An indium-phosphorus heterocubane as a new type of indium phosphide precursor

David A. Atwood; Alan H. Cowley; Richard A. Jones; Miguel A. Mardones

doi:10.1016/0022-328X(93)80126-V

An indium-phosphorus heterocubane as a new type of indium phosphide precursor

David A. Atwood, Alan H. Cowley, Richard A. Jones, Miguel A. Mardones

Producción científica: Article › revisión exhaustiva

38 Citas (Scopus)

Resumen

The first indium-phosphorus cubane, [ⁱPrIn(μ₃-PSiPh₃)]₄ (1) has been prepared via the reaction of Li₂[PSiPh₃] with ⁱPrInI₂. The structure of 1 has been determined by X-ray analysis: monoclinic, space group P2₁/c with a = 15.611(3), b = 25.767(2), c = 22.541(6) Å, β = 96.19(2)°, and Z = 4. Polycrystalline films of indium phosphide have been grown on Si(100) wafers from 1 in a horizontal hot-wall reactor at 500°C. Compound 1 is unstable with respect to photolysis and electrochemical oxidation; however it is relatively stable toward alcoholysis.

Idioma original	English
Páginas (desde-hasta)	C1
Publicación	Journal of Organometallic Chemistry
Volumen	449
N.º	1-2
DOI	https://doi.org/10.1016/0022-328X(93)80126-V
Estado	Published - may 4 1993

Nota bibliográfica

Funding Information:
We thank the National Science Foundation (Grant CHE 9108228a) nd the Robert A. Welch Foundation for generousf inancial support.

Financiación

We thank the National Science Foundation (Grant CHE 9108228a) nd the Robert A. Welch Foundation for generousf inancial support.

Financiadores	Número del financiador
Robert A. Welch Foundation
National Science Foundation (NSF)	CHE 9108228a

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

Acceder al documento

10.1016/0022-328X(93)80126-V

Otros archivos y enlaces

Citar esto

@article{66824433464f4bf7a3522fa1f8c84a58,

title = "An indium-phosphorus heterocubane as a new type of indium phosphide precursor",

abstract = "The first indium-phosphorus cubane, [iPrIn(μ3-PSiPh3)]4 (1) has been prepared via the reaction of Li2[PSiPh3] with iPrInI2. The structure of 1 has been determined by X-ray analysis: monoclinic, space group P21/c with a = 15.611(3), b = 25.767(2), c = 22.541(6) {\AA}, β = 96.19(2)°, and Z = 4. Polycrystalline films of indium phosphide have been grown on Si(100) wafers from 1 in a horizontal hot-wall reactor at 500°C. Compound 1 is unstable with respect to photolysis and electrochemical oxidation; however it is relatively stable toward alcoholysis.",

author = "Atwood, \{David A.\} and Cowley, \{Alan H.\} and Jones, \{Richard A.\} and Mardones, \{Miguel A.\}",

year = "1993",

month = may,

day = "4",

doi = "10.1016/0022-328X(93)80126-V",

language = "English",

volume = "449",

pages = "C1",

number = "1-2",

}

TY - JOUR

T1 - An indium-phosphorus heterocubane as a new type of indium phosphide precursor

AU - Atwood, David A.

AU - Cowley, Alan H.

AU - Jones, Richard A.

AU - Mardones, Miguel A.

PY - 1993/5/4

Y1 - 1993/5/4

N2 - The first indium-phosphorus cubane, [iPrIn(μ3-PSiPh3)]4 (1) has been prepared via the reaction of Li2[PSiPh3] with iPrInI2. The structure of 1 has been determined by X-ray analysis: monoclinic, space group P21/c with a = 15.611(3), b = 25.767(2), c = 22.541(6) Å, β = 96.19(2)°, and Z = 4. Polycrystalline films of indium phosphide have been grown on Si(100) wafers from 1 in a horizontal hot-wall reactor at 500°C. Compound 1 is unstable with respect to photolysis and electrochemical oxidation; however it is relatively stable toward alcoholysis.

AB - The first indium-phosphorus cubane, [iPrIn(μ3-PSiPh3)]4 (1) has been prepared via the reaction of Li2[PSiPh3] with iPrInI2. The structure of 1 has been determined by X-ray analysis: monoclinic, space group P21/c with a = 15.611(3), b = 25.767(2), c = 22.541(6) Å, β = 96.19(2)°, and Z = 4. Polycrystalline films of indium phosphide have been grown on Si(100) wafers from 1 in a horizontal hot-wall reactor at 500°C. Compound 1 is unstable with respect to photolysis and electrochemical oxidation; however it is relatively stable toward alcoholysis.

UR - http://www.scopus.com/inward/record.url?scp=0001823081&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0001823081&partnerID=8YFLogxK

U2 - 10.1016/0022-328X(93)80126-V

DO - 10.1016/0022-328X(93)80126-V

M3 - Article

AN - SCOPUS:0001823081

SN - 0022-328X

VL - 449

SP - C1

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 1-2

ER -

An indium-phosphorus heterocubane as a new type of indium phosphide precursor

Resumen

Nota bibliográfica

Financiación

ASJC Scopus subject areas

Acceder al documento

Otros archivos y enlaces

Huella

Citar esto