Electronic Structure of (η 5-c5h5)pt(ch3)3 and (η5-c5(ch3)5)pt(ch3)3 From Uv Photoelectron Spectra

D. S. Yang; G. M. Bancroft; R. J. Puddephatt; B. E. Bursten; S. D. Mckee

doi:10.1021/ic00304a015

Electronic Structure of (η ⁵-c₅h₅)pt(ch₃)3 and (η⁵-c₅(ch₃)₅)pt(ch₃)3 From Uv Photoelectron Spectra

D. S. Yang
, G. M. Bancroft
, R. J. Puddephatt
, B. E. Bursten
, S. D. Mckee

Producción científica: Article › revisión exhaustiva

20 Citas (Scopus)

Resumen

Gas-phase He I and He II photoelectron spectra for CpPtMe₃and the new complex Cp*PtMe₃(Cp = η⁵-C₅H₅, Cp* = η⁵-C₅Me₅, Me = CH₃) have been obtained. The valence orbitals responsible for the ionizations have been assigned to the corresponding molecular orbitals with the aid of Fenske-Hall molecular orbital calculations. The ordering of the molecular orbitals (in order of increasing binding energy) is Pt 5d < Pt-Me < Pt-Cp. From the photoelectron results, it is apparent that the Cp e₁” orbitals interact strongly with the metal orbitals.

Idioma original	English
Páginas (desde-hasta)	872-877
Número de páginas	6
Publicación	Inorganic Chemistry
Volumen	28
N.º	5
DOI	https://doi.org/10.1021/ic00304a015
Estado	Published - feb 1 1989

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry

Acceder al documento

10.1021/ic00304a015

Otros archivos y enlaces

Citar esto

@article{2d68ab7237a84ceeae5e88c623c50dfe,

title = "Electronic Structure of (η 5-c5h5)pt(ch3)3 and (η5-c5(ch3)5)pt(ch3)3 From Uv Photoelectron Spectra",

abstract = "Gas-phase He I and He II photoelectron spectra for CpPtMe3and the new complex Cp*PtMe3(Cp = η5-C5H5, Cp* = η5-C5Me5, Me = CH3) have been obtained. The valence orbitals responsible for the ionizations have been assigned to the corresponding molecular orbitals with the aid of Fenske-Hall molecular orbital calculations. The ordering of the molecular orbitals (in order of increasing binding energy) is Pt 5d < Pt-Me < Pt-Cp. From the photoelectron results, it is apparent that the Cp e1” orbitals interact strongly with the metal orbitals.",

author = "Yang, \{D. S.\} and Bancroft, \{G. M.\} and Puddephatt, \{R. J.\} and Bursten, \{B. E.\} and Mckee, \{S. D.\}",

year = "1989",

month = feb,

day = "1",

doi = "10.1021/ic00304a015",

language = "English",

volume = "28",

pages = "872--877",

number = "5",

}

TY - JOUR

T1 - Electronic Structure of (η 5-c5h5)pt(ch3)3 and (η5-c5(ch3)5)pt(ch3)3 From Uv Photoelectron Spectra

AU - Yang, D. S.

AU - Bancroft, G. M.

AU - Puddephatt, R. J.

AU - Bursten, B. E.

AU - Mckee, S. D.

PY - 1989/2/1

Y1 - 1989/2/1

N2 - Gas-phase He I and He II photoelectron spectra for CpPtMe3and the new complex Cp*PtMe3(Cp = η5-C5H5, Cp* = η5-C5Me5, Me = CH3) have been obtained. The valence orbitals responsible for the ionizations have been assigned to the corresponding molecular orbitals with the aid of Fenske-Hall molecular orbital calculations. The ordering of the molecular orbitals (in order of increasing binding energy) is Pt 5d < Pt-Me < Pt-Cp. From the photoelectron results, it is apparent that the Cp e1” orbitals interact strongly with the metal orbitals.

AB - Gas-phase He I and He II photoelectron spectra for CpPtMe3and the new complex Cp*PtMe3(Cp = η5-C5H5, Cp* = η5-C5Me5, Me = CH3) have been obtained. The valence orbitals responsible for the ionizations have been assigned to the corresponding molecular orbitals with the aid of Fenske-Hall molecular orbital calculations. The ordering of the molecular orbitals (in order of increasing binding energy) is Pt 5d < Pt-Me < Pt-Cp. From the photoelectron results, it is apparent that the Cp e1” orbitals interact strongly with the metal orbitals.

UR - https://www.scopus.com/pages/publications/0040598175

UR - https://www.scopus.com/pages/publications/0040598175#tab=citedBy

U2 - 10.1021/ic00304a015

DO - 10.1021/ic00304a015

M3 - Article

AN - SCOPUS:0040598175

SN - 0020-1669

VL - 28

SP - 872

EP - 877

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 5

ER -