Analysis of cation—macrocycle complexation by fast atom bombardment mass spectrometry

Toshio Takahashi; Akira Uchiyama; Kaoru Yamada; Bert C. Lynn; George W. Gokel

doi:10.1080/10610279308038313

Analysis of cation—macrocycle complexation by fast atom bombardment mass spectrometry

Toshio Takahashi
, Akira Uchiyama
, Kaoru Yamada
, Bert C. Lynn
, George W. Gokel

Producción científica: Article › revisión exhaustiva

9 Citas (Scopus)

Resumen

Fast atom bombardment mass spectrometry has been used to analyse the cation complexation behaviour of a systematically varied array of crown and lariat ethers having one or two sidearms. Sandwich complexation, apparent when the cation is somewhat larger than the crown cavity, is observed for several systems but the presence of donor-group-containing sidearms in lariat ethers suppresses this phenomenon. Calcium cation complexation proved to be especially interesting.

Idioma original	English
Páginas (desde-hasta)	177-182
Número de páginas	6
Publicación	Supramolecular Chemistry
Volumen	2
N.º	2-3
DOI	https://doi.org/10.1080/10610279308038313
Estado	Published - jul 1 1993

Nota bibliográfica

Funding Information:
We gratefully acknowledge partial support of this work by a grant (GM 36262) to G.W.G.f rom the NIH.

Financiación

We gratefully acknowledge partial support of this work by a grant (GM 36262) to G.W.G.f rom the NIH.

Financiadores
National Institutes of Health (NIH)

ASJC Scopus subject areas

General Chemistry

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title = "Analysis of cation{\textemdash}macrocycle complexation by fast atom bombardment mass spectrometry",

abstract = "Fast atom bombardment mass spectrometry has been used to analyse the cation complexation behaviour of a systematically varied array of crown and lariat ethers having one or two sidearms. Sandwich complexation, apparent when the cation is somewhat larger than the crown cavity, is observed for several systems but the presence of donor-group-containing sidearms in lariat ethers suppresses this phenomenon. Calcium cation complexation proved to be especially interesting.",

author = "Toshio Takahashi and Akira Uchiyama and Kaoru Yamada and Lynn, \{Bert C.\} and Gokel, \{George W.\}",

note = "Funding Information: We gratefully acknowledge partial support of this work by a grant (GM 36262) to G.W.G.f rom the NIH.",

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AU - Takahashi, Toshio

AU - Uchiyama, Akira

AU - Yamada, Kaoru

AU - Lynn, Bert C.

AU - Gokel, George W.

N1 - Funding Information: We gratefully acknowledge partial support of this work by a grant (GM 36262) to G.W.G.f rom the NIH.

PY - 1993/7/1

Y1 - 1993/7/1

N2 - Fast atom bombardment mass spectrometry has been used to analyse the cation complexation behaviour of a systematically varied array of crown and lariat ethers having one or two sidearms. Sandwich complexation, apparent when the cation is somewhat larger than the crown cavity, is observed for several systems but the presence of donor-group-containing sidearms in lariat ethers suppresses this phenomenon. Calcium cation complexation proved to be especially interesting.

AB - Fast atom bombardment mass spectrometry has been used to analyse the cation complexation behaviour of a systematically varied array of crown and lariat ethers having one or two sidearms. Sandwich complexation, apparent when the cation is somewhat larger than the crown cavity, is observed for several systems but the presence of donor-group-containing sidearms in lariat ethers suppresses this phenomenon. Calcium cation complexation proved to be especially interesting.

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UR - https://www.scopus.com/pages/publications/0000496510#tab=citedBy

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DO - 10.1080/10610279308038313

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JO - Supramolecular Chemistry

JF - Supramolecular Chemistry

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ER -

Analysis of cation—macrocycle complexation by fast atom bombardment mass spectrometry

Resumen

Nota bibliográfica

Financiación

ASJC Scopus subject areas

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