Elevated arsenic in deeper groundwater of the western Bengal basin, India: Extent and controls from regional to local scale

Abhijit Mukherjee; Alan E. Fryar; Bridget R. Scanlon; Prosun Bhattacharya; Animesh Bhattacharya

doi:10.1016/j.apgeochem.2011.01.017

Elevated arsenic in deeper groundwater of the western Bengal basin, India: Extent and controls from regional to local scale

Abhijit Mukherjee
, Alan E. Fryar
, Bridget R. Scanlon
, Prosun Bhattacharya
, Animesh Bhattacharya

Producción científica: Article › revisión exhaustiva

144 Citas (Scopus)

Resumen

The deeper groundwater (depending on definition) of the Bengal basin (Ganges-Brahmaputra delta) has long been considered as an alternate, safe drinking-water source in areas with As-enrichment in near-surface groundwater. The present study provides the first collective discussion on extent and controls of elevated As in deeper groundwater of a regional study area in the western part of the Bengal basin. Deeper groundwater is defined here as non-brackish, potable (Cl^-≤250mg/L) groundwater available at the maximum accessed depth (∼80-300m). The extent of elevated As in deeper groundwater in the study area seems to be largely controlled by the aquifer-aquitard framework. Arsenic-enriched deeper groundwater is mostly encountered north of 22.75°N latitude, where an unconfined to semi-confined aquifer consisting of Holocene- to early Neogene-age gray sand dominates the hydrostratigraphy to 300m depth below land surface. Aquifer sediments are not abnormally enriched in As at any depth, but sediment and water chemistry are conducive to As mobilization in both shallow and deeper parts of the aquifer(s). The biogeochemical triggers are influenced by complex redox disequilibria. Results of numerical modeling and profiles of environmental tracers at a local-scale study site suggest that deeper groundwater abstraction can draw As-enriched water to 150m depth within a few decades, synchronous with the advent of wide-scale irrigational pumping in West Bengal (India).

Idioma original	English
Páginas (desde-hasta)	600-613
Número de páginas	14
Publicación	Applied Geochemistry
Volumen	26
N.º	4
DOI	https://doi.org/10.1016/j.apgeochem.2011.01.017
Estado	Published - abr 2011

Nota bibliográfica

Funding Information:
We thank the Government of West Bengal (PHED and State Water Investigation Directorate) for their cooperation and assistance. However, the ideas and views expressed in this paper are solely those of the authors and have not been endorsed by any other person or agency. Funding, analytical and computational help for the study were provided by the University of Kentucky, University of Texas at Austin, Royal Institute of Technology, Geological Society of America, Swedish International Development Agency (SIDA-SAREC), Swedish Research Council (VR-SIDA), and US National Science Foundation (NSF). The authors acknowledge the help provided by Barindra Lal Mukherjee, Murali Singh, Sudipta Rakshit (Montclair State University), and Debashis Chatterjee (Kalyani University) with field work. Charles Harvey (MIT), Holly Michael (University of Delaware), William Thomas (University of Kentucky), D. Kip Solomon and Alan Rigby (University of Utah), Tom Gleeson (University of British Columbia), and Andrew Manning (US Geological Survey) provided advice during data analyses and/or informal reviews of previous drafts of the manuscript.

Financiación

We thank the Government of West Bengal (PHED and State Water Investigation Directorate) for their cooperation and assistance. However, the ideas and views expressed in this paper are solely those of the authors and have not been endorsed by any other person or agency. Funding, analytical and computational help for the study were provided by the University of Kentucky, University of Texas at Austin, Royal Institute of Technology, Geological Society of America, Swedish International Development Agency (SIDA-SAREC), Swedish Research Council (VR-SIDA), and US National Science Foundation (NSF). The authors acknowledge the help provided by Barindra Lal Mukherjee, Murali Singh, Sudipta Rakshit (Montclair State University), and Debashis Chatterjee (Kalyani University) with field work. Charles Harvey (MIT), Holly Michael (University of Delaware), William Thomas (University of Kentucky), D. Kip Solomon and Alan Rigby (University of Utah), Tom Gleeson (University of British Columbia), and Andrew Manning (US Geological Survey) provided advice during data analyses and/or informal reviews of previous drafts of the manuscript.

Financiadores
Sida-SAREC
University of Kentucky, University of Texas at Austin
VR-Sida
National Science Foundation (NSF)
Styrelsen för Internationellt Utvecklingssamarbete
Vetenskapsrådet

ODS de las Naciones Unidas

Este resultado contribuye a los siguientes Objetivos de Desarrollo Sostenible

Clean water and sanitation

ASJC Scopus subject areas

Environmental Chemistry
Pollution
Geochemistry and Petrology

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10.1016/j.apgeochem.2011.01.017

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title = "Elevated arsenic in deeper groundwater of the western Bengal basin, India: Extent and controls from regional to local scale",

abstract = "The deeper groundwater (depending on definition) of the Bengal basin (Ganges-Brahmaputra delta) has long been considered as an alternate, safe drinking-water source in areas with As-enrichment in near-surface groundwater. The present study provides the first collective discussion on extent and controls of elevated As in deeper groundwater of a regional study area in the western part of the Bengal basin. Deeper groundwater is defined here as non-brackish, potable (Cl-≤250mg/L) groundwater available at the maximum accessed depth (∼80-300m). The extent of elevated As in deeper groundwater in the study area seems to be largely controlled by the aquifer-aquitard framework. Arsenic-enriched deeper groundwater is mostly encountered north of 22.75°N latitude, where an unconfined to semi-confined aquifer consisting of Holocene- to early Neogene-age gray sand dominates the hydrostratigraphy to 300m depth below land surface. Aquifer sediments are not abnormally enriched in As at any depth, but sediment and water chemistry are conducive to As mobilization in both shallow and deeper parts of the aquifer(s). The biogeochemical triggers are influenced by complex redox disequilibria. Results of numerical modeling and profiles of environmental tracers at a local-scale study site suggest that deeper groundwater abstraction can draw As-enriched water to 150m depth within a few decades, synchronous with the advent of wide-scale irrigational pumping in West Bengal (India).",

author = "Abhijit Mukherjee and Fryar, \{Alan E.\} and Scanlon, \{Bridget R.\} and Prosun Bhattacharya and Animesh Bhattacharya",

note = "Funding Information: We thank the Government of West Bengal (PHED and State Water Investigation Directorate) for their cooperation and assistance. However, the ideas and views expressed in this paper are solely those of the authors and have not been endorsed by any other person or agency. Funding, analytical and computational help for the study were provided by the University of Kentucky, University of Texas at Austin, Royal Institute of Technology, Geological Society of America, Swedish International Development Agency (SIDA-SAREC), Swedish Research Council (VR-SIDA), and US National Science Foundation (NSF). The authors acknowledge the help provided by Barindra Lal Mukherjee, Murali Singh, Sudipta Rakshit (Montclair State University), and Debashis Chatterjee (Kalyani University) with field work. Charles Harvey (MIT), Holly Michael (University of Delaware), William Thomas (University of Kentucky), D. Kip Solomon and Alan Rigby (University of Utah), Tom Gleeson (University of British Columbia), and Andrew Manning (US Geological Survey) provided advice during data analyses and/or informal reviews of previous drafts of the manuscript. ",

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AU - Bhattacharya, Animesh

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Elevated arsenic in deeper groundwater of the western Bengal basin, India: Extent and controls from regional to local scale

Resumen

Nota bibliográfica

Financiación

ODS de las Naciones Unidas

ASJC Scopus subject areas

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