Bulky end-capped [1]Benzothieno[3,2-b]benzothiophenes: Reaching high-mobility organic semiconductors by fine tuning of the crystalline solid-state Order

Guillaume Schweicher; Vincent Lemaur; Claude Niebel; Christian Ruzié; Ying Diao; Osamu Goto; Wen Ya Lee; Yeongin Kim; Jean Baptiste Arlin; Jolanta Karpinska; Alan R. Kennedy; Sean R. Parkin; Yoann Olivier; Stefan C.B. Mannsfeld; Jérôme Cornil; Yves H. Geerts; Zhenan Bao

doi:10.1002/adma.201500322

Bulky end-capped [1]Benzothieno[3,2-b]benzothiophenes: Reaching high-mobility organic semiconductors by fine tuning of the crystalline solid-state Order

Guillaume Schweicher
, Vincent Lemaur
, Claude Niebel
, Christian Ruzié
, Ying Diao
, Osamu Goto
, Wen Ya Lee
, Yeongin Kim
, Jean Baptiste Arlin
, Jolanta Karpinska
, Alan R. Kennedy
, Sean R. Parkin
, Yoann Olivier
, Stefan C.B. Mannsfeld
, Jérôme Cornil
, Yves H. Geerts
, Zhenan Bao

Chemistry

Producción científica: Article › revisión exhaustiva

159 Citas (Scopus)

Resumen

A series of bulky end-capped [1]benzothieno[3,2-b]benzothiophenes (BTBTs) are developed in order to tune the packing structure via terminal substitution. A coupled theoretical and experimental study allows us to identify 2,7-di-tert-butylBTBT as a new high-performance organic semiconductor with large and well-balanced transfer integrals, as evidenced by quantum-chemical calculations. Single-crystal field-effect transistors show a remarkable average saturation mobility of 7.1 cm² V^-1 s^-1.

Idioma original	English
Páginas (desde-hasta)	3066-3072
Número de páginas	7
Publicación	Advanced Materials
Volumen	27
N.º	19
DOI	https://doi.org/10.1002/adma.201500322
Estado	Published - may 20 2015

Nota bibliográfica

Publisher Copyright:
© 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

ASJC Scopus subject areas

General Materials Science
Mechanics of Materials
Mechanical Engineering

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10.1002/adma.201500322

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Schweicher, G., Lemaur, V., Niebel, C., Ruzié, C., Diao, Y., Goto, O., Lee, W. Y., Kim, Y., Arlin, J. B., Karpinska, J., Kennedy, A. R., Parkin, S. R., Olivier, Y., Mannsfeld, S. C. B., Cornil, J., Geerts, Y. H., & Bao, Z. (2015). Bulky end-capped [1]Benzothieno[3,2-b]benzothiophenes: Reaching high-mobility organic semiconductors by fine tuning of the crystalline solid-state Order. Advanced Materials, 27(19), 3066-3072. https://doi.org/10.1002/adma.201500322

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title = "Bulky end-capped [1]Benzothieno[3,2-b]benzothiophenes: Reaching high-mobility organic semiconductors by fine tuning of the crystalline solid-state Order",

abstract = "A series of bulky end-capped [1]benzothieno[3,2-b]benzothiophenes (BTBTs) are developed in order to tune the packing structure via terminal substitution. A coupled theoretical and experimental study allows us to identify 2,7-di-tert-butylBTBT as a new high-performance organic semiconductor with large and well-balanced transfer integrals, as evidenced by quantum-chemical calculations. Single-crystal field-effect transistors show a remarkable average saturation mobility of 7.1 cm2 V-1 s-1.",

keywords = "high mobility, organic semiconductor, organic transistor, single-crystal",

author = "Guillaume Schweicher and Vincent Lemaur and Claude Niebel and Christian Ruzi{\'e} and Ying Diao and Osamu Goto and Lee, \{Wen Ya\} and Yeongin Kim and Arlin, \{Jean Baptiste\} and Jolanta Karpinska and Kennedy, \{Alan R.\} and Parkin, \{Sean R.\} and Yoann Olivier and Mannsfeld, \{Stefan C.B.\} and J{\'e}r{\^o}me Cornil and Geerts, \{Yves H.\} and Zhenan Bao",

note = "Publisher Copyright: {\textcopyright} 2015 WILEY-VCH Verlag GmbH \& Co. KGaA, Weinheim.",

year = "2015",

month = may,

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doi = "10.1002/adma.201500322",

language = "English",

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Schweicher, G, Lemaur, V, Niebel, C, Ruzié, C, Diao, Y, Goto, O, Lee, WY, Kim, Y, Arlin, JB, Karpinska, J, Kennedy, AR, Parkin, SR, Olivier, Y, Mannsfeld, SCB, Cornil, J, Geerts, YH & Bao, Z 2015, 'Bulky end-capped [1]Benzothieno[3,2-b]benzothiophenes: Reaching high-mobility organic semiconductors by fine tuning of the crystalline solid-state Order', Advanced Materials, vol. 27, n.º 19, pp. 3066-3072. https://doi.org/10.1002/adma.201500322

TY - JOUR

T1 - Bulky end-capped [1]Benzothieno[3,2-b]benzothiophenes

T2 - Reaching high-mobility organic semiconductors by fine tuning of the crystalline solid-state Order

AU - Schweicher, Guillaume

AU - Lemaur, Vincent

AU - Niebel, Claude

AU - Ruzié, Christian

AU - Diao, Ying

AU - Goto, Osamu

AU - Lee, Wen Ya

AU - Kim, Yeongin

AU - Arlin, Jean Baptiste

AU - Karpinska, Jolanta

AU - Kennedy, Alan R.

AU - Parkin, Sean R.

AU - Olivier, Yoann

AU - Mannsfeld, Stefan C.B.

AU - Cornil, Jérôme

AU - Geerts, Yves H.

AU - Bao, Zhenan

PY - 2015/5/20

Y1 - 2015/5/20

N2 - A series of bulky end-capped [1]benzothieno[3,2-b]benzothiophenes (BTBTs) are developed in order to tune the packing structure via terminal substitution. A coupled theoretical and experimental study allows us to identify 2,7-di-tert-butylBTBT as a new high-performance organic semiconductor with large and well-balanced transfer integrals, as evidenced by quantum-chemical calculations. Single-crystal field-effect transistors show a remarkable average saturation mobility of 7.1 cm2 V-1 s-1.

AB - A series of bulky end-capped [1]benzothieno[3,2-b]benzothiophenes (BTBTs) are developed in order to tune the packing structure via terminal substitution. A coupled theoretical and experimental study allows us to identify 2,7-di-tert-butylBTBT as a new high-performance organic semiconductor with large and well-balanced transfer integrals, as evidenced by quantum-chemical calculations. Single-crystal field-effect transistors show a remarkable average saturation mobility of 7.1 cm2 V-1 s-1.

KW - high mobility

KW - organic semiconductor

KW - organic transistor

KW - single-crystal

UR - https://www.scopus.com/pages/publications/85027939139

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SN - 0935-9648

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SP - 3066

EP - 3072

JO - Advanced Materials

JF - Advanced Materials

IS - 19

ER -

Bulky end-capped [1]Benzothieno[3,2-b]benzothiophenes: Reaching high-mobility organic semiconductors by fine tuning of the crystalline solid-state Order

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