Flotation of monazite in the presence of calcite part I: Calcium ion effects on the adsorption of hydroxamic acid

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128 Citas (Scopus)

Resumen

The dissolution of minerals provides elevated concentrations of alkaline earth metal ions such as calcium (Ca2+) in water which may have a significant influence on flotation performance. The effects of Ca2+ ions dissolved from calcite surfaces on the flotation performance of a monazite-calcite system have been investigated using micro-flotation tests followed by fundamental collector adsorption studies. The results indicate that specially adsorbed CaOH+ via hydrogen bonding competed with hydroxamic acid for the phosphate-oxygen active sites on the monazite surface and decreased its hydrophobicity due to hydration. Electrostatically adsorbed CaOH+ on monazite increased the adsorption density of hydroxamic acid through a chelating interaction. At higher dosages of calcium and hydroxamic acid, bulk and surface precipitation of calcium-hydroxamate occurs in the monazite-calcium-hydroxamic acid system.

Idioma originalEnglish
Páginas (desde-hasta)40-48
Número de páginas9
PublicaciónMinerals Engineering
Volumen100
DOI
EstadoPublished - ene 1 2017

Nota bibliográfica

Publisher Copyright:
© 2016 Elsevier Ltd

Financiación

The research results presented in this publication was funded in part by the Kentucky Energy and Environment Cabinet (Project ID No. PON2 127 150002394 1).

FinanciadoresNúmero del financiador
Kentucky Energy and Environment Cabinet Department for EnergyPON2 127 150002394 1

    ASJC Scopus subject areas

    • Control and Systems Engineering
    • General Chemistry
    • Geotechnical Engineering and Engineering Geology
    • Mechanical Engineering

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