Material transfer between Al, Cu, Ti and TiB 2 coatings: Effects of atmosphere and speed

E. Konca; Y. T. Cheng; A. T. Alpas

Material transfer between Al, Cu, Ti and TiB ₂ coatings: Effects of atmosphere and speed

E. Konca, Y. T. Cheng, A. T. Alpas

Producción científica: Conference contribution › revisión exhaustiva

Resumen

In an attempt to better understand the mechanisms of material transfer and adhesion to coated surfaces, magnetron sputtered TiB ₂ coatings on M2 tool steel discs have been tested against commercially pure Al, Cu and Ti pins using an environmentally controlled vacuum pin-on-disc tribometer. A constant load of 4.9 N and three different sliding speeds of 0.015, 0.120 and 0.650 m/s were employed. Pin-on-disc tests were done in ambient air and under argon atmosphere. Material transfer to the TiB ₂ surface was observed to occur in two different morphologies including the formation of a thin layer of metal covering the counterface (smearing), and material transfer in the form of larger pieces, which normally became adhered to the counterface. The minimum amount of material transfer was from the Cu pin to the TiB ₂ coating surface in both argon and ambient air tests. For Al and Ti, the amount of material adhered to the coating surface was significantly greater in argon than in ambient air tests. The most severe form of adhesion occurred when the Ti pin was tested against the TiB ₂ coating in the argon atmosphere. For Al, the transfer material mostly smeared on the TiB ₂ surface in argon. More material was removed from the metal pins in ambient air and the transferred material became mostly oxidized loose wear debris during sliding. The relative amounts of the debris formed could be ranked with respect to the driving forces of the metals for oxidation (i.e. standard Gibbs free energy of oxide formation); it was highest for Al and lowest for Cu. Sliding speed affected both the amount and morphology of the material transferred onto the TiB ₂ coating surface. For Ti, the amount of material adhered to the TiB ₂ coating surface increased with sliding speed in both argon and ambient air. The adhered particles were mostly in the form of chunks of material at the high sliding speed. The observations reported here showed the importance of test atmosphere, loading conditions, and the mechanical properties of the metals on the adhesion and transfer behavior of metals on coating surfaces.

Idioma original	English
Título de la publicación alojada	Surface Engineering in Materials Science III - Proceedings of a Symposium sponsored by the Surface Engineering Committee of the (MPMD) of the Minerals, Metals and Materials Society, TMS
Editores	A. Agarwal, N.B. Dahotre, S. Seal, J.J. Moore, C. Blue
Páginas	345-354
Número de páginas	10
Estado	Published - 2005
Evento	2005 TMS Annual Meeting - San Francisco, CA, United States Duración: feb 13 2005 → feb 17 2005

Serie de la publicación

Nombre	Surface Engineering in Materials Science III - Proceedings of a Symposium sponsored by the Surface Engineering Committee of the(MPMD) of the Minerals, Metals and Materials Society, TMS

Conference

Conference	2005 TMS Annual Meeting
País/Territorio	United States
Ciudad	San Francisco, CA
Período	2/13/05 → 2/17/05

ASJC Scopus subject areas

General Engineering

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Konca, E., Cheng, Y. T., & Alpas, A. T. (2005). Material transfer between Al, Cu, Ti and TiB ₂ coatings: Effects of atmosphere and speed. En A. Agarwal, N. B. Dahotre, S. Seal, J. J. Moore, & C. Blue (Eds.), Surface Engineering in Materials Science III - Proceedings of a Symposium sponsored by the Surface Engineering Committee of the (MPMD) of the Minerals, Metals and Materials Society, TMS (pp. 345-354). (Surface Engineering in Materials Science III - Proceedings of a Symposium sponsored by the Surface Engineering Committee of the(MPMD) of the Minerals, Metals and Materials Society, TMS).

Konca, E. ; Cheng, Y. T. ; Alpas, A. T. / Material transfer between Al, Cu, Ti and TiB ₂ coatings : Effects of atmosphere and speed. Surface Engineering in Materials Science III - Proceedings of a Symposium sponsored by the Surface Engineering Committee of the (MPMD) of the Minerals, Metals and Materials Society, TMS. editor / A. Agarwal ; N.B. Dahotre ; S. Seal ; J.J. Moore ; C. Blue. 2005. pp. 345-354 (Surface Engineering in Materials Science III - Proceedings of a Symposium sponsored by the Surface Engineering Committee of the(MPMD) of the Minerals, Metals and Materials Society, TMS).

