063/1.463337
Estado	Published - 1992

ASJC Scopus subject areas

General Physics and Astronomy
Physical and Theoretical Chemistry

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10.1063/1.463337

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abstract = "The photodissociation of jet-cooled HgI2 has been studied in the 244-323 nm region using a tunable ultraviolet (UV) laser. Dispersed emission, action, and multiphoton ionization spectra have been recorded. A vibrational analysis of the action spectra near 305 nm shows that the production of excited Hg atoms from HgI2 UV photodissociation proceeds through a HgI ground-state intermediate. Near 248 nm the results are less conclusive. Possible reasons for a wavelength-dependent kinetic mechanism are discussed.",

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AU - Lipson, R. H.

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AB - The photodissociation of jet-cooled HgI2 has been studied in the 244-323 nm region using a tunable ultraviolet (UV) laser. Dispersed emission, action, and multiphoton ionization spectra have been recorded. A vibrational analysis of the action spectra near 305 nm shows that the production of excited Hg atoms from HgI2 UV photodissociation proceeds through a HgI ground-state intermediate. Near 248 nm the results are less conclusive. Possible reasons for a wavelength-dependent kinetic mechanism are discussed.

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