Deuterium exchange study for hydrogenation of D 5-1-pentene (4,4,5,5,5) over conventional cobalt Fischer-Tropsch catalyst

Muthu Kumaran Gnanamani; Wilson D. Shafer; Burtron H. Davis

doi:10.1007/s10562-011-0750-8

Deuterium exchange study for hydrogenation of D ₅-1-pentene (4,4,5,5,5) over conventional cobalt Fischer-Tropsch catalyst

Muthu Kumaran Gnanamani
, Wilson D. Shafer
, Burtron H. Davis

Center for Applied Energy Research (CAER)

Producción científica: Article › revisión exhaustiva

1 Cita (Scopus)

Resumen

The hydrogen-deuterium exchange reaction was performed for hydrogenation of D ₅-1-pentene (4,4,5,5,5) under realistic cobalt Fischer-Tropsch synthesis conditions. In the presence of CO, the added deutero-1-pentene did not show any significant H/D exchange but a step-wise H/D exchange occurs when CO was replaced with N ₂. The inhibition effects of CO and other FT products on H/D exchange of D ₅-1-pentene and a pressure dependency effect on H/D exchange are observed. Graphical Abstract: [Figure not available: see fulltext.]

Idioma original	English
Páginas (desde-hasta)	190-194
Número de páginas	5
Publicación	Catalysis Letters
Volumen	142
N.º	2
DOI	https://doi.org/10.1007/s10562-011-0750-8
Estado	Published - feb 2012

Nota bibliográfica

Funding Information:
Acknowledgments The work was supported by funding from the Commonwealth of Kentucky.

Financiación

Acknowledgments The work was supported by funding from the Commonwealth of Kentucky.

Financiadores
COMMONWEALTH OF KENTUCKY

ASJC Scopus subject areas

Catalysis
General Chemistry

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10.1007/s10562-011-0750-8

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title = "Deuterium exchange study for hydrogenation of D 5-1-pentene (4,4,5,5,5) over conventional cobalt Fischer-Tropsch catalyst",

abstract = "The hydrogen-deuterium exchange reaction was performed for hydrogenation of D 5-1-pentene (4,4,5,5,5) under realistic cobalt Fischer-Tropsch synthesis conditions. In the presence of CO, the added deutero-1-pentene did not show any significant H/D exchange but a step-wise H/D exchange occurs when CO was replaced with N 2. The inhibition effects of CO and other FT products on H/D exchange of D 5-1-pentene and a pressure dependency effect on H/D exchange are observed. Graphical Abstract: [Figure not available: see fulltext.]",

keywords = "Cobalt, Deuterium exchange, Deutero-1-pentene, Fischer-Tropsch, Hydrogenation",

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doi = "10.1007/s10562-011-0750-8",

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T1 - Deuterium exchange study for hydrogenation of D 5-1-pentene (4,4,5,5,5) over conventional cobalt Fischer-Tropsch catalyst

AU - Gnanamani, Muthu Kumaran

AU - Shafer, Wilson D.

AU - Davis, Burtron H.

N1 - Funding Information: Acknowledgments The work was supported by funding from the Commonwealth of Kentucky.

PY - 2012/2

Y1 - 2012/2

N2 - The hydrogen-deuterium exchange reaction was performed for hydrogenation of D 5-1-pentene (4,4,5,5,5) under realistic cobalt Fischer-Tropsch synthesis conditions. In the presence of CO, the added deutero-1-pentene did not show any significant H/D exchange but a step-wise H/D exchange occurs when CO was replaced with N 2. The inhibition effects of CO and other FT products on H/D exchange of D 5-1-pentene and a pressure dependency effect on H/D exchange are observed. Graphical Abstract: [Figure not available: see fulltext.]

AB - The hydrogen-deuterium exchange reaction was performed for hydrogenation of D 5-1-pentene (4,4,5,5,5) under realistic cobalt Fischer-Tropsch synthesis conditions. In the presence of CO, the added deutero-1-pentene did not show any significant H/D exchange but a step-wise H/D exchange occurs when CO was replaced with N 2. The inhibition effects of CO and other FT products on H/D exchange of D 5-1-pentene and a pressure dependency effect on H/D exchange are observed. Graphical Abstract: [Figure not available: see fulltext.]

KW - Cobalt

KW - Deuterium exchange

KW - Deutero-1-pentene

KW - Fischer-Tropsch

KW - Hydrogenation

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