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title = "Material transfer between Al, Cu, Ti and TiB 2 coatings: Effects of atmosphere and speed",

abstract = "In an attempt to better understand the mechanisms of material transfer and adhesion to coated surfaces, magnetron sputtered TiB 2 coatings on M2 tool steel discs have been tested against commercially pure Al, Cu and Ti pins using an environmentally controlled vacuum pin-on-disc tribometer. A constant load of 4.9 N and three different sliding speeds of 0.015, 0.120 and 0.650 m/s were employed. Pin-on-disc tests were done in ambient air and under argon atmosphere. Material transfer to the TiB 2 surface was observed to occur in two different morphologies including the formation of a thin layer of metal covering the counterface (smearing), and material transfer in the form of larger pieces, which normally became adhered to the counterface. The minimum amount of material transfer was from the Cu pin to the TiB 2 coating surface in both argon and ambient air tests. For Al and Ti, the amount of material adhered to the coating surface was significantly greater in argon than in ambient air tests. The most severe form of adhesion occurred when the Ti pin was tested against the TiB 2 coating in the argon atmosphere. For Al, the transfer material mostly smeared on the TiB 2 surface in argon. More material was removed from the metal pins in ambient air and the transferred material became mostly oxidized loose wear debris during sliding. The relative amounts of the debris formed could be ranked with respect to the driving forces of the metals for oxidation (i.e. standard Gibbs free energy of oxide formation); it was highest for Al and lowest for Cu. Sliding speed affected both the amount and morphology of the material transferred onto the TiB 2 coating surface. For Ti, the amount of material adhered to the TiB 2 coating surface increased with sliding speed in both argon and ambient air. The adhered particles were mostly in the form of chunks of material at the high sliding speed. The observations reported here showed the importance of test atmosphere, loading conditions, and the mechanical properties of the metals on the adhesion and transfer behavior of metals on coating surfaces.",

keywords = "Adhesion, Aluminum, Copper, Material Transfer, Pin-on-disc, Titanium Diboride",

author = "E. Konca and Cheng, \{Y. T.\} and Alpas, \{A. T.\}",

year = "2005",

language = "English",

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series = "Surface Engineering in Materials Science III - Proceedings of a Symposium sponsored by the Surface Engineering Committee of the(MPMD) of the Minerals, Metals and Materials Society, TMS",

pages = "345--354",

editor = "A. Agarwal and N.B. Dahotre and S. Seal and J.J. Moore and C. Blue",

booktitle = "Surface Engineering in Materials Science III - Proceedings of a Symposium sponsored by the Surface Engineering Committee of the (MPMD) of the Minerals, Metals and Materials Society, TMS",

note = "2005 TMS Annual Meeting ; Conference date: 13-02-2005 Through 17-02-2005",

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Konca, E, Cheng, YT & Alpas, AT 2005, Material transfer between Al, Cu, Ti and TiB ₂ coatings: Effects of atmosphere and speed. En A Agarwal, NB Dahotre, S Seal, JJ Moore & C Blue (eds.), Surface Engineering in Materials Science III - Proceedings of a Symposium sponsored by the Surface Engineering Committee of the (MPMD) of the Minerals, Metals and Materials Society, TMS. Surface Engineering in Materials Science III - Proceedings of a Symposium sponsored by the Surface Engineering Committee of the(MPMD) of the Minerals, Metals and Materials Society, TMS, pp. 345-354, 2005 TMS Annual Meeting, San Francisco, CA, United States, 2/13/05.

Material transfer between Al, Cu, Ti and TiB ₂ coatings: Effects of atmosphere and speed. / Konca, E.; Cheng, Y. T.; Alpas, A. T.
Surface Engineering in Materials Science III - Proceedings of a Symposium sponsored by the Surface Engineering Committee of the (MPMD) of the Minerals, Metals and Materials Society, TMS. ed. / A. Agarwal; N.B. Dahotre; S. Seal; J.J. Moore; C. Blue. 2005. p. 345-354 (Surface Engineering in Materials Science III - Proceedings of a Symposium sponsored by the Surface Engineering Committee of the(MPMD) of the Minerals, Metals and Materials Society, TMS).

Producción científica: Conference contribution › revisión exhaustiva

TY - GEN

T1 - Material transfer between Al, Cu, Ti and TiB 2 coatings

T2 - 2005 TMS Annual Meeting

AU - Konca, E.

AU - Cheng, Y. T.

AU - Alpas, A. T.

