Carbomethoxylation of ethylene catalysed by Pd(II) complexes intercalated in smectite clay

M. Crocker; R. H.M. Herold

doi:10.1016/0304-5102(91)80162-V

Carbomethoxylation of ethylene catalysed by Pd(II) complexes intercalated in smectite clay

M. Crocker
, R. H.M. Herold

Chemistry

Producción científica: Article › revisión exhaustiva

25 Citas (Scopus)

Resumen

Palladium(II) derivatives were intercalated in smectite clay and their activity in the carbomethoxylation of ethylene studied. The activity of the complexes depends on the Brönsted acidity of the clay support: sodium montmorillonite, a weakly acidic clay, shows no promoting effect, whereas with more acidic clays such as K10 montmorillonite reaction rates of the order of 100 turnovers h^-1 are obtained.

Idioma original	English
Páginas (desde-hasta)	209-216
Número de páginas	8
Publicación	Journal of Molecular Catalysis
Volumen	70
N.º	2
DOI	https://doi.org/10.1016/0304-5102(91)80162-V
Estado	Published - dic 1 1991

ASJC Scopus subject areas

General Engineering

Acceder al documento

10.1016/0304-5102(91)80162-V

Otros archivos y enlaces

Link to publication in Scopus

Citar esto

@article{34912601971040559efbe7a4575a034a,

title = "Carbomethoxylation of ethylene catalysed by Pd(II) complexes intercalated in smectite clay",

abstract = "Palladium(II) derivatives were intercalated in smectite clay and their activity in the carbomethoxylation of ethylene studied. The activity of the complexes depends on the Br{\"o}nsted acidity of the clay support: sodium montmorillonite, a weakly acidic clay, shows no promoting effect, whereas with more acidic clays such as K10 montmorillonite reaction rates of the order of 100 turnovers h-1 are obtained.",

author = "M. Crocker and Herold, \{R. H.M.\}",

year = "1991",

month = dec,

day = "1",

doi = "10.1016/0304-5102(91)80162-V",

language = "English",

volume = "70",

pages = "209--216",

number = "2",

}

TY - JOUR

T1 - Carbomethoxylation of ethylene catalysed by Pd(II) complexes intercalated in smectite clay

AU - Crocker, M.

AU - Herold, R. H.M.

PY - 1991/12/1

Y1 - 1991/12/1

N2 - Palladium(II) derivatives were intercalated in smectite clay and their activity in the carbomethoxylation of ethylene studied. The activity of the complexes depends on the Brönsted acidity of the clay support: sodium montmorillonite, a weakly acidic clay, shows no promoting effect, whereas with more acidic clays such as K10 montmorillonite reaction rates of the order of 100 turnovers h-1 are obtained.

AB - Palladium(II) derivatives were intercalated in smectite clay and their activity in the carbomethoxylation of ethylene studied. The activity of the complexes depends on the Brönsted acidity of the clay support: sodium montmorillonite, a weakly acidic clay, shows no promoting effect, whereas with more acidic clays such as K10 montmorillonite reaction rates of the order of 100 turnovers h-1 are obtained.

UR - https://www.scopus.com/pages/publications/0026375920

UR - https://www.scopus.com/pages/publications/0026375920#tab=citedBy

U2 - 10.1016/0304-5102(91)80162-V

DO - 10.1016/0304-5102(91)80162-V

M3 - Article

AN - SCOPUS:0026375920

SN - 0304-5102

VL - 70

SP - 209

EP - 216

JO - Journal of Molecular Catalysis

JF - Journal of Molecular Catalysis

IS - 2

ER -

Carbomethoxylation of ethylene catalysed by Pd(II) complexes intercalated in smectite clay

Resumen

ASJC Scopus subject areas

Acceder al documento

Otros archivos y enlaces

Huella

Citar esto