PY - 2005

Y1 - 2005

N2 - In an attempt to better understand the mechanisms of material transfer and adhesion to coated surfaces, magnetron sputtered TiB 2 coatings on M2 tool steel discs have been tested against commercially pure Al, Cu and Ti pins using an environmentally controlled vacuum pin-on-disc tribometer. A constant load of 4.9 N and three different sliding speeds of 0.015, 0.120 and 0.650 m/s were employed. Pin-on-disc tests were done in ambient air and under argon atmosphere. Material transfer to the TiB 2 surface was observed to occur in two different morphologies including the formation of a thin layer of metal covering the counterface (smearing), and material transfer in the form of larger pieces, which normally became adhered to the counterface. The minimum amount of material transfer was from the Cu pin to the TiB 2 coating surface in both argon and ambient air tests. For Al and Ti, the amount of material adhered to the coating surface was significantly greater in argon than in ambient air tests. The most severe form of adhesion occurred when the Ti pin was tested against the TiB 2 coating in the argon atmosphere. For Al, the transfer material mostly smeared on the TiB 2 surface in argon. More material was removed from the metal pins in ambient air and the transferred material became mostly oxidized loose wear debris during sliding. The relative amounts of the debris formed could be ranked with respect to the driving forces of the metals for oxidation (i.e. standard Gibbs free energy of oxide formation); it was highest for Al and lowest for Cu. Sliding speed affected both the amount and morphology of the material transferred onto the TiB 2 coating surface. For Ti, the amount of material adhered to the TiB 2 coating surface increased with sliding speed in both argon and ambient air. The adhered particles were mostly in the form of chunks of material at the high sliding speed. The observations reported here showed the importance of test atmosphere, loading conditions, and the mechanical properties of the metals on the adhesion and transfer behavior of metals on coating surfaces.

AB - In an attempt to better understand the mechanisms of material transfer and adhesion to coated surfaces, magnetron sputtered TiB 2 coatings on M2 tool steel discs have been tested against commercially pure Al, Cu and Ti pins using an environmentally controlled vacuum pin-on-disc tribometer. A constant load of 4.9 N and three different sliding speeds of 0.015, 0.120 and 0.650 m/s were employed. Pin-on-disc tests were done in ambient air and under argon atmosphere. Material transfer to the TiB 2 surface was observed to occur in two different morphologies including the formation of a thin layer of metal covering the counterface (smearing), and material transfer in the form of larger pieces, which normally became adhered to the counterface. The minimum amount of material transfer was from the Cu pin to the TiB 2 coating surface in both argon and ambient air tests. For Al and Ti, the amount of material adhered to the coating surface was significantly greater in argon than in ambient air tests. The most severe form of adhesion occurred when the Ti pin was tested against the TiB 2 coating in the argon atmosphere. For Al, the transfer material mostly smeared on the TiB 2 surface in argon. More material was removed from the metal pins in ambient air and the transferred material became mostly oxidized loose wear debris during sliding. The relative amounts of the debris formed could be ranked with respect to the driving forces of the metals for oxidation (i.e. standard Gibbs free energy of oxide formation); it was highest for Al and lowest for Cu. Sliding speed affected both the amount and morphology of the material transferred onto the TiB 2 coating surface. For Ti, the amount of material adhered to the TiB 2 coating surface increased with sliding speed in both argon and ambient air. The adhered particles were mostly in the form of chunks of material at the high sliding speed. The observations reported here showed the importance of test atmosphere, loading conditions, and the mechanical properties of the metals on the adhesion and transfer behavior of metals on coating surfaces.

KW - Adhesion

KW - Aluminum

KW - Copper

KW - Material Transfer

KW - Pin-on-disc

KW - Titanium Diboride

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M3 - Conference contribution

AN - SCOPUS:33645025351

SN - 0873395905

SN - 9780873395908

T3 - Surface Engineering in Materials Science III - Proceedings of a Symposium sponsored by the Surface Engineering Committee of the(MPMD) of the Minerals, Metals and Materials Society, TMS

SP - 345

EP - 354

BT - Surface Engineering in Materials Science III - Proceedings of a Symposium sponsored by the Surface Engineering Committee of the (MPMD) of the Minerals, Metals and Materials Society, TMS

A2 - Agarwal, A.

A2 - Dahotre, N.B.

A2 - Seal, S.

A2 - Moore, J.J.

A2 - Blue, C.

Y2 - 13 February 2005 through 17 February 2005

ER -

Konca E, Cheng YT, Alpas AT. Material transfer between Al, Cu, Ti and TiB ₂ coatings: Effects of atmosphere and speed. En Agarwal A, Dahotre NB, Seal S, Moore JJ, Blue C, editores, Surface Engineering in Materials Science III - Proceedings of a Symposium sponsored by the Surface Engineering Committee of the (MPMD) of the Minerals, Metals and Materials Society, TMS. 2005. p. 345-354. (Surface Engineering in Materials Science III - Proceedings of a Symposium sponsored by the Surface Engineering Committee of the(MPMD) of the Minerals, Metals and Materials Society, TMS).